Exhaust gas purification catalyst

Patent metadata

Field	Value
Publication number	US-10731532-B2
Application number	US-201615561738-A
Country	US
Kind code	B2
Filing date	Mar 24, 2016
Priority date	Mar 27, 2015
Publication date	Aug 4, 2020
Grant date	Aug 4, 2020

Abstract

The problem of the present invention is to provide an exhaust gas purification catalyst which can exhibit sufficient purification performance under a high Ga condition while having a resistance to stress such as high-temperature and poisonous substances. The present invention relates to an exhaust gas purification catalyst comprising two or more catalyst coating layers on a substrate, wherein a lower catalyst coating layer that is present lower with respect to an uppermost catalyst coating layer has a structure where a large number of voids are included and high-aspect-ratio pores having an aspect ratio of 5 or more account for a certain proportion or more of the whole volume of voids, thereby to improve gas diffusivity in the lower catalyst coating layer.

First claim

The invention claimed is:

1. An exhaust gas purification catalyst comprising two or more catalyst coating layers on a substrate, wherein:
each catalyst coating layer comprises a catalyst particle having a different composition from that of an adjacent catalyst coating layer;
in a lower catalyst coating layer that is present lower with respect to an uppermost catalyst coating layer,
an average thickness of the coating layer is in a range from 25 μm to 160 μm,
a porosity measured by a weight-in-water method is in a range from 50 to 80% by volume, and
high-aspect-ratio pores having an aspect ratio of 5 or more account for 0.5 to 50% by volume of the whole volume of voids, and

the high-aspect-ratio pore has an equivalent circle diameter of from 2 μm to 50 μm in a cross-sectional image of a catalyst coating layer cross section perpendicular to an exhaust gas flow direction and has an average aspect ratio of from 10 to 50.

2. The exhaust gas purification catalyst according to claim 1 , wherein in the lower catalyst coating layer, the high-aspect-ratio pore is oriented such that an 80% cumulative angle, in a cumulative angle distribution on an angle basis, of an angle (cone angle) between a vector in a longitudinal direction of the high-aspect-ratio pore and a vector in an exhaust gas flow direction of the substrate is in a range from 0 to 45 degrees.

3. The exhaust gas purification catalyst according to claim 1 , wherein a 15% cumulative size, in a cumulative particle size distribution on a cross-sectional area basis, of the catalyst particle contained in the lower catalyst coating layer is in a range from 3 μm to 10 μm.

4. The exhaust gas purification catalyst according to claim 2 , wherein a 15% cumulative size, in a cumulative particle size distribution on a cross-sectional area basis, of the catalyst particle contained in the lower catalyst coating layer is in a range from 3 μm to 10 μm.

5. The exhaust gas purification catalyst according to claim 1 , wherein in the lower catalyst coating layer, an amount of coating is in a range from 50 to 300 g per liter of the volume of the substrate.

6. The exhaust gas purification catalyst according to claim 2 , wherein in the lower catalyst coating layer, an amount of coating is in a range from 50 to 300 g per liter of the volume of the substrate.

7. The exhaust gas purification catalyst according to claim 3 , wherein in the lower catalyst coating layer, an amount of coating is in a range from 50 to 300 g per liter of the volume of the substrate.

8. The exhaust gas purification catalyst according to claim 4 , wherein in the lower catalyst coating layer, an amount of coating is in a range from 50 to 300 g per liter of the volume of the substrate.

9. A method for producing an exhaust gas purification catalyst comprising two or more catalyst coating layers on a substrate, the method comprising the step of forming a lower catalyst coating layer that is present lower with respect to an uppermost catalyst coating layer using a catalyst slurry, wherein the catalyst slurry comprises:
a noble metal particle having catalyst activity,
a metal oxide particle having a 50% cumulative size of 3 μm to 10 μm in a cumulative particle size distribution on a volume basis, and
a fibrous organic substance in an amount of 0.5 to 9.0 parts by mass based on 100 parts by mass of the metal oxide particle, and
the fibrous organic substance has an average fiber diameter in a range from 1.7 μm to 8.0 μm and an average aspect ratio in a range from 9 to 40,
wherein:
each catalyst coating layer comprises a catalyst particle having a different composition from that of an adjacent catalyst coating layer;
in the lower catalyst coating layer that is present lower with respect to the uppermost catalyst coating layer,
an average thickness of the coating layer is in a range from 25 μm to 160 μm,
a porosity measured by a weight-in-water method is in a range from 50 to 80% by volume, and high-aspect-ratio pores having an aspect ratio of 5 or more account for 0.5 to 50% by volume of the whole volume of voids, and
the high-aspect-ratio pore has an equivalent circle diameter of from 2 μm to 50 μm in a cross-sectional image of a catalyst coating layer cross section perpendicular to an exhaust gas flow direction and has an average aspect ratio of from 10 to 50.

10. The method according to claim 9 , comprising the step of forming a catalyst coating by coating a surface of the substrate with the catalyst slurry such that an amount of coating of the catalyst coating layer after firing is in a range from 50 to 300 g per liter of the volume of the substrate and that an average thickness of the catalyst coating layer after firing is in a range from 25 μm to 160 μm.

11. The method according to claim 9 , comprising the step of removing at least a part of the fibrous organic substance by firing after coating the surface of the substrate with the catalyst slurry.

12. The method according to claim 10 , comprising the step of removing at least a part of the fibrous organic substance by firing after coating the surface of the substrate with the catalyst slurry.

Assignees

• Toyota Motor Co Ltd
• Cataler Corp

Inventors

• Suzuki Hiromasa
• Miura Masahide
• Saito Yoshinori
• Katoh Satoru
• Tanabe Toshitaka
• Hirao Tetsuhiro
• Ohashi Tatsuya
• Naito Hiroaki
• Ori Hirotaka
• Takeuchi Michihiko
• Narita Keiichi

Classifications

• B01J23/63 Primary

  with rare earths or actinides · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J35/40

  characterised by dimensions, e.g. grain size (in a colloidal state B01J35/23; crystallite size B01J35/77) · CPC title

• B01D2255/9022

  Two layers · CPC title

• B01D53/945

  characterised by a specific catalyst · CPC title