Molding material mixture and method for producing the same

Patent metadata

Field	Value
Publication number	US-10759930-B2
Application number	US-201715657970-A
Country	US
Kind code	B2
Filing date	Jul 24, 2017
Priority date	Jul 25, 2016
Publication date	Sep 1, 2020
Grant date	Sep 1, 2020

Abstract

A molding material mixture contains cellulose nanofibers (CNFs) and at least one base material selected from the group consisting of a resin and fibers. A hydrophobic polymer is chemically bonded to at least some of the —OH groups of the cellulose nanofibers. The base material and the cellulose nanofibers are ground or pelletized. A method for producing the molding material mixture includes the following: a pre-irradiation step of applying an aqueous dispersion of CNFs to a base material sheet or immersing a base material sheet in the CNF aqueous dispersion, irradiating the base material sheet with an electron beam, and bringing the base material sheet into contact with an aqueous solution or an aqueous dispersion containing a hydrophobic monomer so that the hydrophobic monomer is graft-polymerized onto the CNFs, or a simultaneous irradiation step of mixing an aqueous dispersion of CNFs with a hydrophobic monomer to form a solution, applying the mixed solution to a base material sheet or immersing a base material sheet in the mixed solution, and irradiating the base material sheet with an electron beam so that the hydrophobic monomer is graft-polymerized onto the CNFs; a drying step; and a grinding or pelletizing step. The present invention provides a molding material mixture that contains cellulose nanofibers and at least one base material selected from the group consisting of a resin and fibers, and that can be handled as a ground product or pellets, and also provides a method for producing the molding material mixture.

First claim

What is claimed is:

1. A molding material mixture comprising:
cellulose nanofibers; and
at least one base material selected from the group consisting of a resin and fibers,
wherein the cellulose nanofibers are obtained by microfibrillation of pulp of plants, and have a fiber diameter of 4 to 100 nm and a fiber length of 1 to 10 μm,
a hydrophobic polymer is chemically bonded to at least some of —OH groups of the cellulose nanofibers,
a distance between fibers in the cellulose nanofibers in a dry state is 3 nm or more, and
the base material and the cellulose nanofibers are integrated with each other and ground or pelletized.

2. The molding material mixture according to claim 1 , wherein the molding material mixture does not become viscous when mixed with water.

3. The molding material mixture according to claim 1 , wherein the hydrophobic polymer is formed by graft polymerization of a hydrophobic monomer including an unsaturated hydrocarbon radical.

4. The molding material mixture according to claim 1 , wherein a proportion of the cellulose nanofibers is 1 to 50% by weight and a proportion of the base material is 50 to 99% by weight relative to 100% by weight of the entire molding material mixture.

5. A method for producing a molding material mixture comprising cellulose nanofibers and at least one base material selected from the group consisting of a resin and fibers, the method comprising:
(a1) pre-irradiation comprising:
applying a solvent dispersion of cellulose nanofibers to a base material sheet or immersing the base material sheet in the solvent dispersion of cellulose nanofibers;
irradiating the base material sheet with an electron beam; and
bringing the base material sheet into contact with a solution or a solvent dispersion containing a hydrophobic monomer so that the hydrophobic monomer is graft-polymerized onto the cellulose nanofibers to form a graft-polymer, or

(a2) simultaneous irradiation comprising:
mixing the solvent dispersion of cellulose nanofibers with the hydrophobic monomer to form a solution, applying the mixed solution to the base material sheet, or immersing the base material sheet in the mixed solution; and
irradiating the base material sheet with the electron beam so that the hydrophobic monomer is graft-polymerized onto the cellulose nanofibers to form the graft-polymer;

(b) drying the base material sheet containing the graft polymer; and
(c) grinding or pelletizing the base material sheet containing the graft polymer,
wherein the cellulose nanofibers are obtained by microfibrillation of pulp of plants, and have a fiber diameter of 4 to 100 nm and a fiber length of 1 to 10 μm,
a hydrophobic polymer is chemically bonded to at least some of —OH groups of the cellulose nanofibers,
a distance between fibers in the cellulose nanofibers in a dry state is 3 nm or more, and
the base material and the cellulose nanofibers used for grinding or pelletizing are integrated with each other.

6. The method for producing the molding material mixture according to claim 5 , wherein the base material sheet is at least one selected from the group consisting of a thermoplastic resin sheet and a thermoplastic synthetic fiber sheet.

7. The method for producing the molding material mixture according to claim 6 , wherein the thermoplastic synthetic fiber sheet is a nonwoven fabric.

8. The method for producing the molding material mixture according to claim 5 , wherein the pre-irradiation or the simultaneous irradiation performs the electron beam irradiation when the cellulose nanofibers are wet or after the cellulose nanofibers are dried.

9. The molding material mixture according to claim 1 , wherein the base material is at least one selected from the group consisting of a thermoplastic resin sheet and a thermoplastic synthetic fiber sheet.

10. The molding material mixture according to claim 9 , wherein the thermoplastic synthetic fiber sheet is a nonwoven fabric.

Assignees

• Toyota Auto Body Co Ltd
• Kurashiki Boseki Kk

Inventors

• Akihama Asuka
• Sugiyama Minoru

Classifications

• B29B9/16

  Auxiliary treatment of granules · CPC title

• B29B9/14 Primary

  fibre-reinforced · CPC title

• B29B7/90

  Fillers or reinforcements {, e.g. fibres} · CPC title

• B29B7/002

  Methods (chemical aspects C08J3/00) · CPC title

• B22C1/14

  for separating the pattern from the mould · CPC title