Methanogen substrate for biogas production

Patent metadata

Field	Value
Publication number	US-10731182-B2
Application number	US-201515313328-A
Country	US
Kind code	B2
Filing date	May 26, 2015
Priority date	May 26, 2014
Publication date	Aug 4, 2020
Grant date	Aug 4, 2020

Abstract

The use of a product for internal dehydration of hydrogenated sugar as a methanogen substrate in a method for biogas production, a composition including a monoanhydrohexitol (M), a dianhydrohexitol (D), and anhydrohexitol polymers (P), and a methanisation method.

First claim

The invention claimed is:

1. A composition comprising, relative to its dry matter:
up to 50% of sorbitan (M) and isosorbide (D);
at least 50% of anhydrohexitol polymers (P);
the sum of the constituents (M)+(D)+(P) coming to 100% and said constituents M and D being present according to an M/(M+D) weight ratio ranging from 0.40 to 0.95,
wherein the anhydrohexitol polymers are formed by acid-catalyzed dehydration of sorbitol under heat and pressure conditions to provide a mixture followed by distillation of the mixture to achieve said proportions of (M), (D) and (P).

2. The composition as claimed in claim 1 , wherein said composition comprises:
from 5% to 50% of sorbitan (M) and isosorbide (D);
from 50% to 95% of anhydrohexitol polymers (P).

3. The composition as claimed in claim 1 , wherein the constituents (M) and (D) are present according to an (M)/(M+D) weight ratio ranging from 0.42 to 0.90.

4. The composition as claimed in claim 1 , wherein the weight percentage of 1,4-sorbitan optionally present in the composition is, relative to the total amount of sorbitan is less than 10%.

5. The composition as claimed in claim 1 , wherein said composition has a Brookfield viscosity, according to a test A, included in the range of from 200 to 2000 mPa.s, the test A consisting in adjusting the dry matter of the composition to 85% and then measuring the Brookfield viscosity at 60° C. of the resulting composition.

6. The composition as claimed in claim 1 , wherein said composition has a dry matter ranging from 50% to 100%.

7. The composition as claimed in claim 1 , wherein said composition has, relative to its dry matter, an amount of sulfur of less than 3%.

8. The composition as claimed in claim 1 , wherein said composition has, according to a test B, a freezing point of less than 10° C., the test B consisting in adjusting the dry matter of said composition to 85% and in measuring the freezing point of the composition with the dry matter thus adjusted.

9. A methanization process comprising:
a step of introduction, into a digester, of a methanogenic substrate comprising a product of internal dehydration of a hydrogenated sugar, in the presence of a microorganism, so as to form a methanogenic medium;
a step of anaerobic digestion of the methanogenic substrate at a temperature ranging from 15 to 70° in order to form a biogas;
a step of recovery of said biogas, this step possibly being carried out throughout the digestion step.
wherein the product of internal dehydration of a hydrogenated sugar comprises the composition of claim 1 .

10. The process as claimed in claim 9 , wherein the digestion step has a duration ranging up to 8 weeks.

11. The process as claimed in claim 9 , wherein the dry matter of the methanogenic medium ranges from 0.1% to 50%.

12. The process as claimed in claim 9 , wherein a buffer solution is also introduced into the methanogenic medium in order to carry out the anaerobic digestion step.

13. The process as claimed in claim 9 , wherein a solution of trace elements and/or a solution of macroelements is (are) introduced into the methanogenic medium in order to carry out the anaerobic digestion step.

14. The process as claimed in claim 9 , wherein the product of internal dehydration of a hydrogenated sugar comprises an amount of sulfur of less than 3%.

15. The process as claimed in claim 9 , wherein the product of internal dehydration of a hydrogenated sugar is used as a methanogenic substrate together with at least one additional methanogenic matter different than the product of internal dehydration of a hydrogenated sugar, said additional methanogenic matter possibly being waste of agricultural, food-processing, industrial, household or municipal origin.

16. The process as claimed in claim 9 , wherein the product of internal dehydration of a hydrogenated sugar is a mixture which has a Brookfield viscosity, according to a test A, included in the range of from 200 to 2000 mPa.s, the test A consisting in adjusting the dry matter of the composition to 85% and then measuring the Brookfield viscosity at 60° C. of the resulting composition.

17. The process as claimed in claim 9 , wherein the product of internal dehydration of a hydrogenated sugar has a methane potential greater than 20 milliliters of methane per gram (mLCH 4 /g) of dry matter of said product.

Assignees

• Roquette Freres

Inventors

• Wyart Herve
• Ibert Mathias

Classifications

• C12P5/023 Primary

  Methane · CPC title

• C08G65/34

  from hydroxy compounds or their metallic derivatives {(C08G65/26 takes precedence)} · CPC title

• C07D493/04 Primary

  Ortho-condensed systems · CPC title

• C07D307/20 Primary

  Oxygen atoms · CPC title

• Y02E50/30

  Fuel from waste, e.g. synthetic alcohol or diesel · CPC title