Method for making a lightweight gypsum composition with internally generated foam and products made from same

Patent metadata

Field	Value
Publication number	US-10737981-B2
Application number	US-201715711583-A
Country	US
Kind code	B2
Filing date	Sep 21, 2017
Priority date	Oct 12, 2016
Publication date	Aug 11, 2020
Grant date	Aug 11, 2020

Abstract

A gypsum-based composition of calcium sulfate hemihydrate with (a) alum and calcium carbonate and/or (b) zeolite and sodium percarbonate for making foamed gypsum slurry. A method to make foamed gypsum slurry from the composition. A method to make foamed gypsum product from the composition. A cavity wall having a cavity filled with the foamed gypsum product.

First claim

What is claimed is:

1. A gypsum-based composition comprising a mixture of ingredients, based on 100 parts by weight of said ingredients on a water free basis, comprising:
at least 70 wt. % calcium sulfate hemihydrate;
a combination of compounds for generating CO 2 gas when mixed with water comprising:
3 to 20 wt. % calcium carbonate and 3 to 15 wt. % at least one aluminum compound selected from aluminum sulfate and potassium aluminum sulfate for generating the CO 2 gas;

0.2 to 5 wt. % cellulose thickener.

2. The composition of claim 1 , wherein there is at least 87 wt. % calcium sulfate hemihydrate, 3 to 20 wt. % calcium carbonate, wherein there is 0.2 to 3 wt. % cellulose thickener, wherein the mixture ingredients further comprises; based on 100 parts by weight of said ingredients of said mixture, at least one of:
0.1 to 1 wt. % chelating agent; and
0.05 to 1 wt. % biocide.

3. The composition of claim 1 , wherein there is at least 87 wt. % calcium sulfate hemihydrate, wherein there is 0.2 to 3 wt. % cellulose thickener,
wherein the mixture ingredients further comprise; based on 100 parts by weight of said ingredients of said mixture, at least one additive selected from the group consisting of:
0.1 to 10 wt. % acrylate thickener selected from at least one member of the group consisting of sodium polyacrylates and water-soluble copolymers based on acrylic and (meth)acrylic acid;
0.1 to 10 wt. % casein, gum arabic, guar gum, tragacanth gum, starch, sodium alginate;
0.02 to 1 wt. % citric acid, tartaric acid, malic acid, acetic acid, boric acid;
0.02 to 2 wt. % alkali metal salt of citric acid;
0.02 to 2 wt. % accelerator, the accelerator selected from the group consisting of potassium sulfate, an organic phosphonic compound, a phosphate-containing compound, and a calcium sulfate dihydrate and sugar-containing composition;
0.1 to 5 wt. % foaming agent;
1 to 20 wt. % latex polymer;
0.01 to 1 wt. % 2-amino-2-methyl-1-propanol;
0.05 to 2 wt. % polycarboxylate ether dispersant;
0.05 to 2 wt. % polyphosphate;
0.01 to 2 wt. % naphthalene dispersant or lignosulfonate dispersant;
0.05 to 1 wt. % biocide;
0.01 to 0.5 wt. % silicon based defoamer;
1 to 5 wt. % inorganic particles selected from clay, pigment particles, and combinations thereof;
0.05 to 1% polyethylene oxide (PEO).

4. The composition of claim 2 , wherein the cellulose thickener is selected from at least one member of the group consisting of hydroxy propyl methyl cellulose, hydroxy ethyl methyl cellulose, hydroxy ethyl cellulose, methyl cellulose, methyl ethyl cellulose, ethyl cellulose, and carboxy methyl cellulose, wherein the chelating agent comprises sodium polyacrylate.

