Resin composition and molded body

Patent metadata

Field	Value
Publication number	US-10759935-B2
Application number	US-201716080188-A
Country	US
Kind code	B2
Filing date	Mar 6, 2017
Priority date	Mar 11, 2016
Publication date	Sep 1, 2020
Grant date	Sep 1, 2020

Abstract

Provided is a molded body of a resin composition, which has improved easy wiping-off properties and scratch resistance. This resin composition contains (1) a thermoplastic resin and (2) a fluorine-containing copolymer; and the fluorine-containing copolymer (2) is a copolymer which comprises (a) a repeating unit formed from a fluorine-containing monomer represented by formula CH2═C(—X)—C(═O)—Y—Z—Rf, and (b) a repeating unit formed from a non-fluorine monomer having a hydrocarbon group with 14 or more carbon atoms, and which has a weight average molecular weight of 2,500-20,000.

First claim

The invention claimed is:

1. A resin composition comprising:
(1) a thermoplastic resin, and
(2) a fluorine-containing copolymer,
wherein the fluorine-containing copolymer (2) is a copolymer which comprises:
(a) a repeating unit formed from a fluorine-containing monomer represented by the formula:
CH 2 ═C(—X)—C(═O)—Y—Z—Rf

wherein X is a methyl group,
Y is —O— or —NH—,
Z is a direct bond or an divalent organic group linear alkylene group or branched alkylene group having 1-20 carbon atoms, and
Rf is a fluoroalkyl group having 4 to 6 carbon atoms, and
(b) a repeating unit formed from a fluorine-free monomer containing a hydrocarbon group having at least 14 carbon atoms, and
which has a weight-average molecular weight of 2,500 to 20,000.

2. The resin composition according to claim 1 , wherein the thermoplastic resin (1) is at least one selected from the group consisting of a polypropylene resin, a polyethylene resin, a polyvinyl chloride resin, a polyurethane resin, a polystyrene resin, an acrylonitrile/butadiene/styrene resin (ABS resin), an alloy of a polycarbonate resin and an acrylonitrile/butadiene/styrene resin (PC/ABS alloy), and a polycarbonate resin (PC resin).

3. The resin composition according to claim 1 , wherein the fluorine-free monomer (b), which is a fluorine-free non-crosslinkable monomer containing non-cyclic hydrocarbon group or a cyclic hydrocarbon group having at least 14 carbon atoms, is a (meth)acrylate ester in which an acryloyloxy group is bonded to a monovalent non-cyclic hydrocarbon group or cyclic hydrocarbon group having 14-30 carbon atoms.

4. The resin composition according to claim 1 , wherein the fluorine-free monomer (b) is an acrylate ester in which an alpha-position is a hydrogen atom.

5. The resin composition according to claim 1 , wherein the fluorine-containing copolymer (2) further comprises (c) a repeating unit formed from a fluorine-free crosslinkable monomer, and the amount of the monomer (c) is 0.1 to 100 parts by weight, based on 100 parts by weight of the total of the monomer (a) and the monomer (b).

6. The resin composition according to claim 1 , wherein the fluorine-containing copolymer (2) has a weight-average molecular weight of 3,000 to 15,000.

7. The resin composition according to claim 1 , wherein, in the fluorine-containing copolymer (2), a weight ratio of the fluorine-containing monomer (a) to the fluorine-free monomer (b) is 35:65 to 70:30 and the amount of the fluorine-containing monomer (a) is at least 25 wt %, based on the fluorine-containing copolymer.

8. The resin composition according to claim 1 , wherein the amount of the fluorine-containing copolymer (2) is 0.01 to 50 parts by weight, based on 100 parts by weight of the thermoplastic resin (1).

9. A molded body formed from the resin composition according to claim 1 .

10. A method of producing a molded body, comprising steps of:
(i) mixing a thermoplastic resin (1) with a fluorine-containing copolymer (2) to obtain a resin composition; and
(ii) molding the resin composition,
wherein the fluorine-containing copolymer (2) is a copolymer which comprises:
(a) a repeating unit formed from a fluorine-containing monomer represented by the formula:
CH 2 ═C(—X)—C(═O)—Y—Z—Rf

wherein X is a methyl group,
Y is —O— or —NH—,
Z is a linear alkylene group or branched alkylene group having 1-20 carbon atoms, and
Rf is a fluoroalkyl group having 4 to 6 carbon atoms, and
(b) a repeating unit formed from a fluorine-free monomer containing a hydrocarbon group having at least 14 carbon atoms, and
which has a weight-average molecular weight of 2,500 to 20,000.

11. The resin composition according to claim 1 , wherein a weight ratio of the fluorine-containing monomer (a) to the fluorine-free monomer (b) is 45:55 to 50:50.

12. The resin composition according to claim 1 , wherein the fluorine-free monomer (b) is at least one selected from the group consisting of cetyl (meth)acrylate, stearyl (meth)acrylate and behenyl (meth)acrylate.

13. A method of making a molded body from which stains are easily removed and having excellent scratch resistance, which method comprises:
molding a resin composition, and
wherein the resin composition comprises:
(1) a thermoplastic resin, and
(2) a fluorine-containing copolymer,
wherein the fluorine-containing copolymer (2) is a copolymer which comprises:
(a) a repeating unit formed from a fluorine-containing monomer represented by the formula:
CH 2 ═C(—X)—C(═O)—Y—Z—Rf

wherein X is a methyl group,
Y is —O— or —NH—,
Z is a linear alkylene group or branched alkylene group having 1-20 carbon atoms, and
Rf is a fluoroalkyl group having 4 to 6 carbon atoms, and
(b) a repeating unit formed from a fluorine-free monomer containing a hydrocarbon group having at least 14 carbon atoms, and
which has a weight-average molecular weight of 2,500 to 20,000, and wherein a weight ratio of the fluorine-containing monomer (a) to the fluorine-free monomer (b) is 35:65 to 70:30.

14. The method according to claim 13 , wherein the fluorine-free monomer (b) is at least one selected from the group consisting of cetyl (meth)acrylate, stearyl (meth)acrylate and behenyl (meth)acrylate.

15. The method according to claim 13 , wherein a weight ratio of the fluorine-containing monomer (a) to the fluorine-free monomer (b) is 45:55 to 50:50.

16. The method according to claim 13 , wherein the molded body is at least one selected from interior parts of automobile, interior parts of home electric appliance, and buildings.

Assignees

• Daikin Ind Ltd

Inventors

• Sakami Kazuki
• Masuda Eiji
• Kawahara Kazuya

Classifications

• C08L23/06 Primary

  Polyethylene · CPC title

• C08G18/7678

  containing condensed aromatic rings · CPC title

• C08G18/4833

  Polyethers containing oxyethylene units · CPC title

• C08L33/16 Primary

  Homopolymers or copolymers of esters containing halogen atoms · CPC title

• C08G18/44

  Polycarbonates · CPC title