CO shift catalyst, CO shift reaction apparatus, and method for purifying gasified gas

Patent metadata

Field	Value
Publication number	US-10774278-B2
Application number	US-201715617193-A
Country	US
Kind code	B2
Filing date	Jun 8, 2017
Priority date	Feb 27, 2013
Publication date	Sep 15, 2020
Grant date	Sep 15, 2020

Abstract

A CO shift catalyst according to the present invention reforms carbon monoxide (CO) in gas. The CO shift catalyst has one of molybdenum (Mo) or iron (Fe) as a main component and has an active ingredient having one of nickel (Ni) or ruthenium (Ru) as an accessory component and one or two or more kinds of oxides from among titanium (Ti), zirconium (Zr), and cerium (Ce) for supporting the active ingredient as a support. The temperature at the time of manufacturing and firing the catalyst is equal to or higher than 550° C.

First claim

The invention claimed is:

1. A method of producing a CO shift catalyst in a CO shift reactor which reforms carbon monoxide (CO) in gas based on a reaction formula below:
CO+H 2 O⇄CO 2 +H 2 +40.9 kJ/mol, comprising:

obtaining a complex oxide including titanium (Ti) and silicon (Si) as a support as a first process; and
after obtaining the complex oxide, supporting active ingredients including molybdenum (Mo) or iron (Fe) as a main component and nickel (Ni) or ruthenium (Ru) as an accessory component on the support of the complex oxide as a second process; and
after supporting the active ingredients on the support of the complex oxide, firing them at a high temperature from 550° C. to 800° C. to obtain the CO shift catalyst with a specific surface area thereof being reduced equal to or less than 118m 2 /g to prevent a carbon production reaction to thereby have a ratio of a CO conversion rate after a hundred-hour durability test to an initial CO conversion rate of 78% or more as a third process in a state wherein a water vapor adding ratio (H 2 O/CO) which defines an amount of vapor H 2 O supplied to the gas at a CO shift reactor inlet of the CO shift reactor satisfies that (H 2 O/CO) is equal to 1 which represents a state wherein the amount of vapor H 2 O supplied to the gas is small, wherein
the first process, the second process, and the third process are performed in this order.

2. The method of producing a CO shift catalyst according to claim 1 ,
wherein a support amount of the main component of the active ingredient is 0.1 to 25 percent by weight, and a support amount of the accessory component is 0.01 to 10 percent by weight.

3. A method for purifying gasified gas, comprising:
after smoke and dust in gasified gas obtained by a gasification furnace have been removed by a filter,
further removing halogen in the gasified gas by a wet scrubber apparatus after removing the smoke and the dust,
subsequently removing carbon dioxide and hydrogen sulfide in the gasified gas after removing the halogen; and
obtaining purified gas by performing the CO shift reaction for converting CO in the gasified gas after removing the carbon dioxide and the hydrogen sulfide into CO 2 by using the CO shift catalyst obtained by the method according to claim 1 .

Assignees

• Mitsubishi Heavy Ind Ltd
• Mitsubishi Heavy Ind Eng Ltd

Inventors

• Yonemura Masanao
• Yasutake Toshinobu
• Sawata Akihiro
• Seiki Yoshio
• Tanaka Yukio
• Higashino Koji
• Abe Hyota
• Yoshida Kaori

Classifications

• B01J35/40

  characterised by dimensions, e.g. grain size (in a colloidal state B01J35/23; crystallite size B01J35/77) · CPC title

• C01B2203/049

  the impurity being carbon · CPC title

• C01B2203/061

  Methanol production · CPC title

• B01J23/892

  Nickel and noble metals · CPC title

• C01B2203/0485

  the impurity being a sulfur compound · CPC title