Purification process

Patent metadata

Field	Value
Publication number	US-10767243-B2
Application number	US-201715826280-A
Country	US
Kind code	B2
Filing date	Nov 29, 2017
Priority date	Aug 4, 2010
Publication date	Sep 8, 2020
Grant date	Sep 8, 2020

Abstract

A process for purifying Mo-99 from an acidic solution obtained by dissolving an irradiated solid target comprising uranium in an acidic medium, or from an acidic solution comprising uranium and which has previously been irradiated in a nuclear reactor, or from an acidic solution comprising uranium and which has been used as reactor fuel in a homogeneous reactor, the process comprising contacting the acidic solution with an adsorbent comprising a zirconium oxide, zirconium hydroxide, zirconium alkoxide, zirconium halide and/or zirconium oxide halide, and eluting the Mo-99 from the adsorbent using a solution of a strong base, the eluate then being subjected to a subsequent purification process involving an alkaline-based Mo-99 chromatographic recovery step on an anion exchange material. Also provided is apparatus for carrying out the process.

First claim

The invention claimed is:

1. An apparatus for carrying out a process for purifying Mo-99, the apparatus comprising:
a column or vessel containing an adsorbent comprising a zirconium oxide, zirconium hydroxide, zirconium alkoxide, zirconium halide and/or zirconium oxide halide; a source of a solution of a strong base, the source of strong base solution being arranged in fluid communication at an inlet of the column or vessel containing the adsorbent;
a column or vessel containing an anion exchange material on which Mo-99 can be quantitatively adsorbed and arranged in downstream fluid communication with the column or vessel containing the adsorbent;
a source of a solution of an acid, the source of acid solution being arranged in fluid communication at an inlet of the column or vessel containing the anion exchange material; and
a column or vessel containing MnO 2 material and arranged in downstream fluid communication with the column or vessel containing the anion exchange material;
a source of a solution of sulfuric acid containing thiocyanide ions and a reducing agent, the source of sulfuric acid solution containing thiocyanide ions and a reducing agent being arranged in fluid communication at an inlet of the column or vessel containing the MnO 2 material;
and a column or vessel containing an ion exchange material comprising iminodiacetate groups and arranged in downstream fluid communication with the column or vessel containing the MnO 2 material.

2. An apparatus of claim 1 , wherein the adsorbent further comprises a titanium oxide and/or silicon oxide.

3. An apparatus of claim 1 , wherein the zirconium compound is present at a concentration of from 5 to 70 mol % of the adsorbent.

4. An apparatus of claim 1 , wherein the adsorbent is in the form of pellets.

Assignees

• Curium Us Llc

Inventors

• Barbosa Luis A M M

Classifications

• G21G1/001 Primary

  Recovery of specific isotopes from irradiated targets · CPC title

• G21G2001/0036

  Molybdenum · CPC title

• C22B34/34 Primary

  Obtaining molybdenum {(treatment or purification of solutions by adsorption on solids C22B3/24, by liquid-liquid extraction C22B3/26, by ion-exchange extraction C22B3/42; preparation of molybdenum involving liquid-liquid extraction, adsorption or ion-exchange C01G39/003)} · CPC title