Aqueous based blend composition and method of producing the same

Patent metadata

Field	Value
Publication number	US-10759958-B2
Application number	US-201314404669-A
Country	US
Kind code	B2
Filing date	May 16, 2013
Priority date	Jun 19, 2012
Publication date	Sep 1, 2020
Grant date	Sep 1, 2020

Abstract

An aqueous based blend composition including (a) an aqueous polyolefin dispersion comprising the melt blending product of one or more base polymers and one or more stabilizing agents in the presence of water and optionally one or more neutralizing agents, having an average volume particle size diameter from 400 to 1500 nm, and a pH from 8 to 11; and (b) from 0.1 to 50 percent by weight based on the solid content of the dispersion one or more crosslinking agents is provided.

First claim

We claim:

1. An aqueous based blend composition comprising:
an aqueous polyolefin dispersion comprising the melt blending product of one or more base polymers comprising one or more polyolefins and one or more stabilizing agents in the presence of water and optionally one or more neutralizing agents, wherein the polyolefin dispersion has an average volume particle size diameter in the range of from 400 to 1500 nm, and a pH range from 8 to 11; and
one or more crosslinking agents selected from the group consisting of phenol-formaldehyde resins, hydroxyalkylamide resins, amino-formaldehyde resins; epoxy group containing resins, and combinations thereof, wherein said crosslinking agents comprise from 0.1 to 50 percent by weight based on the solid content of the dispersion;
an acrylic emulsion comprising two or more acrylic emulsions with different glass transition temperatures wherein the difference between the two or more glass transition temperatures is at least 10° C.; and
wherein said aqueous based blend composition has a solid content in the range of from 15 to 70 percent by weight of solids, based on the weight of the aqueous based blend composition, wherein said solid content of said blend composition comprises up to 99.9 percent by weight of the one or more base polymers, based on the weight of the solid content of the aqueous based blend composition, and a pH in the range of from 8 to 11.

2. A film obtained from the aqueous based blend composition of claim 1 .

3. The film of claim 2 , wherein said film has a thickness in the range of from 1 to 20 μm.

4. A multilayer film comprising one or more films according to claim 2 .

5. A container device comprising a substrate and the film of claim 2 associated with at least one surface of said substrate.

6. The aqueous based blend composition of claim 1 , wherein said crosslinking agent is hydroxylalkylamide.

7. The aqueous based blend composition of claim 1 , further comprising one or more binder compositions selected from the group consisting of acrylic latex, vinyl acrylic latex, styrene acrylic latex, and any combination thereof.

8. A process for producing an aqueous based blend composition comprising:
selecting an aqueous polyolefin dispersion comprising the melt blending product of one or more base polymers comprising one or more polyolefins and one or more stabilizing agents in the presence of water and optionally one or more neutralizing agents, wherein the polyolefin dispersion has an average volume particle size diameter in the range of from 400 to 1500 nm, and a pH range from 8 to 11; and
selecting one or more crosslinking agents selected from the group consisting of phenol-formaldehyde resins, hydroxyalkylamide resins, amino-formaldehyde resins; epoxy group containing resins, and combinations thereof, wherein said crosslinking agents comprise from 0.1 to 50 percent by weight based on the solid content of the dispersion;
selecting an acrylic emulsion comprising two or more acrylic emulsions with different glass transition temperatures wherein the difference between the two or more glass transition temperatures is at least 10° C.;
contacting said aqueous polyolefin dispersion and said one or more crosslinking agents and said acrylic emulsion to produce said aqueous based blend composition;
wherein said aqueous based blend composition has a solid content in the range of from 15 to 70 percent by weight of solids, based on the weight of the aqueous based blend composition, wherein said solid content of said blend composition comprises up to 99.9 percent by weight of the one or more base polymers, based on the weight of the solid content of the aqueous based blend composition and a pH in the range of from 8 to 11.

Assignees

• Dow Global Technologies Llc
• Rohm & Haas

Inventors

• Lindenmuth Denise
• Gruver Joceyln
• Hermes Ann R
• Drumright Ray E

Classifications

• C09J123/10

  Homopolymers or copolymers of propene · CPC title

• C08L23/12

  Polypropene · CPC title

• C09D123/00

  Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers · CPC title

• C09D7/65 Primary

  macromolecular (C09D7/41-C09D7/48 take precedence) · CPC title

• C08J5/18

  Manufacture of films or sheets · CPC title