Fuel cell module with hydrodesulfurizer and preheating

Patent metadata

Field	Value
Publication number	US-10770741-B2
Application number	US-201715628783-A
Country	US
Kind code	B2
Filing date	Jun 21, 2017
Priority date	Aug 31, 2016
Publication date	Sep 8, 2020
Grant date	Sep 8, 2020

Abstract

A fuel cell module according to the present embodiment includes a hydrodesulfurizer, a cell stack, an exhaust gas channel portion, and an air-preheating channel portion. The hydrodesulfurizer is configured to desulfurize fuel gas using a hydrodesulfurization catalyst. A reformer is configured to generate a hydrogen-containing gas. The cell stack is constituted by stacking a plurality of fuel cells and is configured to generate electric power. The exhaust gas channel portion is configured to discharge the hydrogen-containing gas, and discharge exhaust gas that is generated by the combustion of the oxygen-containing gas. The air-preheating channel portion is an air-preheating channel portion that is disposed so as to be adjacent to the exhaust gas channel portion and that is configured to preheat the oxygen-containing gas through heat exchange with the exhaust gas channel portion. The air-preheating channel portion is disposed between the hydrodesulfurizer and the cell stack.

First claim

The invention claimed is:

1. A fuel cell module, comprising:
a hydrodesulfurizer configured to desulfurize fuel gas with a hydrodesulfurization catalyst;
a reformer configured to generate hydrogen-containing gas using the desulfurized fuel gas;
a cell stack constituted by stacking a plurality of fuel cells, the cell stack being configured to generate electric power using the hydrogen-containing gas and an oxygen-containing gas;
an exhaust gas channel portion configured to discharge the hydrogen-containing gas that is not consumed by the cell stack, and discharge exhaust gas that is generated by the combustion of the oxygen-containing gas;
an air-preheating channel portion that is disposed so as to be adjacent to the exhaust gas channel portion and that is configured to preheat the oxygen-containing gas through heat exchange with the exhaust gas channel portion, the air-preheating channel portion being disposed between the hydrodesulfurizer and the cell stack;
wherein the air-preheating channel portion includes a first air-preheating channel portion extending from the lower portion to the upper portion of the fuel cell module; and
an insulator configured to be arranged so as to be in contact with the hydrodesulfurizer and the first air-preheating channel portion between the hydrodesulfurizer and the first air-preheating channel portion, wherein the hydrodesulfurizer is disposed on one side of the air-reheating channel portion in contact via the insulator with the first air-preheating channel portion, and the exhaust gas channel portion is disposed on the other side of the first air-preheating channel portion in contact via the first air-preheating channel portion and the insulator with the hydrodesulfurizer.

2. The fuel cell module according to claim 1 , wherein at least part of the air-preheating channel portion has a planar hollowed shape, covering one side of the cell stack via the exhaust gas channel portion, and has a homogenization channel to homogenize a distribution of heat conducted to the hydrodesulfurizer.

3. The fuel cell module according to claim 2 , wherein the homogenization channel is configured such that an amount of the oxygen-containing gas streaming along a central portion of the cell stack is larger than an amount of the oxygen-containing gas streaming along end portions of the cell stack.

4. The fuel cell module according to claim 2 , wherein the air-preheating channel portion includes an inlet portion through which the oxygen-containing gas streams in from outside of the fuel cell module, and includes a meandering channel that meanders toward an upper portion.

5. The fuel cell module according to claim 1 , further comprising:
a first throttling device disposed in a desulfurized fuel gas pipe that communicates with the hydrodesulfurizer and the reformer; and
a first filter disposed between the first throttling device of the desulfurized fuel gas pipe and the hydrodesulfurizer.

6. The fuel cell module according to claim 5 , further comprising:
a fuel blower configured to supply the fuel gas to the hydrodesulfurizer through the desulfurized fuel gas pipe; and
a controller configured to control the fuel blower.

7. The fuel cell module according to claim 1 , wherein the fuel gas is supplied to or discharged from the hydrodesulfurizer through a section that is not filled with the hydrodesulfurization catalyst.

8. The fuel cell module according to claim 1 , further comprising:
a water supply pipe configured to supply water to the reformer; and
a desulfurized fuel gas pipe configured to communicate between the hydrodesulfurizer and the reformer, the desulfurized fuel gas pipe merging with the water supply pipe in an inner portion of the reformer,
wherein the desulfurized fuel gas pipe has a size small enough to block water by means of capillary force, and water is supplied from the water supply pipe to the desulfurized fuel gas pipe to block the desulfurized fuel.

9. The fuel cell module according to claim 8 , further comprising a water partition plate including a hole and disposed upstream of the inner portion of the reformer.

10. The fuel cell module according to claim 1 , further comprising:
a fuel gas pipe configured to supply the fuel gas to the hydrodesulfurizer;
a recycling pipe configured to supply part of the hydrogen-containing gas generated by the reformer to the hydrodesulfurizer, the recycling pipe merging with the fuel gas pipe in the reformer;
a drain trap configured to discharge condensed water in the recycling pipe;
a second throttling device disposed in the recycling pipe, downstream of the reformer;
a second filter disposed in the recycling pipe, upstream of the second throttling device;
a third throttling device disposed in the fuel gas pipe, upstream of the reformer; and
a third filter disposed in the fuel gas pipe, upstream of the third throttling device.

11. The fuel cell module according to claim 1 , further comprising:
a heater disposed between the air-preheating channel portion and the hydrodesulfurizer, which is adjusted based on at least one or more of thermometers in the hydrodesulfurizer.

Assignees

• Toshiba Energy Systems & Solutions Corp
• Toshiba Kk

Inventors

• Matsuno Takeshi

Classifications

• H01M8/04014

  Heat exchange using gaseous fluids; Heat exchange by combustion of reactants · CPC title

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title

• H01M8/0618

  Reforming processes, e.g. autothermal, partial oxidation or steam reforming · CPC title

• Y02E60/50

  Fuel cells · CPC title

• H01M8/0202

  Collectors; Separators, e.g. bipolar separators; Interconnectors · CPC title