Resid upgrading with reduced coke formation

Patent metadata

Field	Value
Publication number	US-10752846-B2
Application number	US-201815933422-A
Country	US
Kind code	B2
Filing date	Mar 23, 2018
Priority date	Apr 7, 2017
Publication date	Aug 25, 2020
Grant date	Aug 25, 2020

Abstract

Systems and methods are provided for improving the processing of heavy or challenged feeds in a refinery based on integrated use of deasphalting, coking, and hydroprocessing. An optional fluid catalytic cracking unit can be included in the integrated system to allow for further improvements. The improved processing can be facilitated based on a process configuration where the vacuum resid fractions and/or other difficult fractions are deasphalted to generate a deasphalted oil and a deasphalter residue or rock fraction. The deasphalted oil can be passed into a hydroprocessing unit for further processing. The rock fraction can be used as the feed to a coking unit. Although deasphalter residue or rock is typically a feed with a high content of micro carbon residue, a high lift deasphalting process can allow a portion of the micro carbon residue in the initial feed to remain with the deasphalted oil. The portion of micro carbon residue that remains in the deasphalted oil can then be upgraded during hydroprocessing and/or during subsequent processing of the feed. By reducing the amount of micro carbon residue passed into a coker for a given initial feed source, the overall capacity for a reaction system to handle heavy feeds can be increased relative to the rate of coke production from the reaction system.

First claim

The invention claimed is:

1. A method for processing a feedstock including at least one cracked feed component, comprising:
performing solvent deasphalting on a feedstock comprising a solubility blending number (S BN ) of 100 or more, a T90 distillation point of 566° C. or more, 8.0 wt % or more of micro carbon residue, and 10 wt % or more of cracked feed to form a deasphalted oil and a deasphalter residue, a yield of the deasphalted oil being about 50 wt % or more relative to a weight of the feedstock, the deasphalted oil comprising a S BN of about 80 or more and about 2.0 wt % or more of micro carbon residue;
exposing at least a portion of the deasphalted oil to a hydroprocessing catalyst under effective hydroprocessing conditions to form a hydroprocessed effluent; and
coking at least a portion of the deasphalter residue under effective coking conditions to form a coker effluent, wherein the coker effluent comprises a coker bottoms, the feedstock comprising at least a portion of the coker bottoms, and coke.

2. The method of claim 1 , wherein a C 5+ portion of the hydroprocessed effluent has an API gravity that is about 15 or more greater than an API gravity of the at least a portion of the deasphalted oil.

3. The method of claim 1 , wherein the hydroprocessed effluent comprises a naphtha boiling range fraction, a yield of the naphtha boiling range fraction being about 10.0 wt % or less relative to a weight of the at least a portion of the deasphalted oil.

4. The method of claim 1 , wherein the feedstock comprises about 1.0 wt % organic sulfur or more, the hydroprocessed effluent comprising about 0.5 wt % or less of organic sulfur.

5. The method of claim 1 , wherein the feedstock comprises 15 wt % or more of micro carbon residue; or wherein 40 wt % or more of the carbons in the feedstock comprise aromatic carbons; or a combination thereof.

6. The method of claim 1 , wherein the deasphalted oil comprises about 5.0 wt % or more of micro carbon residue; or wherein 30 wt % or more of the carbons in the deasphalted oil comprise aromatic carbons; or a combination thereof.

7. The method of claim 1 , wherein the deasphalter residue has a T10 distillation point of 566° C. or less.

8. The method of claim 1 , wherein the cracked feed comprises a catalytic slurry oil, a coker bottoms, a steam cracker tar, a visbreaker gas oil, a coal tar, or a combination thereof.

9. The method of claim 1 , wherein the feedstock comprises at least 20 wt % of the cracked feed; or wherein the cracked feed comprises at least 50 wt % of a catalytic slurry oil relative to a weight of the cracked feed; or a combination thereof.

10. The method of claim 1 , wherein the cracked feed comprises cracked feed having an T5 distillation point of at least 149° C. and a T90 distillation point of 566° C. or less.

