Transition group metals for the capture of radioactive xenon

Patent metadata

Field	Value
Publication number	US-10773203-B2
Application number	US-201715716955-A
Country	US
Kind code	B2
Filing date	Sep 27, 2017
Priority date	Sep 27, 2017
Publication date	Sep 15, 2020
Grant date	Sep 15, 2020

Abstract

A xenon capture system that reduces the concentration of xenon in a carrier gas is disclosed. An example xenon capture system includes a carrier gas with a first concentration of xenon that flows through an intake into a chamber. Within the chamber is a reaction area that has at least one peripheral sidewall. The reaction area operates at a predetermined temperature, flow rate, and low pressure. Within the reaction area is at least one xenon capture mechanism that is at least partially formed of a transition metal. When the carrier gas is exposed to the xenon capture mechanism, the xenon capture mechanism adsorbs xenon from the carrier gas. The carrier gas, with a second concentration of xenon, exits the chamber through the exhaust outlet.

First claim

The invention claimed is:

1. A xenon capture system for reducing the concentration of xenon in a carrier gas, the system comprising:
a carrier gas, the carrier gas having a first concentration of xenon;
a chamber, the chamber having an intake for receiving the carrier gas and an exhaust outlet for discharging the carrier gas;
a reaction area defined by at least one peripheral sidewall, the reaction area having a temperature between approximately −77° C. and 25° C., flow rate and pressure, the intake and the reaction area operatively linked with each other, the exhaust outlet and the reaction area operatively linked with each other; and
at least xenon capture mechanism formed from at least one elemental transition metal, the at least one xenon capture mechanism disposed within the reaction area such that when carrier gas is exposed to the at least one xenon capture mechanism, the at least one xenon capture mechanism adsorbs xenon from the carrier gas such that the carrier gas has a second concentration of xenon at the exhaust outlet.

2. The xenon capture system of claim 1 , wherein said at least one xenon capture mechanism is a metal sponge.

3. The xenon capture system of claim 1 , wherein said at least one xenon capture mechanism is at least one metal pellet.

4. The xenon capture system of claim 1 , wherein said at least one xenon capture mechanism is a metal mesh.

5. The xenon capture system of claim 1 , wherein said xenon capture mechanism releases xenon at a predetermined time.

6. The xenon capture system of claim 1 , wherein two or more xenon capture mechanisms are arranged in series.

7. The xenon capture system of claim 1 , wherein two or more xenon capture mechanisms are arranged in tandem.

8. The xenon capture system of claim 1 , wherein said predetermined pressure is less than 50 psi.

9. The xenon capture system of claim 1 , wherein said predetermined flow rate is between 0.25 L/min and 2 L/min.

10. The xenon capture system of claim 1 , wherein said xenon capture system operates in temperatures swing adsorption.

11. The xenon capture system of claim 1 , wherein said xenon capture system operates in low pressure swing adsorption.

12. The xenon capture system of claim 1 , wherein said xenon capture system operates in temperature swing adsorption, flow rate adsorption, and pressure swing adsorption.

13. The xenon capture system of claim 1 , wherein said carrier gas is inert.

14. The xenon capture system of claim 1 , wherein said carrier gas is argon, helium, or nitrogen.

15. The xenon capture system of claim 1 , wherein said exhaust feeds into a holding tank.

16. The xenon capture system of claim 1 , additionally comprising a controller configured to manage the flow of the carrier gas through the system in a predetermined manner.

17. The xenon capture system of claim 1 , wherein said at least one xenon capture mechanism is formed from elemental nickel (Ni) or zinc (Zn) or copper (Cu) or aluminum (Al) or magnesium (Mg) or a combination of one or more of elemental nickel, zinc, copper, aluminum, or magnesium.

18. The xenon capture system of claim 1 , wherein said at least one xenon capture mechanism is formed from elemental nickel (Ni) or zinc (Zn) or copper (Cu) or aluminum (Al) or magnesium (Mg) or an alloy of one or more of elemental nickel, zinc, copper, aluminum, or magnesium.

Assignees

• Us Energy
• Us Dept Energy

Inventors

• Riddle Catherine
• Scates Dawn M
• Garn Troy G
• Watrous Matthew G

Classifications

• B01D53/0462 Primary

  Temperature swing adsorption · CPC title

• B01D2256/18

  Noble gases · CPC title

• B01D53/02

  by adsorption, e.g. preparative gas chromatography {(solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01)} · CPC title

• B01J20/0244

  Compounds of Zn · CPC title

• B01J20/0248

  Compounds of B, Al, Ga, In, Tl (B01J20/08 takes precedence) · CPC title