SOFC cathode compositions with improved resistance to SOFC degradation

Patent metadata

Field	Value
Publication number	US-10749188-B2
Application number	US-201916279161-A
Country	US
Kind code	B2
Filing date	Feb 19, 2019
Priority date	Nov 12, 2014
Publication date	Aug 18, 2020
Grant date	Aug 18, 2020

Abstract

A solid oxide fuel cell (SOFC) includes a solid oxide electrolyte with a zirconia-based ceramic, an anode electrode, and a cathode electrode that includes a ceria-based ceramic component and an electrically conductive component. Another SOFC includes a solid oxide electrolyte containing a zirconia-based ceramic, an anode electrode, and a cathode electrode that includes an electrically conductive component and an ionically conductive component, in which the ionically conductive component includes a zirconia-based ceramic containing scandia and at least one of ceria, ytterbia and yttria.

First claim

The invention claimed is:

1. A solid oxide fuel cell (SOFC), comprising:
a solid oxide electrolyte comprising a zirconia-based ceramic;
an anode electrode comprising at least a first portion and a second portion, wherein the first portion is located between the solid oxide electrolyte and the second portion, and wherein the first portion has a lower porosity compared to the second portion; and
a cathode electrode comprising a ceria-based ceramic component and an electrically conductive component;
wherein the electrically conductive component comprises an electrically conductive ceramic selected from the group consisting of lanthanum strontium manganite (LSM), lanthanum calcium manganite (LCM), lanthanum strontium cobalt ferrite (LSCF), lanthanum strontium ferrite (LSF), lanthanum strontium manganese ferrite (LSMF) and lanthanum strontium chromite (LSCr), and lanthanum strontium cobaltite (LSCo); and
wherein the cathode electrode consists essentially of 10-90 wt % of the ceria-based ceramic component, 10-90 wt % of the electrically conductive ceramic, and 0-0.5 wt % of at least one of an additional catalyst material comprising one or more of cobalt, platinum, or ruthenium, and a sintering aid comprising one or more of cobalt, magnesium, nickel, iron, or copper.

2. A solid oxide fuel cell (SOFC), comprising:
a solid oxide electrolyte comprising a zirconia-based ceramic;
an anode electrode comprising at least a first portion and a second portion, wherein the first portion is located between the solid oxide electrolyte and the second portion, and wherein the first portion has a lower porosity compared to the second portion; and
a cathode electrode comprising a ceria-based ceramic component and an electrically conductive component;
wherein the electrically conductive component comprises an electrically conductive ceramic selected from the group consisting of lanthanum strontium manganite (LSM), lanthanum calcium manganite (LCM), lanthanum strontium cobalt ferrite (LSCF), lanthanum strontium ferrite (LSF), lanthanum strontium manganese ferrite (LSMF) and lanthanum strontium chromite (LSCr), and lanthanum strontium cobaltite (LSCo); and
wherein the cathode electrode consists essentially of 10-90 wt % of the ceria-based ceramic component, 10-90 wt % of the electrically conductive ceramic.

3. A solid oxide fuel cell (SOFC), comprising:
a solid oxide electrolyte comprising a zirconia-based ceramic;
an anode electrode; and
a cathode electrode comprising a ceria-based ceramic component and an electrically conductive component, wherein the ceria-based ceramic component includes yttria doped ceria (YDC).

4. The SOFC of claim 1 , wherein the ceria-based ceramic component comprises at least one of samaria doped ceria (SDC), gadolinia doped ceria (GDC), and yttria doped ceria (YDC), and wherein the electrolyte is at least 80 wt % zirconia.

5. The SOFC of claim 4 , wherein the ceria-based ceramic component comprises a formula Ce (1-x) A x O 2 , wherein A comprises at least one of samaria (Sm), gadolinium (Gd), and yttria (Y), wherein x is in a range of around 0.1 to 0.4, and wherein the solid oxide electrolyte comprises scandia stabilized zirconia.

Assignees

• Bloom Energy Corp

Inventors

• Leming Andres
• El Batawi Emad
• Gasda Michael
• Armstrong Tad
• Wilson James

Classifications

• H01M4/92

  Metals of platinum group (H01M4/94 {, H01M4/9058} take precedence) · CPC title

• Y02E60/50

  Fuel cells · CPC title

• H01M4/9033 Primary

  Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites · CPC title

• H01M2300/0077

  based on zirconium oxide · CPC title

• Y02P70/50

  Manufacturing or production processes characterised by the final manufactured product · CPC title