Method for producing cell structure

Patent metadata

Field	Value
Publication number	US-10734665-B2
Application number	US-201615752389-A
Country	US
Kind code	B2
Filing date	Aug 5, 2016
Priority date	Aug 17, 2015
Publication date	Aug 4, 2020
Grant date	Aug 4, 2020

Abstract

A method for producing a cell structure includes: a step of firing a laminated body of a layer containing an anode material and a layer containing a solid electrolyte material, to obtain a joined body of an anode and a solid electrolyte layer; a step of laminating a layer containing a cathode material on a surface of the solid electrolyte layer, and firing the obtained laminated body to obtain a cathode. The anode material contains a metal oxide Ma1 and a nickel compound. The metal oxide Ma1 is a metal oxide having a perovskite structure represented by A1 x1 B1 1-y1 M1 y1 O 3-δ (wherein: A1 is at least one of Ba, Ca, and Sr; B1 is at least one of Ce and Zr; M1 is at least one of Y, Yb, Er, Ho, Tm, Gd, In, and Sc; 0.85≤x1≤0.99; 0<y1≤0.5; and δ is an oxygen deficiency amount).

First claim

The invention claimed is:

1. A method for producing a cell structure, the method comprising:
a first step of preparing a cathode material, a solid electrolyte material having proton conductivity, and an anode material;
a second step of laminating a layer containing the anode material and a layer containing the solid electrolyte material to obtain a first laminated body, and firing the obtained first laminated body to form a joined body of an anode and a solid electrolyte layer; and
a third step of laminating a layer containing the cathode material on a surface of the solid electrolyte layer to obtain a second laminated body, and firing the obtained second laminated body to form a cathode, wherein
anode material contains a metal oxide Ma2, a compound Ma3, and a nickel compound,
the metal oxide Ma2 contains an element A1, an element B1, an element M1, and oxygen as constituent elements,
the metal oxide Ma2 is a metal oxide having a perovskite structure represented by formula (II):
A1 x2 B1 1-y2 M1 y2 O 3-δ

(wherein: Al is at least one element selected from the group consisting of barium, calcium, and strontium; B1 is at least one element selected from the group consisting of cerium and zirconium; M1 is at least one element selected from the group consisting of yttrium, ytterbium, erbium, holmium, thulium, gadolinium, indium, and scandium; x2 is a number that satisfies 0.99<x2≤1; y2 is a number that satisfies 0<y2≤0.5; and δ is an oxygen deficiency amount),
the compound Ma 3 does not contain the element Al and contains at least one of the element B1 and the element M1, and
in the first step, the metal oxide Ma2 and the compound Ma3 are mixed such that a ratio x3 of the element A1 to the sum of the element B1 and the element M1 is a number that satisfies 0.85≤x3≤0.99.

2. The method for producing the cell structure according to claim 1 , wherein
in the formula (II),
the A1 contains barium,
the B1 contains zirconium,
the M1 contains yttrium, and
the compound Ma3 contains zirconium dioxide doped with yttrium.

3. The method for producing the cell structure according to claim 1 , further comprising a fourth step of disposing an oxidant passage for supplying an oxidant to the cathode and disposing a fuel passage for supplying fuel to the anode, after the third step.

Assignees

• Sumitomo Electric Industries
• Univ Kyoto

Inventors

• Higashino Takahiro
• Miyamoto Kazunari
• Noda Yohei
• Hiraiwa Chihiro
• Mizuhara Naho
• Tawarayama Hiromasa
• Takeuchi Hisao
• Majima Masatoshi
• Uda Tetsuya
• Han Donglin

Classifications

• C04B2235/656

  characterised by specific heating conditions during heat treatment · CPC title

• C04B2235/3213

  Strontium oxides or oxide-forming salts thereof · CPC title

• C04B2235/80

  Phases present in the sintered or melt-cast ceramic products other than the main phase · CPC title

• H01M2300/0077

  based on zirconium oxide · CPC title

• C04B35/63416

  Polyvinylalcohols [PVA]; Polyvinylacetates · CPC title