5. The composition of claim 3 , wherein the ingredients comprise, based on 100 parts by weight of said ingredients:
at least 70 wt. % calcium sulfate hemihydrate;
3 to 20 wt. % calcium carbonate;
3 to 15 wt. % aluminum sulfate;
0 to 2 wt. % sodium citrate;
0 to 2 wt. % the accelerator comprising calcium sulfate dihydrate and sugar;
0.2 to 3 wt. %, cellulose thickener comprising hydroxy methyl propyl cellulose;
0-3 wt. % said foaming agent, wherein said foaming agent is selected from the group consisting of alkyl benzene sulfonate, fatty acid salts, sodium lauryl sulfate, alkyl sulfate salts, sodium lauryl ether sulfate, sodium alkyl ether sulfate, sodium C14-16 olefin sulfonate, alpha-olefin sulfonates, phosphate esters, sulphosuccinates, alkyl phenol ether sulfates; and isethionates;
0 to 20 wt. % latex comprising surfactant and latex polymer dispersed as solids in aqueous medium, said latex polymer is selected from at least one member of the group consisting of acrylic polymer and styrene butadiene polymer;
0 to 1 wt. % 2-amino-2-methyl-1-propanol;
0 to 1 wt. % modifier comprising calcium hydroxide;
0.1 to 2 wt. % dispersant selected from at least one member of the group consisting of polycarboxylate dispersant; polyphosphate dispersant, and naphthalene dispersant,
wherein the polycarboxylate dispersant comprises a polycarboxylic ether dispersant,
wherein the naphthalene dispersant is selected from at least one of beta-naphthalene sulfonate, naphthalene sulfonate formaldehyde condensate and sodium naphthalene sulfate formaldehyde condensate,
wherein the polyphosphate dispersant is selected from at least one of the group sodium trimetaphosphate (STMP), sodium tripolyphosphate (STPP), potassium tripolyphosphate (KTPP), tetrasodium pyrophosphate (TSPP), tetrapotassium pyrophosphate, and tetrapotassium pyrophosphate (TKPP);
0 to 2 wt. % acrylate thickener selected from at least one member of the group consisting of sodium polyacrylate, acrylic acid/acrylamide and (meth)acrylic acid/acrylic ester copolymers;
0 to 1 wt. % chelating agent selected from
Diethylenetriaminepentaacetic acid (DTPA)
Ethylenediaminetetraacetic acid (EDTA)
Sodium polyacrylate
Polyphosphate, wherein if the polyphosphate is also present as a dispersant the polyphosphate present as a chelating agent is in addition to the polyphosphate present as a dispersant;

0 to 0.5 wt. % silicon based defoamer;
0 to 5 wt. % inorganic particles selected from clay, pigment particles, and combinations thereof;
0-10% wt. % of lightweight aggregate.

6. The composition of claim 1 , wherein the aluminum compound are particles of powder encapsulated in a shell for a controlled release of the powder when adequate shear force is applied to the particles of powder encapsulated particles in the shell in a slurry comprising the particles during a mixing process comprising mixing the slurry.

7. The composition of claim 1 , wherein the aluminum compound are particles coated with a water soluble coating.

8. The composition of claim 1 , wherein the ingredients further comprise lightweight aggregate selected from at least one of perlite and polystyrene.

9. A method of making a foamed gypsum slurry, comprising mixing:
water; and
the composition of claim 1 to form the foamed gypsum slurry, wherein the water to calcium sulfate hemihydrate weight ratio to 0.2-2:1, this water being in addition to water of a latex aqueous medium, if present;
wherein the foamed gypsum slurry has 15 to 90 volume percent gas bubbles.

10. The method of claim 9 , wherein the aluminum compound initially comprises alum powder particles encapsulated in a shell and there is a controlled release of the alum powder when sufficient shear force is applied to the encapsulated alum powder particles in the slurry during the mixing.

11. The method of claim 9 , wherein the calcium carbonate is encapsulated with a coating comprising a member of the group consisting of ethyl cellulose, polyvinyl alcohol, gelatin, sugar, and sodium alginate.

12. The method of claim 9 , wherein the aluminum compound is encapsulated with a coating comprising a member of the group consisting of ethyl cellulose, polyvinyl alcohol, gelatin, sugar, and sodium alginate.

13. A method of making a foamed gypsum product, comprising mixing:
water; and
the composition of claim 1 to form a foamed gypsum slurry, wherein the water to calcium sulfate hemihydrate weight ratio to 0.2-2:1;
wherein calcium sulfate hemihydrate in the foamed gypsum slurry converts to calcium sulfate dihydrate and sets and dries to form the foamed gypsum product,
wherein the foamed gypsum product resulting from the set and dried foamed gypsum slurry has a density of 10 to 55 pounds/cubic foot,
wherein the foamed gypsum product has a total void volume of 30 to 90 volume percent.

Assignees

• United States Gypsum Co

Inventors

• Emami Samar
• Immordino Salvatore C
• Negri Robert H
• Pelot David D
• Grussing Jeffrey F
• Ruiz Castañeda Juan Carlos
• Nelson Christopher R
• Roxburgh John Jason
• Veeramasuneni Srinivas

Classifications

• C04B38/02 Primary

  by adding chemical blowing agents · CPC title

• C04B40/00

  Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability (active ingredients C04B22/00 - C04B24/00; hardening of a well-defined composition C04B26/00 - C04B28/00; making porous, cellular or lightening C04B38/00; mechanical aspects B28, e.g. conditioning the materials prior to shaping B28B17/02) · CPC title

• C04B22/10

  containing carbon in the anion, e.g. carbonates · CPC title

• C04B40/0046

  characterised by their processing, e.g. sequence of mixing the ingredients when preparing the premixtures · CPC title

• C04B22/068

  Peroxides, e.g. hydrogen peroxide · CPC title