Chemical method to create high stability heterogeneous carbon-bonded materials

Patent metadata

Field	Value
Publication number	US-10763537-B1
Application number	US-201715625103-A
Country	US
Kind code	B1
Filing date	Jun 16, 2017
Priority date	Oct 13, 2016
Publication date	Sep 1, 2020
Grant date	Sep 1, 2020

Abstract

The disclosure provides a method a method for generating a heterogeneous carbon-bonded material using an activated carbon support a solution comprising a material precursor and a chemical agent. The material precursor is typically a salt such as SnCl2, and the chemical agent is a substance which thermally decomposes to generate reducing gases. The mixture is heated in an inert, nonreactive atmosphere to generate the reducing gases and remove surface groups from the carbon support, allowing material such as metal from the material precursor to nucleate and directly bond to the sites. The method typically utilizes high specific surface area carbon and may produce a plurality of metal particles having an average diameter of less than about 20 nm dispersed on and strongly bonded to the underlying carbon support.

First claim

What is claimed is:

1. A method of generating a heterogeneous carbon-bonded material comprising:
oxidizing a carbonaceous material by contacting the carbonaceous material and an oxidizing agent for a time sufficient to generate chemisorption of oxygen on the carbonaceous material, thereby generating an activated material, where the carbonaceous material comprises a carbon support;
generating a mixture comprising a precursor solution and the activated material, where the precursor solution comprises a solvent and a material precursor and a chemical agent as solutes, and where the chemical agent produces a reducing gas upon thermal decomposition, where the reducing gas removes surface groups from a surface of the activated material to expose metal nucleation sites on the surface that are exposed to the precursor solution due to hydrophilic conditions at carbon sites of the carbonaceous material, and where the reducing gas comprises at least one of CO, H x , NH x , or mixtures thereof, where x is greater than or equal to 1;
evaporating some portion of the solvent within the precursor solution by heating the mixture to a first temperature in an inert atmosphere, where the first temperature is less than a decomposition temperature of the material precursor and less than a decomposition temperature of the chemical agent, thereby generating a precursor mix;
generating a reactive gas and a metal by heating the precursor mix to a second temperature in an unreactive atmosphere, where the second temperature is greater than the decomposition temperature of the chemical agent, greater than the decomposition temperature of the metal precursor, and less than a combustion temperature of the carbonaceous material;
adjusting an amount of the material precursor, an amount of the chemical agent, an amount of the solvent, and the specific surface area of the carbonaceous material to minimize a mean diameter of particles of the metal from the material precursor to a mean diameter of less than 5 nm; and
contacting the reactive gas and the activated material to form the heterogeneous carbon-bonded material that comprises the particles of the metal having the mean diameter of less than 5 nm, where the heterogeneous carbon-bonded material comprises carbon from the carbonaceous material and the particles of the metal that are directly bonded at the metal nucleation sites.

2. The method of claim 1 , where oxidizing the carbonaceous material comprises heating the carbonaceous material in an atmosphere comprising oxygen to a temperature of at least 250° C. for the time sufficient to generate chemisorption of oxygen on the carbonaceous material, thereby generating the activated material.

3. The method of claim 2 , where the solvent is water, and where the first temperature is greater than 100° C.

4. The method of claim 3 , where carbon comprises greater than 80 weight percent of the carbonaceous material.

5. The method of claim 4 , where the carbonaceous material has a specific surface area of at least 20 m 2 /g and a total pore volume of at least 0.3 cm 3 /g.

6. The method of claim 5 , where the material precursor is a salt.

7. The method of claim 5 , where the metal comprising the material precursor comprises at least one of tin, silicon, or germanium.

8. The method of claim 7 , where the particles comprises at least one of tin, silicon, or germanium, and the method further comprising:
generating a second mixture where the second mixture comprises the heterogeneous carbon-bonded material and a binder; and
covering a substrate surface of a conducting substrate with the second mixture where the conducting substrate has an electrical conductivity greater than 10 3 S/cm.

9. The method of claim 5 , where the material precursor comprises an anion selected from the group consisting of chloride, acetate, formate, nitrate, chloride, sulfate, oxy-chloride, phosphate, or mixtures thereof.

10. The method of claim 5 , where the mixture comprising the material precursor and the activated material has a ratio of moles material precursor to specific surface area of activated material of at least 1.4(10 −5 ) mol/m 2 .

11. The method of claim 5 , where a molar ratio of the chemical agent to the material precursor is greater than one.

12. The method of claim 11 , where the chemical agent comprises a compound comprising NH z where z is greater than or equal to 1.

13. The method of claim 12 , where the decomposition temperature of the chemical agent and the decomposition temperature of the material precursor is from about 400° C. to about 1200° C.

14. A method of generating a heterogeneous carbon-bonded material comprising:
heating a carbonaceous material in an atmosphere comprising oxygen to a temperature of at least 250° C. for a time sufficient to generate chemisorption of oxygen on the carbonaceous material, where carbon comprises at least 50 weight percent of the carbonaceous material and where the carbonaceous material comprises a carbon support and has a specific surface area of at least 20 m 2 /gram, thereby generating an activated material;
generating a mixture comprising an aqueous precursor solution and the activated material, where the aqueous precursor solution comprises water as a solvent and a material precursor and a chemical agent as solutes, and where the material precursor comprises a metal, and where the chemical agent produces a reducing gas upon thermal decomposition, where the reducing gas removes surface groups from a surface of the activated material to expose metal nucleation sites on the surface that are exposed to the precursor solution due to hydrophilic conditions at carbon sites of the carbonaceous material, and where the reducing gas comprises at least one of CO, H x , NH x , or mixtures thereof, where x is greater than or equal to 1, and where a decomposition temperature of the chemical agent and a decomposition temperature of the metal precursor is from about 400° C. to about 1200° C.;
evaporating some portion of the solvent within the precursor solution by heating the mixture to a first temperature in an inert atmosphere, where the first temperature is greater than 100° C. and less than a decomposition temperature of the material precursor and less than a decomposition temperature of the chemical agent, thereby generating a precursor mix;
generating a reactive gas and a metal by heating the precursor mix to a second temperature in an unreactive atmosphere, where the second temperature is greater than the decomposition temperature of the chemical agent, greater than the decomposition temperature of the material precursor, and less than a combustion temperature of the carbonaceous material;
adjusting an amount of the material precursor, an amount of the chemical agent, an amount of the solvent, and the specific surface area of the carbonaceous material to minimize a mean diameter of particles of the metal from the material precursor to a mean diameter of less than 5 nm; and
contacting the reactive gas and the activated material to form the heterogeneous carbon-bonded material that comprises the particles of the metal having the mean diameter of less than 5 nm, where the heterogeneous carbon-bonded material comprises carbon from the carbonaceous material and the particles of the metal that are directly bonded at the metal nucleation sites.

15. The method of claim 14 , where the metal comprising the material precursor comprises at least one of tin, silicon, or germanium.

16. The method of claim 15 , where the mixture comprising the material precursor and the activated material has a ratio of moles material precur

Assignees

• Us Gov Sec Navy

Inventors

• Phillips Jonathan
• Luhrs Claudia C

Classifications

• H01M4/587

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• H01M4/0404

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• H01M4/1393

  of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M4/133

  Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• Y02E60/10

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