Renewable hydrocarbon composition

Patent metadata

Field	Value
Publication number	US-10731085-B2
Application number	US-201816195037-A
Country	US
Kind code	B2
Filing date	Nov 19, 2018
Priority date	Apr 2, 2013
Publication date	Aug 4, 2020
Grant date	Aug 4, 2020

Abstract

The present invention provides a composition comprising 10-40 mass % of C 8-30 linear alkanes, up to 20 mass % of C 7-20 aromatic hydrocarbons, at least 90 mass % of which are monoaromatic, and no more than 1 mass % in total of oxygen-containing compounds; wherein the total amount of C 8-30 alkanes in the composition is 50-95 mass %, and the total amount of C 8-30 alkanes, C 7-20 aromatic hydrocarbons and C 8-30 cycloalkanes is at least 95 mass %; wherein the composition comprises 45-90 mass % in total of C 8-30 cycloalkanes and C 8-30 branched alkanes; and wherein the amounts are based on the mass of the composition. Also provided is a method of producing the composition comprising the step of hydroprocessing a biological feedstock using a catalyst and the step of fractionating the product of the hydroprocessing step.

First claim

The invention claimed is:

1. A composition comprising
10-40 mass % of C 8-30 linear alkanes,
up to 20 mass % of C 7-20 aromatic hydrocarbons,
at least 90 mass % of which are monoaromatic, and no more than 1 mass % in total of oxygen-containing compounds;
wherein the total amount of C 8-30 alkanes in the composition is 50-95 mass %, and the total amount of C 8-30 alkanes, C 7-20 aromatic hydrocarbons and C 8-30 cycloalkanes is at least 95 mass %;
wherein the composition comprises 45-90 mass % in total of C 8-30 cycloalkanes and C 8-30 branched alkanes; and
wherein the amounts are based on the mass of the composition.

2. The composition according to claim 1 , wherein the amount of C 8-30 linear alkanes is 20-40 mass %.

3. The composition according to claim 1 , wherein the amount of C 7-20 aromatic hydrocarbons is 0.1-15 mass %.

4. The composition according to claim 1 , which comprises 45-80 mass % in total of C 8-30 cycloalkanes and C 8-30 branched alkanes.

5. The composition according to claim 1 , which comprises 10-30 mass % of C 8-30 cycloalkanes.

6. The composition according to claim 1 , wherein the alkanes are C 9-23 alkanes.

7. The composition according to claim 1 , wherein the aromatic hydrocarbons are C 8-19 aromatic hydrocarbons.

8. The composition according to claim 1 , wherein the cycloalkanes are C 8-19 cycloalkanes.

9. The composition according to claim 1 , which comprises no more than 1 mass % of polyaromatic hydrocarbons.

10. The composition according to claim 1 , which comprises no more than 2 mass % of alkenes.

11. The composition according to claim 1 , which has a density of 795-830 kg/m 3 , as measured at 15° C. by the method of the EN ISO 12185 Standard.

12. The composition according to claim 1 , which has a lower heating value of 42.0-45.0 MJ/l, as measured using the method of the DIN 51900 Standard.

13. The composition according to claim 1 , which has a cetane number of at least 55, as measured using the method of the EN ISO 5165 Standard.

14. A method of producing a composition as defined in claim 1 comprising the steps of:
(i) hydroprocessing a biological feedstock using one or more catalysts; and
(ii) fractionating the product of step (i) to obtain a composition of claim 1 .

15. The method according to claim 14 , wherein the biological feedstock comprises a vegetable oil and/or an animal fat.

16. The method according to claim 14 , wherein the biological feedstock comprises at least 15 mass % of C 12-18 fatty acids, at least 5 mass % of resin acids and at least 10 mass % of neutral compounds based on the mass of the feedstock.

17. The method according to claim 14 , wherein the hydroprocessing step is performed using one or more catalysts which each comprise one or more metals selected from Group VIA and Group VIII metals and one or more support materials selected from zeolite, alumina, zeolite-alumina, alumina-silica, alumina-silica-zeolite and activated carbon.

18. The method according to claim 17 , wherein the metals are selected from Mo, W, Co, Ni, Pt and Pd.

19. The method according to claim 17 , wherein the hydroprocessing step is performed using one or both of the following catalysts (i) and (ii), and optionally the following catalyst (iii):
(i) a catalyst comprising MoO 3 , one or both of CoO and NiO, and one or more support materials;
(ii) a catalyst comprising NiW and one or more support materials;
(iii) a catalyst comprising a Group VIII metal and/or a molecular sieve;
wherein the support materials are selected from zeolite, alumina, zeolite-alumina, alumina-silica, alumina-silica-zeolite and activated carbon.

20. The method according to claim 19 , wherein the hydroprocessing step is performed using one or more reactors which each comprise catalysts (i) and (ii).

21. The method according to claim 20 , wherein the amount of catalyst (ii) relative to the total amount of catalysts (i) and (ii) increases continuously in the direction of flow of the biological feedstock in the reactor(s).

22. The method according to claim 19 , wherein the hydroprocessing step is performed using two or more reactors, at least one reactor comprising catalyst (i) and at least one other reactor comprising catalyst (ii) and/or catalyst (iii).

23. A fuel blend comprising a composition as defined in claim 1 .

24. The fuel blend according to claim 23 , which contains the composition in an amount of 5-98 vol. % based on the volume of the blend.

25. The fuel blend according to claim 23 , which further comprises a petroleum-derived fuel.

26. The fuel blend according to claim 25 , wherein the petroleum-derived fuel is petrodiesel or kerosene.

Assignees

• Upm Kymmene Corp

Inventors

• Lindberg Teemu
• Nousiainen Jaakko
• Laumola Heli
• Rissanen Arto

Classifications

• Y02P30/20

  using bio-feedstock · CPC title

• Y02E50/10

  Biofuels, e.g. bio-diesel · CPC title

• C10L1/04 Primary

  essentially based on blends of hydrocarbons · CPC title

• C11B3/00

  Refining fats or fatty oils · CPC title

• C10G3/45

  containing iron group metals or compounds thereof · CPC title