Process for reclaiming scrap or unused epoxy resin prepreg

Patent metadata

Field	Value
Publication number	US-10744679-B2
Application number	US-201715762876-A
Country	US
Kind code	B2
Filing date	Jun 7, 2017
Priority date	Jun 20, 2016
Publication date	Aug 18, 2020
Grant date	Aug 18, 2020

Abstract

Method for recycling scrap that contains one or more heat resistant fibers and from 25 to 60 wt. %, based on the total weight of the scrap, of an at least partially uncured to fully uncured two component thermosetting resin mixture of (i) one or more thermosetting resins, and (ii) a solid hardener, the methods comprising shredding the scrap to an average size of from 3 to 50 mm, mixing the shredded scrap, preferably after preheating the scrap, to provide a fluid material charge and then compression molding the fluid material charge to make a cured composite material.

First claim

We claim:

1. A method for reclaiming scrap containing from 25 to 60 wt. %, based on the total weight of the scrap, of an at least partially uncured to fully uncured two component thermosetting resin mixture of (i) one or more thermosetting resins, and (ii) a latent hardener and/or catalyst, and one or more heat resistant fibers, the method comprising shredding the scrap, then preheating the scrap to from 40 to 100° C, and then batch mixing the preheated shredded scrap to provide a fluid material charge and then compression molding the fluid material charge to make a cured composite material.

2. The method as claimed in claim 1 , wherein the (i) one or more thermosetting resins comprises epoxy resin, vinyl ester resin, or polyester.

3. The method as claimed in claim 1 , wherein in the method, the scrap contains the one or more heat resistant fibers impregnated or infused with the one or more at least partially uncured to fully uncured two component thermosetting resin mixture, and the method comprises shredding the scrap material into pieces having an average size of from 3 to 50 mm, mixing the shredded scrap material to form a fluid charge by (a) extruding the shredded material at a temperature A which is at least 10° C. above the glass transition temperature Tg as determined by Dynamic differential scanning calorimetry of the (i) thermosetting resin in the uncured two component thermosetting resin mixture that has Temperature B, the highest Tg as determined by Dynamic differential scanning calorimetry of the thermosetting resins in the scrap material, or by (b) preheating the shredded scrap material to at least 5° C. above the Temperature B, followed by batch mixing the shredded material at least the Temperature B; followed by compression molding the fluid charge to make a cured composite,
further wherein, in (a) or (b), if needed, the mixing includes combining the shredded scrap material with a sufficient amount of one or more uncured two component thermosetting resin mixture which has a Tg of below Temperature B to provide a fluid material charge having a total of from 25 to 60 wt. %, based on the total weight of the scrap, of the uncured two component thermosetting resin mixture.

4. The method as claimed in claim 1 , wherein the mixing includes combining the shredded scrap material with any of (i) a thermosetting resin having a Tg above 30° C., a liquid thermosetting resin, or mixtures thereof; (ii) virgin chopped fiber; one or more catalysts, hardeners, tougheners or mold release agents; and (iii) molding materials, wherein in (ii) or (iii), wherein the resulting shredded scrap material contains from 25 to 60 wt. % of total uncured thermosetting resin, based on the total weight of the resulting shredded scrap material.

5. The method as claimed in claim 1 , further comprising shaping the fluid charge into a desired shape by using nip rolls, or a laminator, or by casting into different molds, prior to compression molding.

6. The method as claimed in claim 1 , wherein the uncured two component thermosetting resin mixture comprises (i) one or more liquid epoxy resins.

7. The method as claimed in claim 1 , wherein the uncured two component thermosetting resin mixture comprises (i) one or more epoxy resins that has a viscosity, as determined with Rheometer at oscillatory shear rate sweep from 0.1-100 rad/sec at 25% strain in a 25 mm parallel plate geometry, of from 500 to 300,000 mPa·s at room temperature.

8. The method as claimed in claim 1 , wherein the one or more heat resistant fibers is chosen from carbon fiber, glass fiber, ceramic fiber, acrylonitrile fibers, aramid fibers, or their admixtures.

9. The method as claimed in claim 1 , wherein the one or more latent hardener and/or catalyst, is a solid catalyst chosen from a urea containing catalyst, a urea resin containing catalyst, a dicyandiamide and an oxazolidine group containing catalyst.

Assignees

• Dow Global Technologies Llc

Inventors

• Bank David H
• Chaudhary Amit K
• Sun Xiaofei

Classifications

• B29B17/0042 Primary

  for shaping parts, e.g. multilayered parts with at least one layer containing regenerated plastic · CPC title

• B29B17/0026 Primary

  by agglomeration or compacting · CPC title

• B29C2043/3455

  for particles, powder, fibres, e.g. fluidized or sprayed · CPC title

• B29B17/0412

  to large particles, e.g. beads, granules, flakes, slices · CPC title

• B29K2105/16

  Fillers · CPC title