Nanocellulose foam stabilizing additive

Patent metadata

Field	Value
Publication number	US-10766813-B2
Application number	US-201616062584-A
Country	US
Kind code	B2
Filing date	Feb 8, 2016
Priority date	Feb 8, 2016
Publication date	Sep 8, 2020
Grant date	Sep 8, 2020

Abstract

A variety of systems, methods and compositions are disclosed, including, in one method, providing a foamed cement composition comprising a hydraulic cement, water, a foaming surfactant, a gas, and a nanocellulose foam stabilizing additive; placing the foamed cement composition in a selected location; and allowing the foamed cement composition to set.

First claim

What is claimed is:

1. A method of cementing comprising:
providing a foamed cement composition comprising:
a hydraulic cement,
water,
a foaming surfactant,
a gas, and
a nanocellulose foam stabilizing additive;

placing the foamed cement composition in a selected location; and
allowing the foamed cement composition to set,
wherein the nanocellulose foam stabilizing additive comprises a nanofibril cellulose.

2. The method of claim 1 wherein the foamed cement composition has a density in a range of from about 4 pounds per gallon to about 16 pounds per gallon, and wherein the water is present in an amount sufficient to form a pumpable slurry.

3. The method of claim 1 wherein the hydraulic cement comprises at least one hydraulic cement selected from the group consisting of Portland cement, pozzolana cement, gypsum cement, high-alumina-content cement, slag cement, silica cement, and any combination thereof.

4. The method of claim 1 wherein the nanocellulose foam stabilizing additive comprises nanofibril cellulose derived from at least one nanocellulose fiber selected from the group consisting of bacteria, wood, bleached kraft pulp, bleached sulfite pulp, sugar beet pulp, wheat straw, soy hulls, sisal, bagasse, palm trees, ramie, carrots, luffa cylindrica and any combination thereof.

5. The method of claim 1 wherein the nanocellulose foam stabilizing additive is present in the cement composition in an amount of about 0.01% to about 10% by weight of the cement.

6. The method of claim 1 wherein the nanocellulose foam stabilizing additive comprises individual nanofibrils with a diameter of about 1,000 nanometers or less.

7. The method of claim 1 wherein the nanocellulose foam stabilizing additive comprises individual nanofibrils with a length from about 35 nanometers to about 10,000 nanometers.

8. The method of claim 1 wherein the nanocellulose foam stabilizing additive comprises individual nanofibrils with a diameter of about 100 nanometers or less and a length of about 1,000 nanometers or greater.

9. The method of claim 1 wherein the nanocellulose foam stabilizing additive is pretreated.

10. The method of claim 1 wherein the selected location is a wellbore annulus in a primary cementing operation.

11. The method of claim 1 wherein the selected location is in a wellbore in a subterranean formation.

12. A foamed cement composition comprising:
a hydraulic cement,
water,
a nanocellulose foam stabilizing additive,
a foaming surfactant, and
a gas;
wherein the nanocellulose foam stabilizing additive comprises a nanofibril cellulose.

13. The foamed cement composition of claim 12 wherein the foamed cement composition has a density in a range of from about 4 pounds per gallon to about 16 pounds per gallon, and wherein the water is present in an amount sufficient to form a pumpable slurry.

14. The foamed cement composition of claim 12 wherein the hydraulic cement comprises at least one hydraulic cement selected from the group consisting of Portland cement, pozzolana cement, gypsum cement, high-alumina-content cement, slag cement, silica cement, and any combination thereof.

15. The foamed cement composition of claim 12 wherein the nanocellulose foam stabilizing additive comprises nanofibril cellulose derived from at least one nanocellulose fiber selected from the group consisting of bacteria, wood, bleached kraft pulp, bleached sulfite pulp, sugar beet pulp, wheat straw, soy hulls, sisal, bagasse, palm trees, ramie, carrots, luffa cylindrica and any combination thereof.

16. The foamed cement composition of claim 12 wherein the nanocellulose foam stabilizing additive is present in the cement composition in an amount of about 0.01% to about 10% by weight of the cement.

17. The foamed cement composition of claim 12 wherein the nanocellulose foam stabilizing additive comprises individual nanofibrils with a diameter of about 1,000 nanometers or less.

18. The foamed cement composition of claim 12 wherein the nanocellulose foam stabilizing additive comprises individual nanofibrils with a diameter of about 100 nanometers or less and a length of about 1,000 nanometers or greater.

19. A cementing system comprising:
a cement composition comprising:
a hydraulic cement,
water,
a nanocellulose foam stabilizing additive, wherein the nanocellulose foam stabilizing additive comprises a nanofibril cellulose,
a foaming surfactant, and
a gas;

mixing equipment capable of mixing the cement composition; and
pumping equipment capable of delivering the cement composition into a wellbore.

20. The cementing system of claim 19 wherein the nanofibril cellulose is derived from at least one nanocellulose fiber selected from the group consisting of bacteria, wood, bleached kraft pulp, bleached sulfite pulp, sugar beet pulp, wheat straw, soy hulls, sisal, bagasse, palm trees, ramie, carrots, luffa cylindrica and any combination thereof.

Assignees

• Halliburton Energy Services Inc

Inventors

• Pearl Jr William Cecil
• Lewis Samuel J
• Karcher Jeffery Dwane

Classifications

• Y02W30/91

  Use of waste materials as fillers for mortars or concrete · CPC title

• C04B18/241

  Paper, e.g. waste paper; Paper pulp · CPC title

• C04B18/24

  Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper {, cork} · CPC title

• C09K8/467

  containing additives for specific purposes · CPC title

• C09K8/46 Primary

  containing inorganic binders, e.g. Portland cement · CPC title