11. A method for processing a feedstock including at least one cracked feed component, comprising:
performing solvent deasphalting on a feedstock comprising a solubility blending number (S BN ) of 100 or more, a T90 distillation point of 566° C. or more, 8.0 wt % or more of micro carbon residue, and 10 wt % or more of cracked feed to form a deasphalted oil and a deasphalter residue, a yield of the deasphalted oil being about 50 wt % or more relative to a weight of the feedstock, the deasphalted oil comprising a S BN of about 80 or more and about 2.0 wt % or more of micro carbon residue;
exposing at least a portion of the deasphalted oil to a hydroprocessing catalyst under effective hydroprocessing conditions to form a hydroprocessed effluent; and
coking at least a portion of the deasphalter residue under effective coking conditions to form a coker effluent, wherein the coker effluent comprises a coker gas oil, and wherein the exposing at least a portion of the deasphalted oil to a hydroprocessing catalyst under effective hydroprocessing conditions further comprises exposing a portion of the coker gas oil having a T10 distillation point of at least 343° C. to the hydroprocessing catalyst under the effective hydroprocessing conditions, and coke.

12. The method of claim 11 , wherein a C 5+ portion of the hydroprocessed effluent has an API gravity that is about 15 or more greater than an API gravity of the at least a portion of the deasphalted oil.

13. The method of claim 11 , wherein the hydroprocessed effluent comprises a naphtha boiling range fraction, a yield of the naphtha boiling range fraction being about 10.0 wt % or less relative to a weight of the at least a portion of the deasphalted oil.

14. The method of claim 11 , wherein the feedstock comprises about 1.0 wt % organic sulfur or more, the hydroprocessed effluent comprising about 0.5 wt % or less of organic sulfur.

15. The method of claim 11 , wherein the feedstock comprises 15 wt % or more of micro carbon residue; or wherein 40 wt % or more of the carbons in the feedstock comprise aromatic carbons; or a combination thereof.

16. A method for processing a feedstock including at least one cracked feed component, comprising:
performing solvent deasphalting on a feedstock comprising a solubility blending number (S BN ) of 100 or more, a T90 distillation point of 566° C. or more, 8.0 wt % or more of micro carbon residue, and 10 wt % or more of cracked feed to form a deasphalted oil and a deasphalter residue, a yield of the deasphalted oil being about 50 wt % or more relative to a weight of the feedstock, the deasphalted oil comprising a S BN of about 80 or more and about 2.0 wt % or more of micro carbon residue;
exposing at least a portion of the deasphalted oil to a hydroprocessing catalyst under effective hydroprocessing conditions to form a hydroprocessed effluent;
separating a first fraction having a T10 distillation point of at least 510° C. and a second fraction having a lower T10 distillation point from a feed having a T10 distillation point of at least 300° C., the feedstock comprising at least a portion of the first fraction; and
exposing the second fraction to a catalyst under fluid catalytic cracking conditions to form a fluid catalytic cracking effluent comprising a catalytic slurry oil.

17. The method of claim 16 , wherein the hydroprocessed effluent comprises a hydroprocessed gas oil boiling range fraction, and wherein exposing the second fraction to a catalyst under fluid catalytic cracking conditions further comprises exposing at least a portion of the hydroprocessed gas oil boiling range fraction to the catalyst under the fluid catalytic cracking conditions.

18. The method of claim 16 , wherein a C 5+ portion of the hydroprocessed effluent has an API gravity that is about 15 or more greater than an API gravity of the at least a portion of the deasphalted oil.

19. The method of claim 16 , wherein the hydroprocessed effluent comprises a naphtha boiling range fraction, a yield of the naphtha boiling range fraction being about 10.0 wt % or less relative to a weight of the at least a portion of the deasphalted oil.

20. The method of claim 16 , wherein the feedstock comprises about 1.0 wt % organic sulfur or more, the hydroprocessed effluent comprising about 0.5 wt % or less of organic sulfur.

Assignees

• Exxonmobil Res & Eng Co
• Exxonmobil Res & Engineering Company

Inventors

• Brown Stephen H
• Cunningham Brian A
• Smiley Randolph J
• Ilias Samia
• Raich Brenda A
• Le Tien V

Classifications

• C10G67/049

  The hydrotreatment being a hydrocracking · CPC title

• C10G67/0463

  The hydrotreatment being a hydrorefining · CPC title

• C10G67/0454

  Solvent desasphalting · CPC title

• C10G55/06 Primary

  including at least one catalytic cracking step · CPC title

• C10G2300/1085

  Solid paraffins · CPC title