Method for preparing a sorbent

Patent metadata

Field	Value
Publication number	US-10751688-B2
Application number	US-201615578748-A
Country	US
Kind code	B2
Filing date	May 5, 2016
Priority date	Jun 5, 2015
Publication date	Aug 25, 2020
Grant date	Aug 25, 2020

Abstract

A method is described for preparing a sorbent comprising the steps of: (i) forming agglomerates comprising a particulate support material, (ii) coating the agglomerates with a coating mixture powder comprising a particulate copper sulphide and a particulate calcined, rehydratable alumina to form a coated agglomerate, and (iii) drying the coated agglomerate to form a dried sorbent.

First claim

The invention claimed is:

1. A method for preparing a dried sorbent comprising the steps of:
(i) forming agglomerates comprising a particulate support material in a granulator with a liquid, and ageing the agglomerates to form aged agglomerates of the particulate support material,
(ii) adding a coating mixture powder to the aged agglomerates, wherein the coating mixture powder comprises a particulate copper sulphide and a particulate calcined, rehydratable alumina, to form coated agglomerates comprising the aged agglomerates having surface layers of the coating mixture powder, and
(iii) drying the coated agglomerates to form the dried sorbent.

2. A method according to claim 1 , wherein the support material is alumina, metal-aluminate, silicon carbide, silica, titania, zirconia, zinc oxide, an aluminosilicate, a zeolite, metal carbonate, carbon, or a mixture thereof.

3. A method according to claim 1 , wherein the support material is a particulate calcined, rehydratable alumina.

4. A method according to claim 1 , wherein the calcined rehydratable alumina comprises a calcined amorphous alumina or a transition alumina that is one or more of rho-alumina, chi-alumina, or pseudo gamma-alumina.

5. A method according to claim 1 , wherein the support material is a powder with a D 50 particle size in a range of from 1 μm to 100 μm.

6. A method according to claim 1 , wherein a binder that is a clay binder, a cement binder, or an organic polymer binder is combined with the support material to form the agglomerates.

7. A method according to claim 6 wherein the binder combined with the support material is a combination of a cement binder and a clay binder.

8. A method according to claim 1 , wherein the coated agglomerates have a diameter in a range of from 1 mm to 15 mm.

9. A method according to claim 1 , wherein the particulate copper sulphide is manufactured by roasting copper or a copper compound with elemental sulphur, precipitating of copper sulphide from solution, sulphiding copper compounds using hydrogen sulphide, or a mechanochemical process comprising mixing powdered copper metal with elemental sulphur under conditions that cause the elemental copper and elemental sulphur to react to form one or more copper sulphides.

10. A method according to claim 1 , wherein the particulate copper sulphide comprises copper (II) sulphide and/or a substoichiometric copper sulphide of formula Cu 2-x S where x is in a range of from 0 to 1.

11. A method according to claim 1 , wherein the particulate copper sulphide has a S:Cu atomic ratio of ≥0.8.

12. A method according to claim 1 , wherein the particulate copper sulphide is a powder with an average particle size, [D 50 ], in a range of from 5 μm to 100 μm.

13. A method according to claim 1 , wherein the dried sorbent contains the particulate copper sulphide in a range of from 0.5% to 75% by weight expressed as CuS in the dried sorbent.

14. A method according to claim 1 , wherein the particulate copper sulphide is present in the coating mixture is in a range of from 50% to 95% by weight of the coating mixture.

15. A method according to claim 1 , wherein the coating mixture consists of the particulate copper sulphide and the particulate calcined, rehydratable alumina.

16. A method according to claim 1 , wherein the surface layers of the coating mixture powder on the aged agglomerates have a thickness in a range of from 1 to 2000 micrometres.

17. A method according to claim 1 , wherein the particulate support material comprises a particulate calcined, rehydratable alumina, the coated agglomerates have a diameter in a range of from 1 mm to 15 mm and the surface layers of the coated agglomerates have a thickness in a range of from 1 μm to 2000 μm thickness.

18. A method according to claim 1 , wherein the coating mixture is applied to the agglomerates under a non-oxidising atmosphere.

19. A method according to claim 1 , wherein the coated agglomerates are aged for a time of from 0.5 hours to 8 hours before drying.

20. A method according to claim 1 , wherein the coated agglomerates are dried at a temperature up to 120° C. under a non-oxidising atmosphere.

21. A dried sorbent obtained by the method of claim 1 .

22. A process for removing a heavy metal from a fluid stream comprising contacting the fluid stream with a dried sorbent according to claim 21 .

Assignees

• Johnson Matthey Plc

Inventors

• Evans Matthew James
• Lunn Matthew David Gwydion
• Partridge Martin Graham
• Young Christopher John

Classifications

• B01J20/3204 Primary

  Inorganic carriers, supports or substrates · CPC title

• B01D2253/1128

  Metal sulfides · CPC title

• C10G25/003

  Specific sorbent material, not covered by C10G25/02 or C10G25/03 · CPC title

• C10G2300/205

  Metal content · CPC title

• B01J20/0237

  Compounds of Cu · CPC title