Helium recovery from gaseous streams

Patent metadata

Field	Value
Publication number	US-10765995-B2
Application number	US-201815990555-A
Country	US
Kind code	B2
Filing date	May 25, 2018
Priority date	Jun 8, 2017
Publication date	Sep 8, 2020
Grant date	Sep 8, 2020

Abstract

Recovering helium from a gaseous stream includes contacting an acid gas removal membrane with a gaseous stream to yield a permeate stream and a residual stream, removing a majority of the acid gas from the residual stream to yield a first acid gas stream and a helium depleted clean gas stream, removing a majority of the acid gas from the permeate stream to yield a second acid gas stream and a helium rich stream, and removing helium from the helium rich stream to yield a helium product stream and a helium depleted stream. A helium removal system for removing helium from a gaseous stream including hydrocarbon gas, acid gas, and helium includes a first processing zone including a first acid gas removal unit, a second processing zone including a second acid gas removal unit, a third processing zone, and a helium purification unit.

First claim

What is claimed is:

1. A helium recovery method comprising:
contacting an acid gas removal membrane with a gaseous stream comprising hydrocarbon gas, acid gas, and helium, thereby separating the gaseous stream into a permeate stream and a residual stream, each comprising a portion of the hydrocarbon gas, a portion of the acid gas, and a portion of the helium, wherein a concentration of the helium in the permeate stream is greater than a concentration of the helium in the residual stream, and wherein a concentration of the acid gas in the permeate stream is greater than a concentration of the acid gas in the residual stream;
removing a majority of the acid gas from the residual stream to yield a first acid gas stream and a helium depleted clean gas stream, wherein a concentration of acid gas in the first acid gas stream is greater than a concentration of acid gas in the helium depleted clean gas stream;
removing a majority of the acid gas from the permeate stream to yield a second acid gas stream and a helium rich stream, wherein a concentration of acid gas in the second acid gas stream is greater than a concentration of acid gas in the helium rich stream; and
removing helium from the helium rich stream to yield a helium product stream and a helium depleted stream, wherein a concentration of helium in the helium product stream is greater than a concentration of helium in the helium depleted stream.

2. The method of claim 1 , wherein the acid gas comprises at least one of carbon dioxide and hydrogen sulfide;
a concentration of hydrogen sulfide in the helium depleted clean gas stream is 4 ppmv or less; and
a concentration of carbon dioxide in the helium depleted clean gas stream is 2 mol % or less.

3. The method of claim 1 , wherein removing the majority of the acid gas from the residual stream to yield the first acid gas stream comprises contacting a second acid gas removal membrane with the residual stream or treating the residual stream via liquid-based absorption process, a distillation process, an adsorption process, or a molecular centrifuge process;
wherein the adsorption process is a pressure swing adsorption process or a temperature swing adsorption process;
wherein the liquid-based absorption process is an amine absorption process, a hot potassium absorption process, a mixed solvent absorption process, or a physical solvent absorption process; and
wherein the first acid gas stream comprises hydrogen sulfide, and the method comprises treating the first acid gas stream to yield sulfur and a tail gas and removing hydrogen sulfide from the tail gas.

4. The method of claim 1 , wherein removing the majority of the acid gas from the permeate stream to yield the second acid gas stream and the helium rich stream comprises contacting a third acid gas removal membrane with the permeate stream.

5. The method of claim 1 , comprising purifying the helium product stream to yield a purified helium product stream by contacting the helium product stream with a molecular sieve, subjecting the helium product stream to an adsorption process or a molecular centrifuge process, or distilling the helium product stream;
wherein the adsorption process is a pressure swing adsorption process or a temperature swing adsorption process;
wherein purifying the helium product stream comprises removing hydrocarbon gas and nitrogen gas from the helium product stream and rectifying the helium in the helium product stream.

