Crosslinkable materials based on organyl oxysilane-terminated polymers

Patent metadata

Field	Value
Publication number	US-10745560-B2
Application number	US-201716076862-A
Country	US
Kind code	B2
Filing date	Jan 31, 2017
Priority date	Feb 12, 2016
Publication date	Aug 18, 2020
Grant date	Aug 18, 2020

Abstract

Moisture curing alkoxysilyl-functional polymer compositions containing a high phenyl-content silicone resin and carbon black exhibit high adhesion to substrates, high tensile strength, very high elongation, and high tear strength without becoming unduly hard.

First claim

The invention claimed is:

1. A crosslinkable composition, comprising:
(A) 100 parts by weight of one or more compounds of the formula
Y—[(CR 1 2 ) b -SiR a (OR 2 ) 3-a ] x   (I),

where
Y denotes an x-valent polymer radical bonded to a carbon of the (CR 1 2 ) b group via nitrogen, oxygen, sulfur or carbon,
R are identical or different and represent monovalent, optionally substituted hydrocarbyl radicals,
R 1 are identical or different and represent hydrogen or monovalent, optionally substituted hydrocarbyl radicals which are optionally attached to the carbon atom of (CR 1 ) b via nitrogen, phosphorus, oxygen, sulfur or a carbonyl group,
R 2 are identical or different and represent hydrogen or a monovalent, optionally substituted hydrocarbyl radical,
x is an integer from 1 to 10,
a is identical or different and is 0, 1 or 2, and
b is identical or different and is an integer from 1 to 10,
(B) at least 5 parts by weight of at least one silicone resin comprising units of the formula
R 3 c (R 4 O) d R 5 e SiO (4-c-d-e)/2   (II),

where
R 3 are identical or different and denote hydrogen, a monovalent, SiC-bonded, optionally substituted aliphatic hydrocarbyl radical or a divalent, optionally substituted, aliphatic hydrocarbyl radical which bridges two units of the formula (II),
R 4 are identical or different and represent hydrogen or a monovalent, optionally substituted hydrocarbyl radical,
R 5 are identical or different and represents a monovalent, SiC-bonded, optionally substituted aromatic hydrocarbyl radical,
c is 0, 1, 2 or 3,
d is 0, 1, 2 or 3, and
e is 0, 1 or 2,
with the proviso that the sum of c+d+e is less than or equal to 3 and in at least 40% of the units of the formula (II) the sum c+e is 0 or 1, and
(C) at least 10 parts by weight of carbon black.

2. The crosslinkable composition of claim 1 , comprising:
(A) 100 parts by weight of compounds of the formula
Y—[(CR 1 2 ) b -SiR a (OR 2 ) 3-a ] x   (I),

where
Y denotes an x-valent polymer radical bonded via nitrogen, oxygen, sulfur or carbon and comprising polyurethanes or polyoxyalkylenes as its polymer chain,
R are identical or different and represent a monovalent, optionally substituted hydrocarbyl radical,
R 1 are identical or different and represent hydrogen or a monovalent, optionally substituted hydrocarbyl radical optionally attached to carbon via nitrogen, phosphorus, oxygen, sulfur or a carbonyl group,
R 2 are identical or different and represent hydrogen atom or a monovalent, optionally substituted hydrocarbyl radical,
x is an integer from 1 to 10,
a is identical or different and is 0, 1 or 2, and
b is identical or different and is an integer from 1 to 10,
(B) at least 5 parts by weight of silicone resin(s) comprising units of the formula
R 3 c (R 4 O) d R 5 e SiO (4-c-d-e)/2   (II),

where
R 3 are identical or different and denote hydrogen, a monovalent, SiC-bonded, optionally substituted aliphatic hydrocarbyl radical or a divalent, optionally substituted, aliphatic hydrocarbyl radical which bridges two units of the formula (II),
R 4 are identical or different and represent hydrogen or a monovalent, optionally substituted hydrocarbyl radical,
R 5 are identical or different and represent a monovalent, SiC-bonded, optionally substituted aromatic hydrocarbyl radical,
c is 0, 1, 2 or 3,
d is 0, 1, 2 or 3, and
e is 0, 1 or 2,
with the proviso that the sum of c+d+e is less than or equal to 3 and in at least 40% of the units of the formula (II) the sum c+e is 0 or 1, and
(C) at least 10 parts by weight of carbon black.

