Process and apparatus for a settler and first stage water wash in a caustic free kerosene sweetening reactor

Patent metadata

Field	Value
Publication number	US-10774274-B2
Application number	US-201815964482-A
Country	US
Kind code	B2
Filing date	Apr 27, 2018
Priority date	Apr 27, 2018
Publication date	Sep 15, 2020
Grant date	Sep 15, 2020

Abstract

The present invention relates to a combined reactor settler with the reactor. More specifically, the present invention relates to a combined reactor settler and reactor in a caustic free kerosene sweetening reactor which reduces equipment costs, operating costs, and plot space requirements.

First claim

The invention claimed is:

1. An apparatus, comprising:
a reactor vessel comprising a reaction section, a water wash and flail separation section, and a fluid permeable shield positioned between the reaction section and the water wash and separation section, wherein fluid passes from the reaction section to the water wash and separation section through said fluid permeable shield;
a catalyst bed supported on the fluid permeable shield;
a hydrocarbon inlet to the vessel located above the reaction section;
a water inlet to the vessel located in the water wash and separation section;
an alkaline outlet from the vessel located at the bottom of the vessel; and
a sweetened hydrocarbon outlet from the vessel located below said water inlet and above said alkaline outlet.

2. The apparatus of claim 1 , wherein an alkaline stream comprising dilute ammonia enters through the hydrocarbon inlet.

3. The apparatus of claim 1 , wherein the vessel operates at a temperature of about 32° C. to about 50° C.

4. The apparatus of claim 1 , wherein the water wash and separation section operates at a pressure of about 340 kPa to about 2100 kPa.

5. The apparatus of claim 1 , further comprising a second stage water wash column in fluid communication with the sweetened hydrocarbon outlet.

6. The apparatus of claim 1 , further comprising a sour water stripper in fluid communication with the alkaline outlet.

7. The apparatus of claim 1 , further comprising a level indicator controller in communication with the water wash and separation section and the alkaline outlet that controls a hydrocarbon aqueous interface by withdrawing spent water to a sour water stripper.

8. The apparatus of claim 1 , wherein the water inlet is in fluid communication with a water outlet of a second stage water wash section.

9. The apparatus of claim 1 , further comprising a baffle above the sweetened hydrocarbon outlet.

10. The apparatus of claim 1 , further comprising an air mixer upstream from the vessel.

11. The apparatus of claim 1 , wherein all of said fluid passing from the reaction section to the water wash and separation section passes through the fluid permeable shield.

12. The apparatus of claim 1 , further including a baffle positioned at a level between said water inlet and said sweetened hydrocarbon outlet.

13. The apparatus of claim 7 further comprising a control valve in communication with the level indicator controller.

14. The apparatus of claim 1 further comprising a distributor having nozzles directed away from the catalyst bed.

15. The apparatus of claim 1 further comprising a residual alkali removal unit in fluid communication with said sweetened hydrocarbon outlet.

Assignees

• Uop Llc

Inventors

• Wong Susanna Kiki
• Tertel Jonathan A

Classifications

• C10G2400/08

  Jet fuel · CPC title

• C10G2300/202

  Heteroatoms content, i.e. S, N, O, P · CPC title

• C10G2300/1051

  Kerosene having a boiling range of about 180 - 230 °C · CPC title

• C10G53/12 Primary

  including at least one alkaline treatment step · CPC title