Ion-conducting membrane production method and production device

Patent metadata

Field	Value
Publication number	US-10774190-B2
Application number	US-201716074145-A
Country	US
Kind code	B2
Filing date	Feb 1, 2017
Priority date	Feb 15, 2016
Publication date	Sep 15, 2020
Grant date	Sep 15, 2020

Abstract

A method of producing an ion-conducting membrane containing a polymer having an ionic group, involves multiple liquid treatment steps in which a precursor membrane is brought into contact with an acid treatment solution or an alkali treatment solution, the precursor membrane containing a polymer in a state in which the aforementioned ionic group forms a salt with an impurity ion, wherein the liquid treatment time in the second and subsequent liquid treatment steps of the multiple liquid treatment steps is shorter than the liquid treatment time in the initial liquid treatment step.

First claim

The invention claimed is:

1. A method of producing an ion-conducting membrane containing a polymer having an ionic group comprising:
a plurality of times of liquid treatment steps of bringing a precursor membrane that contains a polymer containing a salt of the ionic group with an impurity ion into contact with an acid treatment solution or an alkali treatment solution,
wherein, in the plurality of times of liquid treatment steps, a liquid treatment time in each of second and subsequent liquid treatment steps is shorter than a liquid treatment time in a first liquid treatment step.

2. The production method according to claim 1 , wherein the liquid treatment time in each of the second and subsequent liquid treatment steps is two-thirds or less of the liquid treatment time in the first liquid treatment step.

3. A production device that produces an ion-conducting membrane containing a polymer having an ionic group comprising:
a plurality of liquid treatment tanks that brings a precursor membrane containing a polymer having the ionic group capable of forming a salt with an impurity ion into contact with an acid treatment solution or an alkali treatment solution,
wherein, in the plurality of liquid treatment tanks, second and subsequent liquid treatment tanks are smaller than a first liquid treatment tank.

4. The production device according to claim 3 , wherein the second and subsequent liquid treatment tanks each have an internal volume two-thirds or less of an internal volume of the first liquid treatment tank.

5. The production device according to claim 3 , further comprising a liquid treatment section for a precursor membrane including a liquid treatment tank and a liquid supply tank adjacent to the liquid treatment tank, the device having a mechanism that circulates a treatment solution sent from the liquid supply tank to the liquid treatment tank and overflowed from the liquid treatment tank to the liquid supply tank, and a mechanism that supplies a new treatment solution.

6. The production device according to claim 5 , wherein the liquid treatment section includes a plurality of liquid treatment tanks, and liquid supply tanks equal in number with the liquid treatment tanks.

7. The production device according to claim 5 , wherein a direction in which the treatment solution overflows from the liquid treatment tank is a direction parallel to a surface of the precursor membrane at the time the precursor membrane intersects with the surface of the treatment solution.

8. The production device according to claim 3 , further comprising, following the liquid treatment section, a washing section in which an ion-conducting membrane obtained by liquid treatment of the precursor membrane is washed, a drying section in which the washed ion-conducting membrane is dried, and a winding section in which the dried ion-conducting membrane is wound up.

9. The production device according to claim 8 , wherein the washing section has a mechanism that subjects the ion-conducting membrane to immersion washing in deionized water in multiple stages, and a mechanism that subjects the ion-conducting membrane to shower washing in multiple stages.

10. The production device according to claim 8 , wherein the drying section has a mechanism including a decompression device, and a suction conveyor roll of which at least a roll surface is made from a porous material and connects to the decompression device.

11. The production device according to claim 8 , wherein the winding section has a mechanism that winds up the ion-conducting membrane with a winding tension being controlled to be constant.

12. The production device according to claim 5 , comprising a mechanism that individually controls a liquid sending speed from the liquid supply tank to the liquid treatment tank.

13. The production device according to claim 4 , further comprising a liquid treatment section for a precursor membrane including a liquid treatment tank and a liquid supply tank adjacent to the liquid treatment tank, the device having a mechanism that circulates a treatment solution sent from the liquid supply tank to the liquid treatment tank and overflowed from the liquid treatment tank to the liquid supply tank, and a mechanism that supplies a new treatment solution.

14. The production device according to claim 6 , wherein a direction in which the treatment solution overflows from the liquid treatment tank is a direction parallel to a surface of the precursor membrane at the time the precursor membrane intersects with the surface of the treatment solution.

15. The production device according to claim 4 , further comprising, following the liquid treatment section, a washing section in which an ion-conducting membrane obtained by liquid treatment of the precursor membrane is washed, a drying section in which the washed ion-conducting membrane is dried, and a winding section in which the dried ion-conducting membrane is wound up.

16. The production device according to claim 5 , further comprising, following the liquid treatment section, a washing section in which an ion-conducting membrane obtained by liquid treatment of the precursor membrane is washed, a drying section in which the washed ion-conducting membrane is dried, and a winding section in which the dried ion-conducting membrane is wound up.

17. The production device according to claim 6 , further comprising, following the liquid treatment section, a washing section in which an ion-conducting membrane obtained by liquid treatment of the precursor membrane is washed, a drying section in which the washed ion-conducting membrane is dried, and a winding section in which the dried ion-conducting membrane is wound up.

18. The production device according to claim 7 , further comprising, following the liquid treatment section, a washing section in which an ion-conducting membrane obtained by liquid treatment of the precursor membrane is washed, a drying section in which the washed ion-conducting membrane is dried, and a winding section in which the dried ion-conducting membrane is wound up.

19. The production device according to claim 9 , wherein the drying section has a mechanism including a decompression device, and a suction conveyor roll of which at least a roll surface is made from a porous material and connects to the decompression device.

Assignees

• Toray Industries

Inventors

• Fukuda Seiji
• Yabuuchi Yuko

Classifications

• C08J5/2237 Primary

  containing fluorine · CPC title

• Y02P70/50

  Manufacturing or production processes characterised by the final manufactured product · CPC title

• Y02E60/50

  Fuel cells · CPC title

• B01J47/12

  characterised by the use of ion-exchange material in the form of ribbons, filaments, fibres or sheets, e.g. membranes (electrodialysis or electro-osmosis B01D61/42) · CPC title

• H01M8/1086

  After-treatment of the membrane other than by polymerisation · CPC title