A Thermosetting Epoxy Resin Composition for the Preparation of Outdoor Articles, and the Articles Obtained Therefrom
US-2018371153-A1 · Dec 27, 2018 · US
US10774244B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10774244-B2 |
| Application number | US-201615745530-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 19, 2016 |
| Priority date | Jul 17, 2015 |
| Publication date | Sep 15, 2020 |
| Grant date | Sep 15, 2020 |
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The present disclosure relates to insulation. Teachings thereof may be embodied in a solid insulation material, especially in tape form, the use thereof in a vacuum impregnation process and to an insulation system produced therewith, and also an electrical machine comprising the insulation system, especially for the medium- and high-voltage sector, namely for medium- and high-voltage machines, especially rotating electrical machines in the medium- and high-voltage sector, and to semifinished products for electrical switchgear. For example a solid insulation material with an anhydride-free impregnating agent may include: a carrier; a barrier material; a curing catalyst; and a tape adhesive. The curing catalyst and the tape adhesive are inert toward one another but react under the conditions of a vacuum impregnation process if combined with an anhydride-free impregnating agent having gelation times of 1 h to 15 h at impregnation temperature. The tape adhesive is free of oxirane groups and includes at least two free hydroxyl groups.
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What is claimed is: 1. An insulation system, the system comprising: a solid insulation material comprising: a carrier; a barrier material; a curing catalyst; and a tape adhesive; an anhydride-free impregnating agent; wherein the curing catalyst and the tape adhesive are inert toward one another at standard atmospheric conditions, but react under vacuum when combined with the impregnating agent in a vacuum impregnation process to form a mixture with gelation times of 1 h to 15 h at an impregnation temperature in a range between 20 degrees Celsius and 100 degrees Celsius; wherein the tape adhesive comprises a carbon-based organic compound with at least two free hydroxyl groups and free of oxirane groups; and; wherein the curing catalyst is selected from the group consisting of: cationic superacids and superacid salts. 2. The insulation system as claimed in claim 1 , wherein the tape adhesive within a temperature range from 60° C. to 70° C. shows a viscosity between 0.5 and 100 Pas. 3. The insulation system as claimed in claim 1 , wherein the tape adhesive does not melt or soften at a temperature below 100° C. 4. The insulation system of claim 1 , wherein the tape adhesive comprises tricyclodecanedimethanol. 5. The insulation system of claim 1 , wherein the tape adhesive comprises polyvinyl acetal. 6. The insulation system of claim 5 , wherein the polyvinyl acetal comprises the at least two free hydroxyl groups present as polyvinyl alcohol in an amount less than 35 mol %. 7. The insulation system as claimed in claim 1 , wherein the tape adhesive comprises at least one compound selected from the group consisting of ester polyols, polyester polyols, linear polyester polyols, branched polyester polyols, hydroxy-functional polyester polyols, hydroxy-functional dendritic polyester polyols, polyester polyols based on propionic acid or based on alkyl-substituted propionic acid, a polyester polyol based on a bis(hydroxyalkyl)propionic acid, a polyol based on 2,2-bis(hydroxymethyl)propionic acid. 8. The insulation system as claimed in claim 1 , further comprising a carrier comprising woven fabric, nonwoven fabric, or film. 9. The insulation system as claimed in claim 8 , comprising a perforated film. 10. The insulation system as claimed in claim 1 , comprising a particulate barrier material. 11. The insulation system as claimed in claim 10 , wherein the particulate barrier material comprises barrier material particles at least partly in platelet form. 12. The insulation system as claimed in claim 11 , wherein the particles of the barrier material have been coated. 13. The insulation system as claimed in claim 12 , wherein the coating comprises a metal oxide. 14. The insulation system as claimed in claim 12 , wherein the coating has been doped. 15. The insulation system as claimed in claim 1 , wherein the tape adhesive amounts to from 1% to 30% by weight of a total weight of the insulation material. 16. The insulation system as claimed in claim 1 , wherein the curing catalyst comprises less than 10% by weight of a total weight of the insulation material.
epoxy resins · CPC title
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