Self-strengthening polymer composites

Patent metadata

Field	Value
Publication number	US-10759127-B2
Application number	US-201815932512-A
Country	US
Kind code	B2
Filing date	Mar 8, 2018
Priority date	Mar 8, 2017
Publication date	Sep 1, 2020
Grant date	Sep 1, 2020

Abstract

A composite material is provided including a polymer matrix and undercooled liquid metallic core-shell particles disposed in the matrix, wherein the particles each have an outer shell and a liquid metallic material as a core contained within the outer shell. The outer shell is frangible such that the liquid metallic material is released from at least some of the particles in response to a mechanical load applied to the composite and solidifies in-situ in the polymer matrix. As a result, the composite material can be self-strengthening and self-healing and can be reconfigurable in shape at ambient temperature.

First claim

We claim:

1. A composite material, comprising a polymer matrix and undercooled liquid metallic core-shell particles disposed in the matrix, said particles each having an outer shell and a liquid metallic material as a core contained within the outer shell, which is frangible such that the liquid metallic material is released from at least some of the particles in response to a stimulus applied to the composite and phase-changes in-situ in the polymer matrix.

2. The composite material of claim 1 wherein the released liquid metallic material is selected to solidify in-situ in the polymer matrix.

3. The composite material of claim 1 wherein at least some of the particles are fused together by inter-particle solidification of the released liquid metallic material after the stimulus is applied.

4. The composite material of claim 1 wherein the polymer comprises a single polymer or a copolymer.

5. The composite material of claim 1 wherein the outer shell comprises an oxide shell.

6. The composite material of claim 1 wherein the outer shell is functionalized with an organic moiety.

7. The composite of claim 1 which is self-healing in response to a stimulus that forms a crack in the composite wherein said self-healing is achieved as a result of said liquid metallic material filling said crack and solidifying there.

8. The composite of claim 1 which has a changed shape after application of the stimulus, which changed shape is retained by said phase transformation.

9. The composite of claim 8 wherein the changed shape is thermally reversible.

10. A self-strengthening composite material, comprising a polymer matrix and undercooled liquid metallic core-shell particles disposed in the matrix, said particles each having an outer shell and a liquid metallic material as a core contained within the outer shell, which is frangible such that the liquid metallic material is released from at least some of the particles in response to a stimulus applied to the composite and solidifies within the polymer matrix to increase the strength of the composite.

11. The composite material of claim 9 wherein the polymer comprises a single polymer or a copolymer.

12. The composite material of claim 9 wherein the outer shell comprises an oxide.

13. The composite material of claim 9 wherein the outer shell is functionalized with an organic moiety.

14. A reconfigurable composite material, comprising an elastomeric polymer matrix and undercooled liquid metallic core-shell particles disposed in the matrix, said particles each having an outer shell and a liquid metallic material as a core contained within the outer shell, which is frangible such that the liquid metallic material is released from at least some of the particles in response to a stimulus to the composite to change its shape and solidifies within the polymer matrix to retain the changed shape of the composite.

15. The composite material of claim 14 wherein the elastomeric polymer comprises a single or a copolymer.

16. The composite material of claim 14 wherein the outer shell comprises an oxide shell.

17. The composite material of claim 14 wherein the outer shell is functionalized with an organic moiety.

18. A method of making a polymer composite, comprising mixing undercooled liquid metallic core-shell particles and a polymer and curing the polymer to form the polymer composite.

19. The method of claim 18 wherein the polymer comprises a single polymer or a copolymer.

20. The method of claim 18 wherein the outer shell comprises an oxide shell.

21. The method of claim 18 wherein the outer shell is functionalized with an organic moiety.

22. A method of treating a polymer composite having a polymer matrix and undercooled liquid metallic core-shell particles disposed in the matrix by applying a stimulus that breaks the outer shell of the undercooled particles in a manner to release liquid metallic material from at least some of the particles and induce phase transformation of the released liquid metallic material in-situ in the polymer matrix.

23. The method of claim 22 wherein the composite is treated by applying an external stimulus to the composite comprising at least one of a tensile force, a compressive force, a shear force, vibrational force, a chemical etchant, a chemical flux, heat application, shock wave impingement, ultrasound impingement, and light impingement such as laser light and focused beam light impingement.

24. The method of claim 22 wherein applying of the stimulus effects a change of shape of the composite wherein the changed shape is retained after application of the stimulus by said phase transformation of the released metallic material.

25. The method of claim 24 including the further step of heating the composite to thermally reverse the changed shape.

Assignees

• Univ Iowa State Res Found Inc

Inventors

• Thuo Martin
• Chang Boyce S

Classifications

• C08J3/12

  Powdering or granulating · CPC title

• C08J2383/04

  Polysiloxanes · CPC title

• C08J2300/26

  Elastomers · CPC title

• C08K3/08

  Metals · CPC title

• C23C22/00

  Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals · CPC title