Polymerizable composition for optical materials, optical material, and process for producing same
US-2016313575-A1 · Oct 27, 2016 · US
US10752726B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10752726-B2 |
| Application number | US-201815992839-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 30, 2018 |
| Priority date | Jul 29, 2016 |
| Publication date | Aug 25, 2020 |
| Grant date | Aug 25, 2020 |
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Provided is a resin composition obtained by polymerizing a polymerizable composition including a polyisocyanate compound and a polythiol compound. The polymerizable composition includes a dye L having an absorption maximum wavelength of 550 nm or more and 600 nm or less in a toluene solution of 20 ppm by mass, and a dye S having an absorption maximum wavelength of 500 nm or more and less than 550 nm in a toluene solution of 20 ppm by mass. A mass ratio [(mass of dye L)/(mass of dye S)] of the dye L to the dye S is 5 or more and 500 or less.
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The invention claimed is: 1. A resin composition obtained by polymerizing a polymerizable composition including a polyisocyanate compound and a polythiol compound, wherein the polymerizable composition includes a dye L having an absorption maximum wavelength of 550 nm or more and 600 nm or less in a toluene solution of 20 ppm by mass, and a dye S having an absorption maximum wavelength of 500 nm or more and less than 550 nm in a toluene solution of 20 ppm by mass, and a mass ratio [(mass of dye L)/(mass of dye S)] of the dye L to the dye S is 5 or more and 500 or less. 2. The resin composition according to claim 1 , wherein the total amount of the dye L and the dye S to be added is 200 ppb by mass or more and 10,000 ppb by mass or less in the resin composition. 3. The resin composition according to claim 1 , wherein the polyisocyanate compound is one or more selected from the group consisting of xylylene diisocyanate, isophorone diisocyanate, hexamethylene diisocyanate, bis(isocyanatomethyl)cyclohexane, dicyclohexylmethane diisocyanate, and bis(isocyanatomethyl)bicycloheptane. 4. The resin composition according to claim 1 , wherein the polythiol compound is one or more selected from the group consisting of bis(mercaptomethyl)dithiane, pentaerythritol tetrakis(2-mercaptoacetate), pentaerythritol tetrakis(3-mercaptopropionate), bis(mercaptoethylthio)mercaptopropane, bis(mercaptomethyl)-3,6,9-trithiaundecanedithiol, trimethylolpropane tris(2-mercaptoacetate), trimethylolpropane tris(3-mercaptopropionate), butanediol bis(2-mercaptoacetate), butanediol bis(3-mercaptopropionate), dipentaerythritol hexakis(2-mercaptoacetate), and dipentaerythritol hexakis(3-mercaptopropionate. 5. The resin composition according to claim 4 , wherein bis(mercaptomethyl)-3,6,9-trithiaundecanedithiol is a mixture of 4,7-bis(mercaptomethyl)-3,6,9-trithiaundecane-1,11-dithiol, 4,8-bis(mercaptomethyl)-3,6,9-trithiaundecane-1,11-dithiol, and 5,7-bis(mercaptomethyl)-3,6,9-trithiaundecane-1,11-dithiol. 6. The resin composition according to claim 1 , wherein the polymerizable composition further includes an ultraviolet absorber. 7. A spectacle lens comprising a base material made of the resin composition according to claim 1 . 8. A method for producing a resin composition, comprising a step of polymerizing a polymerizable composition including a polyisocyanate compound and a polythiol compound, wherein the polymerizable composition includes a dye L having an absorption maximum wavelength of 550 nm or more and 600 nm or less in a toluene solution of 20 ppm by mass, and a dye S having an absorption maximum wavelength of 500 nm or more and less than 550 nm in a toluene solution of 20 ppm by mass, and a mass ratio [(mass of dye L)/(mass of dye S)] of the dye L to the dye S is 5 or more and 500 or less.
containing also tin-carbon bonds · CPC title
made of organic materials, e.g. plastics (G02B1/08 takes precedence) · CPC title
Lenses · CPC title
having sulfur · CPC title
Optical parts (characterised by the material G02B1/00) · CPC title
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