Carbon nanomaterial composite sheet and method for making the same

Patent metadata

Field	Value
Publication number	US-10758936-B2
Application number	US-201615007379-A
Country	US
Kind code	B2
Filing date	Jan 27, 2016
Priority date	Dec 8, 2015
Publication date	Sep 1, 2020
Grant date	Sep 1, 2020

Abstract

A carbon nanomaterial composite sheet and a method for making a carbon nanomaterial composite sheet may include a layer of a carbon nanomaterial structure being bonded to a carrier layer, the carrier layer being fabricated from a porous metalized nonwoven material.

First claim

What is claimed is:

1. A carbon nanomaterial composite sheet in the form of a laminate, useful in a skin panel composite structure of an aircraft, for providing lightning strike protection on the aircraft, the carbon nanomaterial composite sheet consisting essentially of:
a) a network consisting of randomly oriented, uniformly distributed, and entangled carbon nanotubes, entangled in multiple directions, wherein the carbon nanotubes consist of single-wall carbon nanotubes, and wherein the network includes the single-wall carbon nanotubes in a quantity sufficient to form a number of crossover locations that stabilize the carbon nanotube network;
b) a porous metalized nonwoven material comprising carbon fiber nonwoven material coated with nickel, and wherein at least some of the single-wall carbon nanotubes of the network are interspersed through a thickness of and entangled with the nickel-coated carbon fiber nonwoven material, to permanently bond the nickel-coated carbon fiber nonwoven material to the network of single wall carbon nanotubes; and
c) at least one of the following:
a polymer layer coupled to the network;
a polymer encapsulating layer coupled to the network; and
a prepreg material coupled to the network.

2. The carbon nanomaterial composite sheet according to claim 1 , wherein the network has a basis weight of at least 1 gram per square meter (gsm).

3. A roll formed from a continuous sheet of the carbon nanomaterial composite sheet of claim 1 .

4. The carbon nanomaterial composite sheet according to claim 1 , wherein the carbon nanotubes have an aspect ratio of at least 2,500:1.

5. The carbon nanomaterial composite sheet of claim 1 being coupled to a releasable protective film such that the porous metalized nonwoven material is located between the releasable protective film and the network.

6. A composite structure comprising:
at least one fiber-reinforced polymer layer; and
the carbon nanomaterial composite sheet of claim 1 connected to the fiber-reinforced polymer layer.

7. A method for imparting lightning strike protection to a composite structure comprising:
incorporating into said composite structure the carbon nanomaterial composite sheet of claim 1 .

8. A method for imparting electromagnetic interference shielding to a composite structure comprising:
incorporating into said composite structure the carbon nanomaterial composite sheet of claim 1 .

9. The carbon nanomaterial composite sheet according to claim 1 comprising the polymer layer coupled to the network.

10. The carbon nanomaterial composite sheet according to claim 1 comprising the polymer encapsulating layer coupled to the network.

11. The carbon nanomaterial composite sheet according to claim 1 comprising the prepreg material coupled to the network.

12. The composite structure of claim 6 wherein the network has a basis weight of at least 1 gram per square meter (gsm).

13. The composite structure of claim 6 wherein the carbon nanotubes have an aspect ratio of at least 2,500:1.

14. The composite structure of claim 6 wherein the carbon nanomaterial composite sheet comprises the polymer layer coupled to the network.

15. The composite structure of claim 6 wherein the carbon nanomaterial composite sheet comprises the polymer encapsulating layer coupled to the network.

16. The composite structure of claim 6 wherein the carbon nanomaterial composite sheet comprises the prepreg material coupled to the network.

17. A carbon nanomaterial composite sheet in the form of a laminate, useful in a skin panel composite structure of an aircraft, for providing lightning strike protection on the aircraft, the carbon nanomaterial composite sheet consisting essentially of:
a) a network consisting of randomly oriented, uniformly distributed, and entangled carbon nanotubes, entangled in multiple directions, wherein the carbon nanotubes consist of single-wall carbon nanotubes, wherein the network includes the single-wall carbon nanotubes in a quantity sufficient to form a number of crossover locations that stabilize the carbon nanotube network, and wherein the network has a basis weight of at least 1 gram per square meter (gsm); and
b) a porous metalized nonwoven material comprising carbon fiber nonwoven material coated with nickel, and wherein at least some of the single-wall carbon nanotubes of the network are interspersed through a thickness of and entangled with the nickel-coated carbon fiber nonwoven material, to permanently bond the nickel-coated carbon fiber nonwoven material to the network of single wall carbon nanotubes.

18. The carbon nanomaterial composite sheet if claim 17 wherein the carbon nanotubes have an aspect ratio of at least 2,500:1.

19. A composite structure comprising:
at least one fiber-reinforced polymer layer; and
the carbon nanomaterial composite sheet of claim 17 connected to the fiber-reinforced polymer layer.

20. A carbon nanomaterial composite sheet in the form of a laminate, useful in a skin panel composite structure of an aircraft, for providing lightning strike protection on the aircraft, the carbon nanomaterial composite sheet consisting essentially of:
a) a network consisting of randomly oriented, uniformly distributed, and entangled carbon nanotubes, entangled in multiple directions, wherein the carbon nanotubes consist of single-wall carbon nanotubes, and wherein the network includes the single-wall carbon nanotubes in a quantity sufficient to form a number of crossover locations that stabilize the carbon nanotube network;
b) a porous metalized nonwoven material comprising carbon fiber nonwoven material coated with nickel, and wherein at least some of the single-wall carbon nanotubes of the network are interspersed through a thickness of and entangled with the nickel-coated carbon fiber nonwoven material, to permanently bond the nickel-coated carbon fiber nonwoven material to the network of single wall carbon nanotubes; and
c) a releasable protective film coupled to the porous metalized nonwoven material such that the porous metalized nonwoven material is located between the releasable protective film and the network.

Assignees

• Boeing Co
• General Nano Llc

Inventors

• Braley Daniel J
• Belk John H
• Battat Jacob I
• Truscello Justine M
• Ferriell Daniel R
• Sprengard Joseph
• Christy Larry

Classifications

• B32B9/047

  made of fibres or filaments · CPC title

• B64C3/20

  Integral or sandwich constructions · CPC title

• B32B9/041

  of metal · CPC title

• C23C24/08

  by application of heat or pressure and heat (C23C24/04 takes precedence) · CPC title

• B32B5/16

  characterised by features of a layer formed of particles, e.g. chips, powder {or granules (layer formed of natural mineral particles B32B19/00; layer being formed of wood fibres, chips or particles B32B21/02)} · CPC title