Method for preparing a sorbent

Patent metadata

Field	Value
Publication number	US-10751687-B2
Application number	US-201615578525-A
Country	US
Kind code	B2
Filing date	May 5, 2016
Priority date	Jun 5, 2015
Publication date	Aug 25, 2020
Grant date	Aug 25, 2020

Abstract

A method is described for preparing a sorbent precursor comprising the steps of: (i) forming agglomerates comprising a particulate support material, (ii) coating the agglomerates with a coating mixture powder comprising a particulate sulphidable copper compound and a particulate calcined, rehydratable alumina to form a coated agglomerate, and (iii) drying the coated agglomerate to form a dried sorbent precursor. The sorbent precursor may be sulphided and used to remove heavy metals such as mercury from fluid streams.

First claim

The invention claimed is:

1. A method for preparing a dried sorbent precursor comprising the steps of:
(i) forming agglomerates comprising a particulate support material in a granulator with a liquid, and ageing the agglomerates to form aged agglomerates of the particulate support material,
(ii) adding a coating mixture powder to the aged agglomerates, wherein the coating mixture powder comprises a particulate sulphidable copper compound and a particulate calcined, rehydratable alumina, to form coated agglomerates comprising the aged agglomerates having surface layers of the coating mixture powder, and
(iii) drying the coated agglomerates to form the dried sorbent precursor.

2. A method according to claim 1 wherein the support material is alumina, metal-aluminate, silicon carbide, silica, titania, zirconia, zinc oxide, aluminosilicate, zeolite, metal carbonate, carbon, or a mixture thereof.

3. A method according to claim 1 , wherein the support material is a particulate calcined, rehydratable alumina.

4. A method according to claim 1 , wherein the calcined rehydratable alumina comprises a calcined amorphous alumina or a transition alumina that is one or more of rho-alumina, chi-alumina, or pseudo gamma-alumina.

5. A method according to claim 1 , wherein the support material is a powder with a D 50 particle size in a range of from 1 μm to 100 μm.

6. A method according to claim 1 , wherein a binder that is a clay binder, cement binder, or organic polymer binder is combined with the support material to form the agglomerates.

7. A method according to claim 6 wherein the binder combined with the support material is a combination of a cement binder and a clay binder.

8. A method according to claim 1 , wherein the coated agglomerates have a diameter in a range of from 1 mm to 15 mm.

9. A method according to claim 1 , wherein the particulate sulphidable copper compound is one or more compounds that is copper oxide, basic copper carbonate, or a precipitated material comprising copper basic carbonate and zinc basic carbonate.

10. A method according to claim 1 , wherein the particulate sulphidable copper compound is a powder with an average particle size, [D 50 ], in a range of from 5 μm to 100 μm.

11. A method according to claim 1 , wherein a copper content of the dried sorbent precursor is in a range of 0.5 to 35% by weight expressed as copper present in the dried sorbent precursor.

12. A method according to claim 1 , wherein the coating mixture powder has a particulate sulphidable copper compound content in a range of from 50% to 95% by weight.

13. A method according to claim 1 , wherein the coating mixture consists of the particulate sulphidable copper compound and the particulate calcined, rehydratable alumina.

14. A method according to claim 1 , wherein the surface layers of the coating mixture powder on the aged agglomerates have a thickness in a range of from 1 to 2000 micrometres.

15. A method according to claim 1 , wherein the support material comprises a particulate calcined, rehydratable alumina, the coated agglomerates have a diameter in a range of from 1 mm to 15 mm and the surface layers of the coated agglomerates have a thickness in a range of from 1 μm to 2000 μm.

16. A method according to claim 1 , wherein the coated agglomerates are aged for 0.5 to 8 hours before drying.

17. A method according to claim 1 , wherein the coated agglomerates are dried at a temperature in a range of from 70 to 150° C.

18. A method for preparing a sorbent comprising preparing the dried sorbent precursor according to claim 1 and subjecting the dried sorbent precursor to a sulphiding step to convert the sulphidable copper compound to copper sulphide.

19. A method according to claim 18 , wherein the sulphiding step is performed by reacting the copper compound with a sulphur compound that is hydrogen sulphide, alkali metal sulphide, ammonium sulphide, elemental sulphur or a polysulphide.

20. A method according to claim 18 , wherein the sulphiding step is performed using hydrogen sulphide at a concentration in a range of from 0.1 to 5% by volume in an inert gas.

21. A method according to claim 18 , wherein the sulphiding step is performed (i) ex-situ in a sulphiding vessel and a sulphiding agent is passed through the sulphiding vessel, or (ii) in situ in a vessel in which it is used to absorb heavy metals.

22. A dried sorbent precursor obtained by the method of claim 1 .

23. A sorbent obtained by the method of claim 18 .

24. A process for removing a heavy metal from a fluid stream comprising contacting the fluid stream with a sorbent of claim 23 .

Assignees

• Johnson Matthey Plc

Inventors

• Evans Matthew James
• Foran Paul Thomas
• Lunn Matthew David Gwydion

Classifications

• B01D2253/102

  Carbon · CPC title

• B01D2257/60

  Heavy metals or heavy metal compounds · CPC title

• B01J20/2803 Primary

  Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products · CPC title

• B01J20/3078

  Thermal treatment, e.g. calcining or pyrolizing · CPC title

• B01J20/0285 Primary

  Sulfides of compounds other than those provided for in B01J20/045 · CPC title