Method to recover free fatty acids from fats and oils

Patent metadata

Field	Value
Publication number	US-10745643-B2
Application number	US-201816114103-A
Country	US
Kind code	B2
Filing date	Aug 27, 2018
Priority date	Nov 13, 2012
Publication date	Aug 18, 2020
Grant date	Aug 18, 2020

Abstract

Methods for producing oil from distillers corn oil having high free fatty acid content are provided. In the method, distiller's corn oil is treated with a mixture including an alcohol to result in a low-free fatty acid oily phase and an alcohol phase. The mixture may also include an alkali. The alcohol may be a monohydric alcohol and an aqueous alcohol, such as an aqueous alcohol having a concentration of at least about 15% alcohol-by-weight. The low-free fatty acid phase may include oil and at least one impurity. The low-free fatty acid phase may be cooled, and the oil may be separated from the at least one impurity using membrane filtration.

First claim

The invention claimed is:

1. A method of producing oil comprising:
receiving a stream of distillers corn oil having a high free fatty acid content of at least 5%;
treating the distillers corn oil having the high free fatty acid content with a monohydric alcohol to form a low-free fatty acid oily phase and an alcohol phase, wherein the monohydric alcohol has a concentration of at least 17% alcohol by weight and is a solvent;
wherein the low-free fatty acid oily phase comprises oil and at least one impurity;
cooling the low free-fatty acid oily phase to a temperature range of 5 to 20 degrees Celsius; and
separating the low-free fatty acid oily phase into oil and the at least one impurity by using membrane filtration.

2. A method of producing oil comprising:
receiving distillers corn oil having a high free fatty acid content of at least 5%;
treating the distillers corn oil having a high free fatty acid content with a mixture comprising a monohydric alcohol and an alkali to form a low-free fatty acid oily phase and an alcohol phase wherein the monohydric alcohol has a concentration of at least 16% alcohol by weight and is a solvent;
wherein the low free-fatty acid oily phase comprises oil and at least one impurity, the at least one impurity selected from the group consisting of free fatty acid soaps, waxes, unsaponifiables, and combinations thereof; and
separating the low-free fatty acid oily phase into oil and the at least one impurity by using membrane filtration.

3. A method of producing oil comprising:
receiving a stream of fats and oils;
treating the stream of fats and oils having a high free fatty acid content of at least 5% with a mixture comprising a monohydric alcohol and an alkali to form a low-free fatty acid oily phase and an alcohol phase, wherein the monohydric alcohol has a concentration of at least about 17% alcohol by weight and is a solvent;
wherein the low free-fatty acid oily phase comprises oil and impurities comprising free fatty acid soaps and waxes;
cooling the low free-fatty acid oily phase to a temperature range of 5 to 30 degrees Celsius; and
separating the low free-fatty acid oily phase into the free fatty acids soaps and waxes and the oil by using membrane filtration.

4. The method of claim 1 , wherein the monohydric alcohol comprises at least one of methanol, ethanol, propanol, isopropanol, butanol, isobutanol, or pentanol.

5. The method of claim 2 , wherein the monohydric alcohol comprises at least one of methanol, ethanol, propanol, isopropanol, butanol, isobutanol, or pentanol.

6. The method of claim 2 , wherein the alkali comprises at least one of hydroxide, oxide, carbonate, amine, amide, sodium hydroxide, potassium hydroxide, magnesium hydroxide, calcium hydroxide, sodium amide, or ammonia.

7. The method of claim 3 , wherein the stream of fats and oil comprises at least corn oil, high acid grease, high acid tallow, flotation oils, flotation greases, fatty acid streams, waste frying grease.

8. The method of claim 3 , wherein the cooling the low free-fatty acid oily phase is at a temperature of 10 degrees Celsius.

9. The method of claim 3 , wherein the cooling the low free-fatty acid oily phase is at a temperature of 20 degrees Celsius.

Assignees

• Icm Inc

Inventors

• Gallop Charles C
• Dasari Mohan Prasad
• Warren Hugh Tallant
• Knox Kidron Joel

Classifications

• C11B3/00 Primary

  Refining fats or fatty oils · CPC title

• C11B3/006

  by extraction · CPC title

• C11B7/0008

  by differences of solubilities, e.g. by extraction, by separation from a solution by means of anti-solvents (addition of a minor amount of solvent intended to lower the melting point C11B7/0083, C11B7/0091) · CPC title

• C11B3/008

  by filtration, e.g. including ultra filtration, dialysis (C11B3/005 takes precedence) · CPC title

• C11B7/0066

  between two or more non-miscible solvent phases · CPC title