Spark plasma sintered polycrystalline diamond compact

Patent metadata

Field	Value
Publication number	US-10773303-B2
Application number	US-201515742455-A
Country	US
Kind code	B2
Filing date	Aug 5, 2015
Priority date	Aug 5, 2015
Publication date	Sep 15, 2020
Grant date	Sep 15, 2020

Abstract

The present disclosure relates to polycrystalline diamond covalently bonded to a substrate by spark plasma sintering and methods of covalently bonding polycrystalline diamond and a substrate. Spark plasma sintering produces plasma from a reactant gas found in the pores in the polycrystalline diamond and, optionally, also the substrate. The plasma forms carbide structures in the pores, which covalently bond to the substrate.

First claim

What is claimed is:

1. A method of covalently bonding polycrystalline diamond and a substrate via a cemented carbide, the method comprising:
placing polycrystalline diamond (PCD) having pores adjacent a cemented carbide substrate with a reactant gas including a carbide-forming metal in gas form in an assembly;
and applying a voltage to the assembly sufficient to heat the reactant gas to a temperature of 1500° C. or less at which the reactant gas forms a plasma, which plasma forms carbide structures in at least a portion of the PCD pores, wherein the carbide structures are covalently bonded to the cemented carbide substrate,
wherein the PCD, substrate, reactant gas, or any combination thereof have a rate of temperature increase while the voltage is applied of at least 300° C./minute.

2. The method of claim 1 , wherein the PCD comprises a leached portion in which less than 2% of the volume is occupied by a diamond sintering aid.

3. The method of claim 1 , wherein the carbide-forming metal in gas form comprises a metal salt.

4. The method of claim 3 , wherein the metal salt comprises a metal chloride.

5. The method of claim 1 , wherein the carbide structures comprise zirconium carbide (ZrC), titanium carbide (TiC), silicon carbide (SiC), vanadium carbide (VC), chromium carbide (CrC), boron carbide (BC), tungsten carbide (WC), tantalum carbide (TaC), manganese carbide (MnC), nickel carbide (NiC), molybdenum carbide (MoC), halfnium carbide (HfC), rhenium carbide (ReC), and any combinations thereof.

6. The method of claim 1 , wherein plasma comprises metal ions.

7. The method of claim 1 , wherein the reactant gas comprises hydrogen gas.

8. The method of claim 7 , wherein the plasma comprises atomic hydrogen, a proton, or a combination thereof.

9. The method of claim 1 , wherein the reactant gas further comprises a hydrocarbon gas.

10. The method of claim 9 , wherein the hydrocarbon gas comprises methane, acetone, methanol, or any combinations thereof.

11. The method of claim 9 , wherein the plasma comprises methyl, carbon dimmers, or a combination thereof.

12. The method of claim 1 , wherein the voltage is supplied by a continuous direct current or a pulsed direct current.

13. The method of claim 1 , wherein the voltage is supplied for 20 minutes or less.

14. The method of claim 1 , wherein diamond bonds, carbide structures, or both are formed in at least 25% of the pores of the PCD.

15. The method of claim 1 , wherein the temperature is 1200° C. or less.

16. The method of claim 1 , wherein the temperature is 700° C. or less.

17. The method of claim 1 , further comprising, prior to applying the voltage:
placing the assembly in a sealed, electrically conductive sintering can;
placing the sintering can between presses and in electrical contact with electrically conductive plates in a vacuum chamber;
evacuating the vacuum chamber; and
applying pressure to the sintering can with the presses sufficient to drive the reactant gas into at least a portion of the pores of the PCD.

18. The method of claim 1 , further comprising:
dissolving a portion of the substrate using an acid to introduce pores near a surface of the substrate placed adjacent the PCD, in which the carbide structures are later covalently bonded.

19. The method of claim 1 , wherein the substrate further comprises carbide grains adjacent the PCD to which the carbide structures are covalently bonded.

20. A method of covalently bonding polycrystalline diamond and a substrate via a cemented carbide, the method comprising:
placing polycrystalline diamond (PCD) having pores and comprising a leached portion in which less than 2% of the volume is occupied by a diamond sintering aid adjacent a cemented carbide substrate with a reactant gas including a carbide-forming metal in gas form and a hydrogen gas or a hydrocarbon gas in an assembly;
and applying a voltage to the assembly sufficient to heat the reactant gas to a temperature of 1500° C. or less at which the reactant gas forms a plasma, which plasma forms carbide structures in at least a portion of the PCD pores, wherein the carbide structures are covalently bonded to the cemented carbide substrate,
wherein the PCD, substrate, reactant gas, or any combination thereof have a rate of temperature increase while the voltage is applied of at least 300° C./minute.

Assignees

• Halliburton Energy Services Inc

Inventors

• Liang Qi
• Atkins William Brian

Classifications

• C22C29/06

  based on carbides, but not containing other metal compounds · CPC title

• B22F3/11

  Making porous workpieces or articles · CPC title

• C22C26/00

  Alloys containing diamond {or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes} · CPC title

• B22F2999/00

  Aspects linked to processes or compositions used in powder metallurgy · CPC title

• B22F7/06

  of composite workpieces or articles from parts, e.g. to form tipped tools {(B22F7/002 takes precedence)} · CPC title