Soft, strong and bulky tissue

Patent metadata

Field	Value
Publication number	US-10753046-B2
Application number	US-201916452184-A
Country	US
Kind code	B2
Filing date	Jun 25, 2019
Priority date	Feb 27, 2015
Publication date	Aug 25, 2020
Grant date	Aug 25, 2020

Abstract

The disclosure provides tissue webs and products comprising cross-linked cellulosic fibers. In certain embodiments cross-linked cellulosic fibers are selectively disposed in one or more layers of a multi-layered tissue, wherein the tissue layer comprising cross-linked fibers is adjacent to a layer which is substantially free from cross-linked fiber. The cross-linked fibers may include hardwood kraft fibers reacted with a cross-linking agent selected from the group consisting of DMDHU, DMDHEU, DMU, DHEU, DMEU, and DMeDHEU. Tissue products and webs produced in this manner generally have improved sheet bulk, without losses in strength, compared to similar tissue products produced without cross-linked cellulosic fibers. As such the tissue products of the present invention generally have a basis weight from about 10 to about 50 gsm, a sheet bulk greater from about 8.0 to about 12.0 cc/g and geometric mean tensile from about 730 to about 1,500 g/3″.

First claim

We claim:

1. A tissue product having a geometric mean tensile (GMT) from 730 to 1,200 g/3″, a sheet bulk from 8.0 to 12.0 cc/g and a TS7 value less than 10.0, wherein the product comprises two multi-layered, creped and unembossed plies, each ply comprising a first fibrous layer comprising cross-linked cellulosic fibers and a second fibrous layer that is substantially free from cross-linked cellulosic fibers and wherein the product comprises from 5 to 75 percent, by weight of the product, cross-linked hardwood kraft fibers.

2. The tissue product of claim 1 having a Slough less than 10.0 mg.

3. The tissue product of claim 1 having a TS7 value from 5.0 to 9.0.

4. The tissue product of claim 1 having a Durability Index from 26.0 to 32.0.

5. The tissue product of claim 1 having a Stiffness Index from 10.0 to 13.0.

6. The tissue product of claim 1 wherein the cross-linked cellulosic fibers comprise eucalyptus hardwood kraft fibers reacted with a cross-linking reagent selected from the group consisting of 1,3-dimethyl-4,5-dihydroxy-2-imidazolidinone (DMDHU), 1,3-dihydroxymethyl-4,5-dihydroxy- 2 -imidazolidinone (DMDHEU), bis[N-hydroxymethyl]urea (DMU), 4,5-dihydroxy-2-imidazolidinone (DHEU), 1,3-dihydroxymethyl-2-imidazolidinone(DMEU) and 4,5-dihydroxy-1,3-dimethyl-2-imidazolidinone (DMeDHEU).

7. The tissue product of claim 1 having a Slough less than 10.0 mg and a Durability Index from 26.0 to 32.0.

8. A non-embossed creped multi-ply tissue product having increased sheet bulk, the product comprising at least two multi-layered plies, each ply comprising a first fibrous layer comprising cross-linked cellulosic fibers and a second fibrous layer that is substantially free from cross-linked cellulosic fibers and wherein the product comprises at least 10 percent, by weight of the product, cross-linked cellulosic fibers, wherein the sheet bulk of the product is at least 20 percent greater and geometric mean tensile strength (GMT) is not 5 percent less than a comparable tissue product substantially free of cross-linked cellulosic fibers.

9. The tissue product of claim 8 having a sheet bulk from 8.0 to 12.0 cc/g.

10. The tissue product of claim 8 wherein the cross-linked fibers comprise hardwood kraft fibers reacted with a cross-linking reagent selected from the group consisting of 1,3-dimethyl-4,5-dihydroxy-2-imidazolidinone (DMDHU), 1,3-dihydroxymethyl-4,5-dihydroxy-2-imidazolidinone (DMDHEU), bis[N-hydroxymethyl]urea (DMU), 4,5-dihydroxy-2-imidazolidinone (DHEU), 1,3-dihydroxymethyl-2-imidazolidinone (DMEU) and 4,5-dihydroxy-1,3-dimethyl-2-imidazolidinone (DMeDHEU).

11. The tissue product of claim 8 wherein the product comprises from 10 to 50 percent, by weight of the product, cross-linked cellulosic fiber.

12. The tissue product of claim 8 having a sheet bulk from 9.0 to 11.0 cc/g, a GMT from 730 to 1,200 g/3″ and a Stiffness Index from 10 to 13.

Assignees

• Kimberly Clark Co

Inventors

• Zawadzki Michael Andrew
• Lindsay Stephen Michael
• Satori Christopher Lee
• Goulet Mike Thomas
• Uttecht Cathleen Mae
• Waldroup Donald Eugene
• Zwick Kenneth John

Classifications

• D21H25/005 Primary

  Mechanical treatment (D21H25/08, D21H25/18 take precedence) · CPC title

• D21H27/005 Primary

  relating to physical or mechanical properties, e.g. tensile strength, stretch, softness · CPC title

• D21H27/002

  Tissue paper; Absorbent paper (D21H21/22, D21H27/02, D21H27/20 take precedence; toilet paper A47K10/00; absorbent pads for physiological fluids A61L15/16; making on paper-making machines D21F11/00) · CPC title

• D21H11/12

  Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse · CPC title

• D21H27/30

  Multi-ply (for surface covering D21H27/18; making on paper-making machines D21F9/00, D21F11/00) · CPC title