Method of negative electrode pre-lithiation for lithium-ion capacitors

Patent metadata

Field	Value
Publication number	US-10755867-B2
Application number	US-201715489813-A
Country	US
Kind code	B2
Filing date	Apr 18, 2017
Priority date	Apr 18, 2016
Publication date	Aug 25, 2020
Grant date	Aug 25, 2020

Abstract

The present invention is directed to a method for pre-lithiation of negative electrodes during lithium loaded electrode manufacturing for use in lithium-ion capacitors. There is provided a system and method of manufacture of LIC electrodes using thin lithium film having holes therein, and in particular, to the process of manufacturing lithium loaded negative electrodes for lithium-ion capacitors by pre-lithiating electrodes with thin lithium metal films, wherein the thin lithium metal films include holes therein, and the lithium loaded negative electrodes are manufactured using a roll-to-roll lamination manufacturing process.

First claim

We claim:

1. A method for lithium loaded electrode manufacturing for lithium-ion capacitors wherein a lithium loaded negative electrode is manufactured using lithium metal thin film having holes in a roll-to-roll process, comprising the steps of:
(a) the manufacturing process should be done in a temperature and humidity controlled clean and dry room;
(b) providing the negative electrode sheet and the top Li thin film having holes and bottom Li thin film having holes;
(c) feed roll insertion of the bottom Li thin film having holes through tension control rolls and the lamination rolls;
(d) feed roll and the insertion of the negative electrode sheet through the tension control rolls and into the lamination rolls;
(e) feed roll insertion of the top Li thin film having holes through the tension rolls and into the lamination rolls; and
(f) exertion of pressure on the lamination rolls and the extension of the laminated Li loaded negative electrode sheet through the tension control rolls and on to the take up roll to be completed and ready for use in Li-ion capacitors;
wherein there is no adhesive drying time and no heat required on the lamination rolls, the pressure may be adjusted to a pressure range of from 40 to 400 kg/cm 2 as required to press the top Li thin film having holes and bottom Li foil thin film having holes into the negative electrode sheet and the gap between the top and bottom lamination rolls may be adjusted according to the laminated Li loaded negative electrode sheet requirements.

2. The method of lithium loaded electrode manufacturing for lithium-ion capacitors wherein a lithium loaded negative electrode is manufactured using lithium thin film having holes in a roll-to-roll process, according to claim 1 , wherein the width range of said negative electrode is from 2 mm to 300 mm.

3. The method of lithium loaded electrode manufacturing for lithium-ion capacitors wherein a lithium loaded negative electrode is manufactured using lithium thin film having holes in a roll-to-roll process, according to claim 1 , wherein the thickness range of said negative electrode is from 20 μm to 400 μm.

4. The method of lithium loaded electrode manufacturing for lithium-ion capacitors wherein a lithium loaded negative electrode is manufactured using lithium thin film having holes in a roll-to-roll process, according to claim 1 , wherein the said negative electrode material includes graphite, hard carbon and soft carbon.

5. The method of lithium loaded electrode manufacturing for lithium-ion capacitors wherein a lithium loaded negative electrode is manufactured using lithium thin film having holes in a roll-to-roll process, according to claim 1 , wherein the width range of said lithium films is from 2 mm to 300 mm.

6. The method of lithium loaded electrode manufacturing for lithium-ion capacitors wherein a lithium loaded negative electrode is manufactured using lithium thin film having holes in a roll-to-roll process, according to claim 5 , wherein the area of the loaded thin Li film having holes is from 25% to 100% of the area of the negative electrode.

7. The method of lithium loaded electrode manufacturing for lithium-ion capacitors wherein a lithium loaded negative electrode is manufactured using lithium thin film having holes in a roll-to-roll process, according to claim 1 , wherein the thickness range of said lithium films is from 2 μm to 50 μm.

8. The method of lithium loaded electrode manufacturing for lithium-ion capacitors wherein a lithium loaded negative electrode is manufactured using lithium thin film having holes in a roll-to-roll process, according to claim 7 , wherein the mass ratio of the Li loading weight to the negative electrode active layer weight is from 3% to 20%.

9. The method of lithium loaded electrode manufacturing for lithium-ion capacitors wherein a lithium loaded negative electrode is manufactured using lithium thin film having holes in a roll-to-roll process, according to claim 1 , wherein the area size percentage range of said holes in lithium films is from 0.01% to 75%.

10. The method of lithium loaded electrode manufacturing for lithium-ion capacitors wherein a lithium loaded negative electrode is manufactured using lithium thin film having holes in a roll-to-roll process, according to claim 1 , includes a top lithium film and a bottom lithium film.

11. The method of lithium loaded electrode manufacturing for lithium-ion capacitors wherein a lithium loaded negative electrode is manufactured using lithium thin film having holes in a roll-to-roll process, according to claim 10 , further includes a top lithium film and a bottom lithium film, wherein the locations of said top lithium film and said bottom lithium film are the same on each side of negative electrode.

Assignees

• Univ Florida State Res Found Inc
• Univ Florida State Res Found
• General Capacitor Llc

Inventors

• Cao Wanjun
• Zheng Jim P

Classifications

• H01G11/54

  Electrolytes · CPC title

• H01G11/06

  with one of the electrodes allowing ions to be reversibly doped thereinto, e.g. lithium ion capacitors [LIC] · CPC title

• Y02E60/13

  Energy storage using capacitors · CPC title

• H01G11/14

  Arrangements or processes for adjusting or protecting hybrid or EDL capacitors (emergency protective circuit arrangements specially adapted for capacitors, and effecting automatic switching in the event of an undesired change from normal working conditions H02H7/16; emergency protective circuit arrangements for limiting excess current or voltages without disconnection H02H9/00) · CPC title

• H01G11/86

  specially adapted for electrodes (carbonisation or activation of carbon for the manufacture of electrodes H01G11/34) · CPC title