3. The crosslinkable composition of claim 2 , wherein component (B) comprises silicone resins (B1) which, based on the total number of units of the formula (II), have at least 30% of units of the formula (II) in which the value of e is 1 and the value of c is 0.

4. The crosslinkable composition of claim 2 , wherein component (C) comprises furnace blacks.

5. The crosslinkable composition of claim 2 , wherein component (C) comprises furnace blacks having a BET surface area of 30 to 600 m 2 /g and an oil number of between 40 and 180 ml/100 g.

6. A method for producing a composition of claim 2 , comprising mixing the individual components in any order.

7. A shaped article produced by crosslinking a composition of claim 2 .

8. A method for producing an assembly of materials, comprising applying a composition of claim 2 to at least one substrate, and subsequently crosslinking the composition.

9. The crosslinkable composition of claim 1 , wherein component (B) comprises silicone resins (B1) which, based on the total number of units of the formula (II), have at least 30% of units of the formula (II) in which the value of e is 1 and the value of c is 0.

10. The crosslinkable composition of claim 1 , wherein component (C) comprises furnace blacks.

11. The crosslinkable composition of claim 1 , wherein component (C) comprises furnace blacks having a BET surface area of 30 to 600 m 2 /g and an oil number of between 40 and 180 ml/100 g.

12. The crosslinkable composition of claim 1 , comprising:
(A) 100 parts by weight of compound(s) of the formula (I),
(B) 5-300 parts by weight of silicone resin(s) comprising units of the formula (II),
(C) 10-200 parts by weight of carbon black,
(D) 0.1-25 parts by weight of organosilicon compound(s) comprising units of the formula
D h Si(OR 7 ) g R 6 f O (4-f-g-h)/2   (III),

in which
R 6 are identical or different and denote a monovalent, optionally substituted, SiC-bonded, nitrogen-free organic radical,
R 7 are identical or different and denote hydrogen or an optionally substituted hydrocarbyl radical,
D are identical or different and denote a monovalent, SiC bonded radical having at least one nitrogen atom not bonded to a carbonyl group (C═O)
f is 0, 1, 2 or 3,
g is 0, 1, 2 or 3, and
h is 0, 1, 2, 3 or 4,
with the proviso that the sum of f+g+h is less than or equal to 4 and there is at least one radical D present per molecule,
(E) 10-1000 parts by weight of fillers,
optionally (F) plasticizers,
optionally (G) catalysts,
optionally (H) adhesion promoters,
optionally (I) water scavengers,
optionally (J) additives, and
optionally (K) adjuvants.

13. A method for producing a composition of claim 12 , comprising mixing the individual components in any order.

14. A shaped article produced by crosslinking a composition of claim 12 .

15. A method for producing an assembly of materials, comprising applying a composition of claim 12 to at least one substrate, and subsequently crosslinking the composition.

16. The crosslinkable composition of claim 12 , comprising:
(A) 100 parts by weight of compounds of the formula (I) where Y is an x-valent polymer radical which is bonded via nitrogen, oxygen, sulfur or carbon and which comprises polyurethanes or polyoxyalkylenes as its polymer chain,
(B) 10-200 parts by weight of silicone resins comprising units of the formula (II) in which R 5 is a phenyl radical, and which, based in each case on the total number of units of the formula (II), have at least 70% of units of the formula (II) in which e has a value of 1,
(C) 20-200 parts by weight of furnace black,
(D) 0.1-25 parts by weight of silanes of the formula (III),
(E1) 10-900 part

Assignees

• Wacker Chemie Ag

Inventors

• Stanjek Volker
• Zander Lars

Classifications

• C08G65/336

  containing silicon · CPC title

• C08G77/80

  Siloxanes having aromatic substituents, e.g. phenyl side groups · CPC title

• C08K3/26

  Carbonates; Bicarbonates · CPC title

• C08L71/02 Primary

  Polyalkylene oxides · CPC title

• C08K2201/006

  Additives being defined by their surface area · CPC title