Polymer composite comprising an interfacially modified fiber and particle

Patent metadata

Field	Value
Publication number	US-10752777-B2
Application number	US-201916251301-A
Country	US
Kind code	B2
Filing date	Jan 18, 2019
Priority date	Mar 14, 2013
Publication date	Aug 25, 2020
Grant date	Aug 25, 2020

Abstract

Embodiments herein relate to a composite material including about 10 to 80 wt. % of a polymer phase, the polymer phase comprising a thermoplastic polymer with a density of less than about 1.9 g-m −3 ; and about 20 to 90 wt. % of a dispersed mixed particulate phase, the dispersed mixed particulate phase comprising a mixed particulate and about 0.005 to 8 wt. % of a coating of at least one interfacial modifier. The mixed particulate including a portion of a reinforcing fiber and a portion of a particle. The composite material having a Young's modulus of greater than 700 MPa. In various embodiments, structural building components made from the composite are included as well as additive manufacturing components made from the composite. Other embodiments are also included herein.

First claim

The invention claimed is:

1. A thermoplastic composite comprising:
(i) about 10 to 80 wt. % of a polymer phase comprising a thermoplastic polymer with a density of less than about 1.9 g-m −3 and
(ii) about 20 to 90 wt. % of a dispersed particulate phase comprising greater than 50 wt. % of a reinforcing cellulosic fiber and the balance comprising at least 5 vol. % of a mineral particulate or a glass particulate, the dispersed phase comprising about 0.2-3 wt. % of a coating of at least one interfacial modifier;
wherein the composite material has a Young's modulus of greater than 700 MPa; the interfacial modifier provides a coating on the dispersed particulate that can form a close association between the particulate and polymer and covalent bonding between fiber, particulate and polymer is not formed.

2. The composite material of claim 1 wherein the cellulosic fiber comprises a wood fiber.

3. The composite material of claim 1 wherein the glass particulate comprises a solid glass sphere.

4. The composite material of claim 1 wherein the glass particulate comprises a hollow glass sphere.

5. A structural member comprising a thermoplastic composite comprising:
about 10 to 80 wt. % of a polymer phase comprising a thermoplastic polymer with a density of less than 1.9 g-m −3 and
(ii) about 20 to 90 wt. % of a dispersed particulate phase comprising greater than 50 wt. % of a reinforcing cellulosic fiber and the balance comprising at least 5 vol. % of a mineral particulate or a glass particulate, the dispersed phase comprising about 0.2-3 wt. % of a coating of at least one interfacial modifier;
wherein the composite material has a Young's modulus of greater than 700 MPa; the interfacial modifier provides a coating on the dispersed particulate that can form a close association between the particulate and polymer and covalent bonding between fiber, particulate and polymer is not formed.

6. The composite material of claim 5 forming a structural decking.

7. The composite material of claim 5 forming an extruded panel member.

8. The composite material of claim 5 forming a structural fencing member.

9. The composite material of claim 5 forming at least two extruded panels and joinery features.

10. The composite material of claim 5 comprising a fenestration opening.

11. A filament adapted for use in an additive manufacturing system comprising:
(i) about 10 to 80 wt. % of a polymer phase, the polymer phase comprising a thermoplastic polymer with a density of less than about g-m −3 ; and
(ii) about 20 to 90 wt. % of a dispersed mixed particulate phase, the dispersed mixed particulate phase comprising a mixed particulate and about 0.005 to 8 wt. % of a coating of at least one interfacial modifier; the mixed particulate comprising a portion of a reinforcing fiber and a portion of aparticle; wherein the filament has a Young's modulus of greater than 700 MPa.

12. The filament of claim 11 wherein the reinforcing fiber comprises a cellulosic fiber.

13. The filament of claim 12 wherein the reinforcing fiber comprises a wood fiber.

14. The filament of claim 11 wherein the particle comprises a solid glass sphere.

15. The filament of claim 11 wherein the particle comprises a hollow glass sphere.

Assignees

• Tundra Composites Llc

Inventors

• Heikkila Kurt E
• Kroll John S

Classifications

• B33Y70/10

  Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials · CPC title

• C08J5/045

  with vegetable or animal fibrous material · CPC title

• B27N3/28

  characterised by using extrusion presses · CPC title

• B29K2027/06

  PVC, i.e. polyvinylchloride · CPC title

• C08J2327/06

  Homopolymers or copolymers of vinyl chloride · CPC title