Conical heater assembly for a gas chromatography column

Patent metadata

Field	Value
Publication number	US-10764964-B2
Application number	US-201514877729-A
Country	US
Kind code	B2
Filing date	Oct 7, 2015
Priority date	Oct 7, 2015
Publication date	Sep 1, 2020
Grant date	Sep 1, 2020

Abstract

A heating apparatus for a gas chromatography column is described. The GC column heating apparatus includes a conical heater assembly comprising a heating element between an inner layer and an outer layer. The apparatus can also include optionally an outer cowl and/or an inner cowl surrounding the conical heater assembly. The conical heater assembly rapidly increases the temperature of the column by conductive heating. The selection of shape (in particular, the cone angle of a conical heater) and materials allows the GC column to adapt to expansion that occurs upon heating. A gas chromatography (GC) column heating and cooling apparatus is also described, in which the heater and outer cowl define a flowpath through which a cooling fluid can pass and cool the GC column.

First claim

What is claimed is:

1. A heating apparatus for a gas chromatography (GC) column, comprising:
a conical heater assembly comprising a heating element between an inner layer and an outer layer wherein the inner layer and the outer layer are conical, wherein the conical heater assembly is adapted for a GC column to move along the conical heater assembly in response to differing thermal expansions of the conical heater assembly and the GC column, and
a cooling system, wherein the cooling system comprises a fan or pressurized gas, and the cooling system is configured to blow cooling gas over the conical heater assembly.

2. The apparatus of claim 1 , wherein the conical heater assembly further comprises
a first interior layer disposed between the heating element and the inner layer, or
a second interior layer disposed between the heating element and the outer layer, or
both a first interior layer disposed between the heating element and the inner layer, and a second interior layer disposed between the heating element and the outer layer.

3. The apparatus of claim 2 , wherein the first interior layer and the second interior layer of the conical heater assembly form a unitary coating that encases the heating element.

4. The apparatus of claim 1 , further comprising an outer cowl surrounding the outer layer of the conical heater assembly, wherein the outer cowl is arranged to provide a first flowpath between the outer layer of the conical heater assembly and the outer cowl.

5. The apparatus of claim 4 , further comprising a cooling system, wherein the first flowpath between the outer cowl and the heater assembly is fluidly connected with the cooling system.

6. The apparatus of claim 1 , further comprising an inner cowl that is surrounded by and arranged to provide a second flowpath between the inner layer of the conical heater assembly and the inner cowl.

7. The apparatus of claim 6 , further comprising a cooling system, wherein the second flowpath between the inner cowl and the heater assembly is fluidly connected with the cooling system.

8. The apparatus of claim 1 , wherein the outer layer of the conical heater assembly comprises one or more of metals, metal alloys, silicon, quartz, diamond, silicon carbide, boron nitride, aluminum nitride, or alumina.

9. A gas chromatography apparatus comprising
a conical heater assembly comprising a heating element between an inner layer and an outer layer wherein the inner layer and the outer layer are conical and wherein the outer layer has an inner surface proximate to the heating element and an outer surface distal to the heating element and the inner layer has an outer surface proximate to the heating element and an inner surface distal to the heating element; and
a gas chromatography (GC) column wound around the outer surface of the outer layer of the conical heater assembly, wherein the column is in contact with the outer layer of the heater assembly or
a gas chromatography (GC) column wound on the inner surface of the inner layer of the conical heater assembly, wherein the column is in contact with the inner layer of the conical heater assembly,
wherein the GC column and the conical heater assembly are adapted for the GC column to move along the conical heater assembly in response to differing thermal expansions of the conical heater assembly and the GC column.

10. The gas chromatography apparatus of claim 9 , wherein the conical heater assembly is frustoconical.

11. The gas chromatography apparatus of claim 9 , wherein the outer layer of the conical heater assembly comprises one or more of metal, metal alloys, silica, quartz, diamond, silicon carbide, boron nitride, aluminum nitride, or alumina, and the GC column comprises fused silica, glass, or metal.

12. The gas chromatography apparatus of claim 9 , wherein the conical heater assembly has a cone angle θ, and
the conical heater assembly and the column are made from different materials, whereby a coefficient of friction μ exists for the different materials;
wherein the coefficient of friction and the cone angle are selected so that
N sin (θ/2) is greater than (mg+T y +μN cos (θ/2)) when adding heat,

where N is a normal force from conical heater assembly; T y is a vertical tensile force from the column; and mg is a gravitational force acting vertically on the column.

13. The gas chromatography apparatus of claim 12 , wherein the apparatus has an operational temperature range, and N sin (θ/2) is greater than (mg+T y +μN cos (θ/2)) when adding heat throughout the temperature range.

14. The gas chromatography apparatus of claim 9 , wherein the GC column has a length from about 1 m to about 105 m.

15. The gas chromatography apparatus of claim 9 , wherein the conical heater assembly further comprises a first interior layer and a second interior layer, and the first and second interior layers form a unitary coating that encases the heating element.

16. The gas chromatography apparatus of claim 9 , further comprising an outer cowl surrounding the outer layer of the conical heater assembly, and/or an inner cowl surrounding the inner layer of the conical heater assembly.

17. The gas chromatography apparatus of claim 9 , further comprising a cooling system configured to blow cooling gas over the conical heater assembly.

Assignees

• Agilent Technologies Inc

Inventors

• Harrison Thomas
• Traudt Sammye Elizabeth
• Wilson William H

Classifications

• G01N30/30 Primary

  of temperature · CPC title

• G01N30/6052

  body · CPC title

• G01N30/54

  Temperature · CPC title

• G01N30/60 Primary

  Construction of the column · CPC title

• G01N2030/3007

  same temperature for whole column · CPC title