Method of forming reverse osmosis membrane

Patent metadata

Field	Value
Publication number	US-10751668-B2
Application number	US-201615745766-A
Country	US
Kind code	B2
Filing date	Jul 28, 2016
Priority date	Jul 28, 2015
Publication date	Aug 25, 2020
Grant date	Aug 25, 2020

Abstract

A method of forming a reverse osmosis membrane 1 of the present invention includes a coating membrane forming step of forming a coating membrane which is soluble in a predetermined solvent on a surface of a porous support substrate 2 that is insoluble in the solvent, a carbon membrane forming step of forming a carbon membrane 3 on the coating membrane by a physical vapor deposition which deposits carbon as a target material under an atmosphere where rare gas and nitrogen gas are contained, and a removing-by-dissolving step of removing the coating membrane by dissolving the same in the solvent after formation of the carbon membrane 3.

First claim

The invention claimed is:

1. A method of forming a reverse osmosis membrane, comprising:
a coating membrane forming step of forming a coating membrane which is soluble in a predetermined solvent on a surface of a porous support substrate that is insoluble in the solvent so as to block pores provided through the porous support substrate;
a carbon membrane forming step of forming, on the coating membrane, by a physical vapor deposition that deposits carbon as a target material under an atmosphere where rare gas and nitrogen gas are contained and supplying concentration of the nitrogen gas is 9% or more, a carbon membrane which has a diamond-like-carbon structure containing a nitrogen atom and which is configured to be diffusely permeated with a particular material contained in a solution and to separate the particular material as an object targeted for removal; and
a removing-by-dissolving step of, after formation of the carbon membrane, removing the coating membrane by immersing in the solvent a laminate formed of the porous support substrate, the coating membrane and the carbon membrane to dissolve the coating membrane in the solvent, thereby layering the carbon membrane on the porous support substrate.

2. The method of forming a reverse osmosis membrane according to claim 1 , wherein the carbon membrane is formed under an atmosphere where hydrocarbon gas is further contained, in addition to the rare gas and the nitrogen gas, in the carbon membrane forming step.

3. The method of forming a reverse osmosis membrane according to claim 2 , wherein the hydrocarbon gas consists of methane gas.

4. The method of forming a reverse osmosis membrane according to claim 3 , wherein:
the solvent consists of water and/or alcohol; and
the coating membrane is removed by dissolving the same in the water and/or alcohol in the removing-by-dissolving step.

5. The method of forming a reverse osmosis membrane according to claim 4 , wherein:
the porous support substrate comprises a nonwoven fabric-type backing layer and a porous plastic layer provided on the backing layer; and
the coating membrane is formed on the porous plastic layer of the porous support substrate in the coating membrane forming step.

6. The method of forming a reverse osmosis membrane according to claim 3 , wherein:
the porous support substrate comprises a nonwoven fabric-type backing layer and a porous plastic layer provided on the backing layer; and
the coating membrane is formed on the porous plastic layer of the porous support substrate in the coating membrane forming step.

7. The method of forming a reverse osmosis membrane according to claim 2 , wherein:
the solvent consists of water and/or alcohol; and
the coating membrane is removed by dissolving the same in the water and/or alcohol in the removing-by-dissolving step.

8. The method of forming a reverse osmosis membrane according to claim 7 , wherein:
the porous support substrate comprises a nonwoven fabric-type backing layer and a porous plastic layer provided on the backing layer; and
the coating membrane is formed on the porous plastic layer of the porous support substrate in the coating membrane forming step.

9. The method of forming a reverse osmosis membrane according to claim 2 , wherein:
the porous support substrate comprises a nonwoven fabric-type backing layer and a porous plastic layer provided on the backing layer; and
the coating membrane is formed on the porous plastic layer of the porous support substrate in the coating membrane forming step.

10. The method of forming a reverse osmosis membrane according to claim 1 , wherein:
the solvent consists of water and/or alcohol; and
the coating membrane is removed by dissolving the same in the water and/or alcohol in the removing-by-dissolving step.

11. The method of forming a reverse osmosis membrane according to claim 10 , wherein:
the porous support substrate comprises a nonwoven fabric-type backing layer and a porous plastic layer provided on the backing layer; and
the coating membrane is formed on the porous plastic layer of the porous support substrate in the coating membrane forming step.

12. The method of forming a reverse osmosis membrane according to claim 1 , wherein:
the porous support substrate comprises a nonwoven fabric-type backing layer and a porous plastic layer provided on the backing layer; and
the coating membrane is formed on the porous plastic layer of the porous support substrate in the coating membrane forming step.

Assignees

• Kitagawa Ind Co Ltd
• Univ Shinshu

Inventors

• Kitano Hiroki
• Yamaguchi Akio
• Endo Morinobu
• Ortiz Medina Josue

Classifications

• B01D69/1071

  Woven, non-woven or net mesh · CPC title

• B01D71/021

  Carbon · CPC title

• B01D67/0072 Primary

  by deposition from the gaseous phase, e.g. sputtering, CVD, PVD · CPC title

• B01D53/228

  characterised by specific membranes · CPC title

• B01D61/025 Primary

  Reverse osmosis; Hyperfiltration · CPC title