Photodegradation-resistant biodegradable films

Patent metadata

Field	Value
Publication number	US-10774197-B2
Application number	US-201314434165-A
Country	US
Kind code	B2
Filing date	Oct 9, 2013
Priority date	Oct 10, 2012
Publication date	Sep 15, 2020
Grant date	Sep 15, 2020

Abstract

This invention relates to biodegradable films characterised by high resistance to processes of the photodegradative type, mainly activated by the ultraviolet component of sunlight, which are particularly suitable for use in the mulch film sector. These films comprise a composition containing at least one polyphenol of plant origin.

First claim

The invention claimed is:

1. A film comprising a composition containing at least one thermoplastic polyester and 0.5-4% by weight of a mixture of polyphenols comprising silybin, silydianin, isosilybin and silycristin, wherein the thermoplastic polyester is an aliphatic-aromatic polyester and has a dicarboxylic component comprising at least one aromatic acid having multiple functional groups in an amount of between 30 and 90% in moles with respect to the total moles of the dicarboxylic component selected from dicarboxylic aromatic compounds of phthalic acid and their esters and heterocyclic dicarboxylic aromatic compounds and their esters and at least one aliphatic diacid selected from oxalic acid, malonic acid, succinic acid, glutaric acid, 2-methylglutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, undecandioic acid, dodecandioic acid and brassilic acid and an aliphatic diol component comprising at least 85% by moles with respect to the total moles of the diol component of butanediol.

2. The film according to claim 1 in which the mixture comprising silybin, silydianin, isosilybin and silycristin is obtained by extraction from milk thistle seeds.

3. The film according to claim 1 , in which the aromatic aliphatic polyester is selected from:
(A) polyesters comprising repeated units deriving from at least one aromatic acid of phthalic acid, at least one aliphatic diacid and at least one aliphatic diol having an aromatic units content of between 35-60% in moles with respect to the total moles of the dicarboxylic component; or
(B) polyesters comprising repeating units deriving from at least one heterocyclic dicarboxylic aromatic compound, at least one aliphatic diacid and at least one aliphatic diol, having an aromatic units content of between 50-85% in moles with respect to the total moles of the dicarboxylic component.

4. The film according to claim 1 , in which the composition comprises one or more polymers of synthetic or natural origin.

5. A method for mulching which comprises applying a film according to claim 1 to an area of soil.

6. A mulch film comprising the film according to claim 1 .

7. The film according to claim 1 , wherein the composition further comprises one or more polymers of natural origin in an amount between 5 and 50% by weight based upon the total weight of the composition.

8. The film according to claim 1 , wherein the composition comprises up to 30% by weight of polymers from a hydroxyacid with respect to the total weight of the composition.

Assignees

• Novamont Spa
• Consiglio Nazionale Ricerche
• Consiglio Naz Delle Richerche

Inventors

• Bastioli Catia
• Capuzzi Luigi
• Russo Claudio
• Martinelli Tommaso

Classifications

• C08L101/16

  the macromolecular compounds being biodegradable · CPC title

• C08J2300/16

  Biodegradable polymers · CPC title

• C08K5/13

  Phenols; Phenolates · CPC title

• C08L67/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds (C08L67/06 takes precedence) · CPC title

• C08K5/15 Primary

  Heterocyclic compounds having oxygen in the ring · CPC title