Graphene dispersion, method for producing electrode paste, and method for producing electrode

Patent metadata

Field	Value
Publication number	US-10734652-B2
Application number	US-201716077623-A
Country	US
Kind code	B2
Filing date	Mar 9, 2017
Priority date	Mar 9, 2016
Publication date	Aug 4, 2020
Grant date	Aug 4, 2020

Abstract

The purpose of the present invention is to provide a graphene dispersion which has high dispersibility and which is capable of exhibiting high electrical conductivity and ionic conductivity when used as a raw material for producing an electrode material. The present invention provides a graphene dispersion including a graphene, an amine compound having a molecular weight of 150 or less, and an organic solvent, wherein the mass ratio of an amine compound to the graphene is 0.005 or more and 0.30 or less.

First claim

The invention claimed is:

1. A graphene dispersion comprising a graphene, an amine compound having a molecular weight of 150 or less, and an organic solvent, wherein the mass ratio of the amine compound to the graphene is 0.02 or more and 0.15 or less, wherein the organic solvent is an organic solvent containing 50% by mass or more of N-methylpyrrolidone, wherein the amine compound is a compound having an alcoholic hydroxyl group, and wherein a solid content is 1.5% by mass or more and 5% by mass or less.

2. The graphene dispersion according to claim 1 , wherein the amine compound is a primary amine compound.

3. The graphene dispersion according to claim 1 , wherein the amine compound is isobutanolamine.

4. The graphene dispersion according to claim 1 , wherein the element ratio of oxygen to carbon (O/C ratio) as measured by X-ray photoelectron spectroscopy in the graphene is 0.06 or more and 0.30 or less.

5. The graphene dispersion according to claim 1 , wherein the element ratio of nitrogen to carbon (N/C ratio) as measured by X-ray photoelectron spectroscopy in the graphene is 0.005 or more and 0.030 or less.

6. The graphene dispersion according to claim 1 , wherein the median diameter of the graphene is 1 μm or more and 15 μm or less.

7. The graphene dispersion according to claim 1 , wherein the specific surface area of the graphene is 80 m 2 /g or more and 250 m 2 /g or less.

8. The graphene dispersion according to claim 1 , wherein a viscosity of the graphene dispersion under the condition of a temperature of 23° C. and a shear velocity of 1 s −1 , as a dispersion, a solid content of which is adjusted to 2% by mass with the organic solvent, is 30 cp or less.

9. The graphene dispersion according to claim 1 , wherein a viscosity of the graphene dispersion under the condition of a temperature of 23° C. and a shear velocity of 1 s −1 , as a dispersion, the solid content of which is adjusted to 3% by mass with the organic solvent, is 20000 cp or less.

10. The graphene dispersion according to claim 1 , wherein a content of a compound having a mass average molecular weight of 3000 or more is 0.5% by mass or less.

11. A method for producing an electrode paste, comprising mixing the graphene dispersion according to claim 1 , an electrode active material, a binder, and an appropriate amount of a solvent as necessary.

12. A method for producing an electrode, comprising applying to a current collector the electrode paste produced by the production method according to claim 11 , and drying the electrode paste.

Assignees

• Toray Industries

Inventors

• Wu Zhenqi
• Chen Zhijun
• Sun Peiyu
• Tamaki Eiichiro
• Kawasaki Manabu
• Liu Gangqiao

Classifications

• H01M10/052

  Li-accumulators · CPC title

• H01M4/0404

  by coating on electrode collectors · CPC title

• H01M4/625 Primary

  Carbon or graphite · CPC title

• H01M4/139

  Processes of manufacture · CPC title

• C01B32/194 Primary

  After-treatment · CPC title