Method for fractionating a stream of cracked gas to obtain an ethylene-rich cut and a stream of fuel, and related installation

Patent metadata

Field	Value
Publication number	US-10767924-B2
Application number	US-201013503697-A
Country	US
Kind code	B2
Filing date	Oct 26, 2010
Priority date	Oct 27, 2009
Publication date	Sep 8, 2020
Grant date	Sep 8, 2020

Abstract

This method includes introducing a downstream stream ( 140 ) of cracked gas from a downstream heat exchanger ( 58 ) in a downstream separator ( 60 ) and recovering, at the head of the downstream separator ( 60 ), a high-pressure fuel gas stream ( 144 ).
The method includes the passage of the stream ( 144 ) of fuel through the downstream exchanger ( 58 ) and an intermediate exchanger ( 50, 54 ) to form a reheated high-pressure fuel stream ( 146 ), the expansion of the reheated high-pressure fuel stream ( 146 ) in at least a first dynamic expander ( 68 ) and the passage of the partially expanded fuel stream ( 148 ) from the intermediate exchanger ( 50, 54 ) in a second dynamic expander ( 70 ) to form an expanded fuel stream ( 152 ).
The expanded fuel stream ( 152 ) from the second dynamic expander ( 70 ) is reheated in the downstream heat exchanger ( 58 ) and in the intermediate heat exchanger ( 50, 54 ).

First claim

What is claimed is:

1. A method for fractionating a stream of cracked gas from a hydrocarbon pyrolysis installation to obtain an ethylene-rich cut and a stream of fuel having a low C 2 + hydrocarbon content, the method comprising the following steps:
cooling and introducing in at least one compressor a raw cracked gas stream to form a compressed cracked gas stream;
forming a reboiling fraction from the compressed cracked gas stream;
introducing the reboiling fraction into a reboiling heat exchanger of a fractionating column;
partial condensing of the reboiling fraction in the reboiling heat exchanger;
introducing a stream foiined from the reboiling fraction into a first upstream separating drum to form an upstream stream of raw cracked gas;
upstream cooling of the upstream stream of raw cracked gas and partial condensation of the upstream stream of raw cracked gas by at least partial heat exchange with a coolant fluid circulating in a first external refrigeration cycle and separation of an upstream liquid in an upstream drum to form an intermediate stream of cracked gas pre-cooled to a first temperature below −63° C.;
intermediate cooling of the intermediate stream of cracked gas and partial condensation of the inteiiiiediate stream of cracked gas in at least one intermediate heat exchanger and separation of an intermediate liquid in at least one intermediate separation drum to form a downstream stream of cracked gas cooled to a second temperature lower than the first temperature;
downstream cooling of the downstream stream of cracked gas and partial condensation of the downstream stream of cracked gas in a downstream heat exchanger to a third temperature lower than the second temperature;
introducing the partially condensed downstream stream of cracked gas obtained from the downstream heat exchanger in a downstream separator;
recovering, at the head of the downstream separator, a high-pressure gas stream of fuel, with a low C 2 + hydrocarbon content, and recovering, at the bottom of the downstream separator, a downstream liquid, with a high C 2 + hydrocarbon content;
passing the high-pressure fuel stream through the downstream exchanger and the at least one intermediate exchanger to form a reheated high-pressure fuel stream;
expansion of the reheated high-pressure fuel stream in at least a first dynamic expander to obtain a partially expanded fuel stream;
heating the partially expanded fuel stream through the downstream exchanger and the at least one intermediate exchanger;
passing the partially expanded flow of fuel from the at least one intermediate exchanger into a second dynamic expander to form an expanded stream of fuel;
reheating the expanded fuel stream from the second dynamic expander in the downstream heat exchanger and in the at least one intermediate heat exchanger;
compressing the reheated expanded fuel stream in at least one fuel compressor coupled to at least one turbo-expander of one of the first dynamic expander and the second dynamic expander to form the stream of fuel having a low C 2 + hydrocarbon content,
wherein the intermediate cooling of the intermediate stream of cracked gas to the second temperature is carried out exclusively by heat exchange with the high pressure fuel stream, by heat exchange with the partially expanded fuel stream, by heat exchange with the expanded fuel stream, by heat exchange with a first fraction of the intermediate liquid recovered in the intermediate cooling step and the downstream liquid recovered in the downstream cooling step from the downstream separator, the heat exchanges being carried out in the intermediate heat exchanger, without heat exchange with an external coolant fluid circulating in a refrigeration cycle,
wherein a processing step comprises the introduction of at least said upstream liquid, and a second fraction of said intermediate liquid in a fractionating column and the production in the fractionating column of a stream with a high ethylene content intended to form the ethylene-rich cut.

2. The method according to claim 1 , further comprising recovery of the downstream liquid and reheating thereof through the downstream heat exchanger, and the intermediate heat exchanger,
the downstream liquid being sub-cooled in the downstream heat exchanger before it is reheated in the downstream heat exchanger, then in the intermediate heat exchanger.

3. The method according to claim 1 , wherein the first fraction of the intermediate liquid is sub-cooled before being reintroduced into the downstream heat exchanger, then in the intermediate heat exchanger.

4. The method according to claim 1 , wherein the first fraction of the intermediate liquid and the downstream liquid evaporates during passage in the downstream heat exchanger, and passage in the intermediate heat exchanger to provide the intermediate cooling of the intermediate stream of cracked gas, to form a gas recirculation flow, the gas recirculation flow being mixed with the stream of raw cracked gas, before the passage of the raw cracked gas in the at least one compressor.

5. The method according to claim 1 , wherein the entirety of the overhead stream from the fractionating column is conveyed through the upstream heat exchanger.

6. The method according to claim 1 , wherein the first dynamic expander comprises at least one dynamic turbo expander, and the second dynamic expander comprises at least one dynamic turbo-expander.

7. The method according to claim 1 , wherein the molar content of hydrogen in the high-pressure fuel stream is greater than 75%.

8. The method according to claim 1 , wherein the first temperature is below −63° C., the second temperature is below −85° C., and the third temperature is below −120° C.

9. The method according to claim 1 , wherein the entirety of the overhead stream from the fractionating column is conveyed through the upstream heat exchanger, before being mixed with the raw cracked gas, without a fraction of the overhead stream being condensed to be sent to the fractionating column as reflux.

Assignees

• Laugier Jean Paul
• Simon Yvon
• Technip France

Inventors

• Laugier Jean-Paul
• Simon Yvon

Classifications

• F16D23/12

  Mechanical clutch-actuating mechanisms arranged outside the clutch as such (specific for combined clutches F16D21/00; mechanisms specific for synchronisation F16D23/02) · CPC title

• F16D21/00

  Systems comprising a plurality of actuated clutches (for synchronisation F16D23/04) · CPC title

• F25J3/0219 Primary

  Refinery gas, cracking gas, coke oven gas, gaseous mixtures containing aliphatic unsaturated CnHm or gaseous mixtures of undefined nature · CPC title

• F25J2270/12

  External refrigeration with liquid vaporising loop · CPC title

• C10G2400/20

  C2-C4 olefins · CPC title