6. The method of claim 1 , comprising recovering sulfur and water from the gaseous stream.

7. A helium removal system for removing helium from a gaseous stream comprising hydrocarbon gas, acid gas, and helium, the helium removal system comprising:
a first processing zone comprising a first acid gas removal unit configured to separate a gaseous stream into a residual stream and a permeate stream, each comprising a portion of the hydrocarbon gas, a portion of the acid gas, and a portion of the helium, wherein a concentration of the helium in the permeate stream is greater than a concentration of the helium in the residual stream, and wherein a concentration of the acid gas in the permeate stream is greater than a concentration of the acid gas in the residual stream;
a second processing zone fluidly coupled to the first processing zone and comprising a second acid gas removal unit configured to receive the residual stream from the first processing zone and to remove a majority of the acid gas from the residual stream, thereby yielding a first acid gas rich stream and a helium depleted clean gas stream, wherein a concentration of acid gas in the first acid gas rich stream is greater than concentration of acid gas in the helium depleted clean gas stream; and
a third processing zone fluidly coupled to the first processing zone and comprising:
a third acid gas removal unit configured to receive the permeate stream from the first processing zone and to remove a majority of the acid gas from the permeate stream, thereby yielding a second acid gas rich stream and a helium rich stream, wherein a concentration of acid gas in the second acid gas rich stream is greater than a concentration of acid gas in the helium rich stream; and
a helium purification unit fluidly coupled to the third acid gas removal unit and configured to receive the helium rich stream and to recover a majority of the helium from the helium rich stream, thereby yielding a helium depleted stream and a helium product stream, wherein a concentration of helium in the helium product stream is greater than a concentration of helium in the helium depleted stream.

8. The system of claim 7 , wherein the first acid gas removal unit comprises an acid gas removal membrane, and the permeance of the acid gas removal membrane for acid gas and helium is greater than the permeance of the acid gas removal membrane for hydrocarbon gas and nitrogen gas.

9. The system of claim 7 , wherein the second acid gas removal unit and the third acid gas removal unit each independently comprises a liquid-based absorption process unit, a molecular centrifuge unit, an adsorption process unit, or a distillation process.

10. The system of claim 9 , wherein the liquid-based absorption process unit comprises an amine absorption process unit, a hot potassium absorption process unit, a mixed solvent absorption process unit, or a physical solvent absorption process.

11. The system of claim 9 , wherein the adsorption process unit comprises a pressure swing adsorption process unit or temperature swing adsorption unit.

12. The system of claim 7 , comprising a sulfur removal unit fluidly coupled to the third acid gas removal unit and configured to receive the second acid gas rich stream.

13. The system of claim 12 , wherein the sulfur removal unit comprises removal unit comprises a unit configured to remove hydrogen sulfide via catalytic conversion and amine; and a unit configured to oxidize hydrogen sulfide to yield sulfur dioxide and to react hydrogen sulfide and sulfur dioxide to yield sulfur.

14. The system of claim 7 , wherein the third processing zone comprises a dehydration unit fluidly coupled to the third acid gas removal unit and the helium purification unit and configured to remove water from the helium rich stream, thereby yielding a dehydrated helium rich stream and a water stream.

15. The system of claim 14 , wherein the helium purification unit is configured to receive the dehydrated helium rich stream from the dehydration unit.

16. The system of claim 7 , wherein the helium purification unit comprises a helium absorption unit, a helium adsorption unit, a molecular centrifuge

Assignees

• Saudi Arabian Oil Co

Inventors

• Hamad Feras
• Rithauddeen Megat A
• Abang Taib
• Vaidya Milind
• Duval Sebastien A

Classifications

• F25J2220/66

  Separating acid gases, e.g. CO2, SO2, H2S or RSH · CPC title

• F25J2205/80

  using membrane, i.e. including a permeation step · CPC title

• F25J2205/50

  using absorption, i.e. with selective solvents or lean oil, heavier CnHm and including generally a regeneration step for the solvent or lean oil · CPC title

• F25J3/029

  of helium · CPC title

• F25J3/0209

  Natural gas or substitute natural gas · CPC title