Application method and device for cold field plasma discharge assisted high energy ball milled powder

Patent metadata

Field	Value
Publication number	US-10758916-B2
Application number	US-201415539360-A
Country	US
Kind code	B2
Filing date	Dec 24, 2014
Priority date	Dec 24, 2014
Publication date	Sep 1, 2020
Grant date	Sep 1, 2020

Abstract

Generating plasma by using dielectric barrier discharge and introducing a dielectric barrier discharge electrode bar into a high-speed vibrating ball milling tank requires that, on one hand, a solid insulation medium on the outer layer of the electrode bar can simultaneously bear high-voltage discharge and mechanical shock failure of the grinding ball, and on the other hand, the high-speed vibrating ball milling device can uniformly process the powder. The discharge space pressure is set to a non-thermal equilibrium discharge state with a pressure of about 102 to 106 Pa, discharge plasmas are introduced to input another kind of effective energy to the processed powder, so as to accelerate refinement of the powder to be processed and promote the alloying process and improve the processing efficiency and the effect of the ball mill.

First claim

What is claimed is:

1. A plasma assisted high energy ball milling device, the device comprising: a vibrating high energy ball milling main engine, an external cold field plasma power supply, a discharge ball milling tank, a discharge electrode bar, a controllable atmosphere system and a cooling system;
wherein the vibrating high energy ball milling main engine is in a form of a double-cylinder vibrating mill;
wherein the discharge ball milling tank comprises a connecting cylinder, a front cover, a rear cover, and a plasma power supply negative grounding electrode connected to the discharge ball milling tank; and
wherein the discharge electrode bar, in a form of a cylindrical rod, is composed of an inner conductive core made of iron, copper, or combinations thereof and an outer insulation layer made of a pure alumina ceramic material; the inner conductive core, as an electrode for plasma discharge, is connected to a plasma power supply positive high-voltage electrode, and the outer insulation layer is present as a discharge dielectric barrier layer;
wherein a stainless steel sleeve and a rubber sealing ring are embedded in a through hole of the front cover of the discharge ball milling tank, and a stainless steel sleeve gasket is embedded in a blind hole of an inner side of the rear cover; and
wherein the front cover comprises a polytetrafluoroethylene plate and a ceramic plate, and the rear cover comprises a polytetrafluoroethylene plate and a ceramic plate.

2. The plasma assisted high energy ball milling device according to claim 1 , wherein the vibrating high energy ball milling main engine is alternatively in a form of an eccentric vibrating mill.

3. The plasma assisted high energy ball milling device according to claim 1 , wherein the external cold field plasma power supply converts a mains supply current into a high-frequency current by using a high-voltage AC power supply in a conversion mode of AC-DC-AC, wherein an FM control mode is used for a DC-AC conversion, with a working frequency in a range of 1-20 kHz, and a power supply output voltage is in a range of 1-30 kV.

4. The plasma assisted high energy ball milling device according to claim 1 , wherein a tightening end of the inner conductive core made of iron, copper, or combinations thereof in the discharge electrode bar threadedly fits in with the outer insulation layer made of a pure alumina ceramic material, a discharge end fits in with the outer insulation layer by having a bare rod structure, a heat-resistant adhesive is provided between the inner conductive core and the outer insulation layer, and a top side of the inner conductive core fits in with a medium in the outer insulation layer by having a spherical structure.

5. The plasma assisted high energy ball milling device according to claim 1 , wherein the outer insulation layer made of the pure alumina ceramic material is formed by a direct deposition method or a micro-arc oxidation method.

6. The plasma assisted high energy ball milling device according to claim 1 , wherein the outer insulation layer of the discharge electrode bar made of the pure alumina ceramic material is covered with a metal sleeve with meshes.

7. The plasma assisted high energy ball milling device according to claim 1 , wherein the controllable atmosphere system, mounted above inlet and outlet holes of the discharge ball milling tank, can independently regulate ball milling effects of plasma on processed powder under different atmospheric pressure and in various atmospheres of argon, nitrogen, ammonia, hydrogen, and oxygen.

8. The plasma assisted high energy ball milling device according to claim 1 , wherein flanges on both ends of the connecting cylinder of the discharge ball milling tank are sealedly connected to the front cover and the rear cover through a sealing ring and a bolt, respectively, with the through hole and the blind hole for fixing the discharge electrode bar provided in a central position of the front cover and the rear cover, respectively.

9. The plasma assisted high energy ball milling device according to claim 8 , wherein the front cover of the discharge ball milling tank is provided on an outer end face with a vacuum valve.

Assignees

• Univ South China Tech

Inventors

• Zhu Min
• Zeng Meiqin
• Lu Zhongchen
• Ouyang Liuzhang
• Wang Hui
• Hu Renzong

Classifications

• B02C19/16

  Mills provided with vibrators ({roller mills B02C4/423}; tumbling mills B02C17/14) · CPC title

• B02C17/1875

  passing gas through crushing zone · CPC title

• B02C17/14

  Mills in which the charge to be ground is turned over by movements of the container other than by rotating, e.g. by swinging, vibrating, tilting {(mills provided with vibrators in general B02C19/16)} · CPC title

• B02C19/18 Primary

  Use of auxiliary physical effects, e.g. ultrasonic waves or irradiation, for disintegrating · CPC title

• B02C17/18

  Details · CPC title