Method for purifying phenol

Patent metadata

Field	Value
Publication number	US-10766843-B2
Application number	US-201615742980-A
Country	US
Kind code	B2
Filing date	Oct 11, 2016
Priority date	Oct 22, 2015
Publication date	Sep 8, 2020
Grant date	Sep 8, 2020

Abstract

Disclosed is a method for purifying phenol, by which the loss of a heat source is minimized, the amount used of steam is decreased, and efficiency of energy consumed in a process may be maximized. The method for purifying phenol includes a step of passing impurities including phenol, acetone and hydrocarbon, which are prepared using cumene as a raw material, via a plurality of distillation columns one by one, and performing azeotropic distillation, wherein the ratio of phenol and water at the uppermost end of the distillation column where the azeotropic distillation is performed, is from 60:40 to 65:35, for the optimized separation of the hydrocarbon.

First claim

The invention claimed is:

1. A method for purifying phenol, comprising a step of passing first impurities comprising phenol, acetone and hydrocarbon, which are prepared using cumene as a raw material, through a plurality of distillation columns sequentially and performing azeotropic distillation,
wherein the plurality of distillation columns comprise:
a crude acetone column (CAC) for receiving the first impurities comprising phenol, acetone and hydrocarbon and for separating and purifying acetone;
a crude phenol column (CPC) for receiving second impurities comprising phenol and hydrocarbon discharged from a bottom part of the crude acetone column, for discharging light impurities comprising phenol and light hydrocarbon from a top part, and for discharging heavy impurities including heavy hydrocarbon and phenol from a bottom part;
a hydrocarbon removal column (HRC) for receiving the light impurities comprising phenol and light hydrocarbon and performing azeotropic distillation, for discharging third impurities comprising phenol from a bottom part, and for discharging fourth impurities comprising light hydrocarbon from a top part; and
a phenol finishing column (PFC) for receiving the third impurities comprising phenol from the HRC and for productization, and
wherein a weight ratio of phenol and water at an uppermost part of the top part of the HRC in which the azeotropic distillation is performed is from 60:40 to 65:35, so that separation of the hydrocarbon can be optimized.

2. The method for purifying phenol of claim 1 , wherein a phenolic steam generated during the azeotropic distillation is recovered and reused in a purification process.

3. The method for purifying phenol of claim 2 , wherein the recovered phenolic steam preheats a feed of the crude acetone column (CPC).

4. The method for purifying phenol of claim 2 , wherein the phenolic steam is recovered in the hydrocarbon removal column (HRC) after being condensed in a condenser.

5. The method for purifying phenol of claim 1 , wherein if an operation pressure of the distillation column is increased, a logarithmic mean temperature difference of a side reboiler is increased, and a quantity of heat recovered is increased.

6. The method for purifying phenol of claim 5 , wherein the distillation column of which operation pressure is increased, is at least one distillation column selected from the group consisting of the crude phenol column (CPC) and the phenol finishing column (PFC).

7. The method for purifying phenol of claim 1 , further comprising a step of transporting the heavy impurities comprising heavy hydrocarbon and phenol discharged from the bottom part of the crude phenol column (CPC) to a heavies removal column (RC), refluxing the phenol to the crude phenol column (CPC) by high pressure distillation in the RC, and discharging and discarding remaining heavy impurities.

8. The method for purifying phenol of claim 1 , further comprising a step of passing the light hydrocarbon discharged from the bottom part of the hydrocarbon removal column (HRC) through a resin bed for converting into heavy hydrocarbon and being adsorbed on the resin bed.

9. The method for purifying phenol of claim 1 , wherein the phenol finishing column (PFC) refluxes a portion of a phenolic stream to the crude phenol column (CPC) for recovering unpurified phenol.

Assignees

• Lg Chemical Ltd

Inventors

• Kim Sung-Kyun
• Lee Sung-Kyu
• Choo Yeon-Uk
• Shin Joon-Ho
• Lee Ha-Na
• Kim Tae-Woo

Classifications

• B01D3/007

  Energy recuperation; Heat pumps · CPC title

• B01D3/36

  Azeotropic distillation · CPC title

• C07C37/78 Primary

  by azeotropic distillation · CPC title

• B01D3/143

  by two or more of a fractionation, separation or rectification step · CPC title

• B01D3/06

  Flash distillation · CPC title