Rare-earth permanent magnet and method for manufacturing rare-earth permanent magnet

Patent metadata

Field	Value
Publication number	US-10770207-B2
Application number	US-201314233286-A
Country	US
Kind code	B2
Filing date	Mar 8, 2013
Priority date	Mar 12, 2012
Publication date	Sep 8, 2020
Grant date	Sep 8, 2020

Abstract

There are provided a rare-earth permanent magnet and a manufacturing method of a rare-earth permanent magnet capable of preventing deterioration of magnet properties. In the method, magnet material is milled into magnet powder. Next, a mixture 12 is prepared by mixing the magnet powder and a binder, and the mixture 12 is formed into a sheet-like shape to obtain a green sheet 14 . Thereafter, magnetic field orientation is performed to the green sheet 14 , which is then held for several hours in a non-oxidizing atmosphere at a pressure higher than normal atmospheric pressure, at 200 through 900 degrees Celsius for calcination. Thereafter, the calcined green sheet 14 is sintered at a sintering temperature. Thereby a permanent magnet 1 is manufactured.

First claim

The invention claimed is:

1. A manufacturing method of a rare-earth permanent magnet comprising, in order, steps of:
milling magnet material into magnet powder;
mixing the magnet powder with a binder to obtain a mixture;
forming the mixture into a formed body;
calcining the formed body in a non-oxidizing atmosphere, wherein the calcining comprises a calcination process during which the formed body is held at a temperature in a range of 200 degrees Celsius to 900 degrees Celsius and the on-oxidizing atmosphere is pressurized at 0.5 MPa or higher so that a residual oxygen content contained in the formed body after sintering is 5000 ppm or less; and
holding the calcined formed body at a sintering temperature so as to sinter the calcined formed body,
wherein the binder consists of a resin that is made of a polymer or a copolymer consisting essentially of one or more kinds of monomers expressed with a general formula (1):

wherein R 1 and R 2 represent a hydrogen atom, a lower alkyl group, a phenyl group or a vinyl group, and
wherein the calcination process has a duration of several hours.

2. The manufacturing method of a rare-earth permanent magnet according to claim 1 , wherein, in the step of calcining the formed body, the binder is decomposed and removed from the formed body.

3. The manufacturing method of a rare-earth permanent magnet according to claim 1 , wherein, in the step of calcining the formed body, the formed body is held for at least the duration of the calcination process in a hydrogen atmosphere or a mixed gas atmosphere of hydrogen and inert gas.

4. The manufacturing method of a rare-earth permanent magnet according to claim 1 , wherein, in the step of forming the mixture, the mixture is thermally melted and formed into the formed body.

5. The manufacturing method of a rare-earth permanent magnet according to claim 1 , wherein the binder comprises: polyisobutylene; or a styrene-isoprene copolymer.

6. The manufacturing method of a rare-earth permanent magnet according to claim 1 , wherein, in the step of milling magnet material, the magnet material is wet-milled in an organic solvent.

7. The manufacturing method of a rare-earth permanent magnet according to claim 6 , wherein, in the step of calcining the formed body, an organic compound included in the organic solvent thermally decomposes and carbon therein is removed, while the binder decomposes and is removed from the formed body.

8. The manufacturing method of a rare-earth permanent magnet according to claim 1 , wherein the duration of the calcination process is five hours.

9. The manufacturing method of a rare-earth permanent magnet according to claim 1 , wherein the calcining further comprises:
increasing a pressure of the non-oxidizing atmosphere from standard atmospheric pressure to at least 0.5 MPa for the calcination process.

10. A manufacturing method of a rare-earth permanent magnet comprising, in order, steps of:
milling magnet material into magnet powder;
mixing the magnet powder with a binder to obtain a mixture;
forming the mixture into a formed body;
calcining the formed body in a non-oxidizing atmosphere, wherein during the calcining, the formed body is held at a temperature in a range of 200 degrees Celsius to 900 degrees Celsius and the non-oxidizing atmosphere is always pressurized at 0.5 MPa to 15 MPa so that a residual oxygen content contained in the formed body after sintering is 5000 ppm or less; and
holding the calcined formed body at a sintering temperature so as to sinter the calcined formed body,
wherein the binder consists of a resin that is made of a polymer or a copolymer consisting essentially of one or more kinds of monomers expressed with a general formula (1):

wherein R 1 and R 2 represent a hydrogen atom, a lower alkyl group, a phenyl group or a vinyl group.

11. The manufacturing method of a rare-earth permanent magnet according to claim 10 , wherein the formed body is held at the temperature in the range of 200 degrees Celsius to 900 degrees Celsius and the non-oxidizing atmosphere is always pressurized at 0.5 MPa to 15 MPa for a duration of several hours.

12. The manufacturing method of a rare-earth permanent magnet according to claim 10 , wherein the calcining further comprises:
increasing a pressure of the non-oxidizing atmosphere from standard atmospheric pressure to 0.5 MPa to 15 MPa.

13. A manufacturing method of a rare-earth permanent magnet comprising, in order, steps of:
milling magnet material into magnet powder;
mixing the magnet powder with a binder to obtain a mixture;
forming the mixture into a formed body;
calcining the formed body in a non-oxidizing atmosphere, wherein during the calcining, the non-oxidizing atmosphere is pressurized to 0.5 MPa to 15 MPa while the formed body is concurrently held at a temperature in a range of 200 degrees Celsius to 900 degrees Celsius for several hours so that a residual oxygen content contained in the formed body after sintering is 5000 ppm or less; and
holding the calcined formed body at a sintering temperature so as to sinter the calcined formed body,
wherein the binder consists of a resin that is made of a polymer or a copolymer consisting essentially of one or more kinds of monomers expressed with a general formula (1):

wherein R 1 and R 2 represent a hydrogen atom, a lower alkyl group, a phenyl group or a vinyl group.

14. The manufacturing method of a rare-earth permanent magnet according to claim 13 , wherein the non-oxidizing atmosphere is pressurized to 0.5 MPa to 15 MPa and the formed body is concurrently held at the temperature in the range of 200 degrees Celsius to 900 degrees Celsius for a duration of five hours.

15. The manufacturing method of a rare-earth permanent magnet according to claim 13 , wherein the calcining further comprises:
increasing a pressure of the non-oxidizing atmosphere from standard atmospheric pressure to 0.5 MPa to 15 MPa.

Assignees

• Nitto Denko Corp

Inventors

• Kume Katsuya
• Okuno Toshiaki
• Ozeki Izumi
• Omure Tomohiro
• Ozaki Takashi
• Taihaku Keisuke
• Yamamoto Takashi

Classifications

• B22F1/10

  Metallic powder containing lubricating or binding agents; Metallic powder containing organic material · CPC title

• B22F3/18 Primary

  by using pressure rollers · CPC title

• H01F1/0536 Primary

  sintered · CPC title

• B22F2301/355

  Rare Earth - Fe intermetallic alloys · CPC title

• H01F1/086

  sintered · CPC title