Peelable adhesive composition

Patent metadata

Field	Value
Publication number	US-10731058-B2
Application number	US-201816032229-A
Country	US
Kind code	B2
Filing date	Jul 11, 2018
Priority date	Dec 26, 2011
Publication date	Aug 4, 2020
Grant date	Aug 4, 2020

Abstract

The invention relates to an adhesive composition comprising at least one natural latex and at least one polymeric composition having a glass transition temperature ranging from −50° C. to 0° C. The invention also relates to a membrane obtained after drying the adhesive composition according to the invention, to a combination of a flexible surface coating with an adhesive composition according to the invention, to a method for applying a flexible surface coating onto a substrate as well as a substrate coated with a peelable adhesive membrane according to the invention.

First claim

The invention claimed is:

1. A method for applying a flexible surface coating on a substrate consisting of the successive steps:
a) applying a peelable adhesive composition layer on a surface of the substrate,
b) observing a gumming time ranging from 10 to 30 minutes
c) displaying a flexible surface coating on the substrate by contacting the flexible surface coating with the adhesive layer on the surface of the substrate,

wherein said adhesive composition comprises:
i) from 10% to 40% by weight of at least one natural latex,
ii) from 10% to 40% by weight of dry material based on the total weight of the adhesive composition, of at least one polymeric composition having a glass transition temperature ranging from −50° C. to 0° C., said polymeric composition comprising:
(1) a terpolymer of vinyl acetate, of ethylene and of acrylate and a mixture of polyester and polyurethane, and/or
(2) a terpolymer of vinyl acetate, of ethylene and of acrylate

iii) from 10% to 40% by weight based on the total weight of the adhesive composition, of at least one filler having an apparent density ranging from 1.30 to 1.70, wherein the amount of applied adhesive composition is greater than or equal to 200 g/m 2 , and
wherein said substrate and said flexible surface coating, after pulling off, are both capable of being recovered without any adhesive residues after removal of the peelable film or membrane obtained after drying of the peelable adhesive composition.

2. A method for renovation of a substrate coated with a peelable adhesive film comprising: drying the adhesive composition of claim 1 , and pulling off the adhesive composition from a surface.

3. The method of claim 1 , wherein:
i) the natural latex represents from 15% to 35% by weight of the total weight of the adhesive composition and/or
ii) the polymeric composition represents from 10% to 25% by weight of dry material based on the total weight of the adhesive composition, and/or
iii) the filler(s) represent(s) from 15% to 35% by weight of the total weight of the composition.

4. The method of claim 1 , wherein the adhesive composition further comprises up to 10% by weight of a tackifying resin.

5. The method of claim 1 , wherein the polymeric composition has a glass transition temperature ranging from −40° C. to −10° C.

6. The method of claim 1 , wherein the adhesive composition further comprises fibers.

7. The method of claim 1 wherein the amount of applied adhesive composition is greater than or equal to 250 g/m 2 .

8. The method of claim 1 wherein the amount of applied adhesive composition is greater than or equal to 300 g/m 2 .

9. The method of claim 1 wherein the amount of applied adhesive composition is greater than or equal to 350 g/m 2 .

10. The method of claim 4 wherein tackifying resin is rosin esters, terpene resins, terpene phenol resins or dispersions based on terpene phenol resin.

11. The method of claim 5 wherein the polymeric composition has a glass transition temperature ranging from −37° C. to −15° C.

12. The method of claim 6 wherein fibers are cellulose fibers, glass fibers, rubber fibers, natural fibers, viscose, jute, sisal or synthetic fibers.

13. The method of claim 1 , wherein the substrate is selected from surfaced concretes, cement-based screeds, anhydrite screeds, old tilings, old suitably smoothed parquet flooring, particle panels or plywoods, standard wall claddings.

14. A method for applying a flexible surface coating on a substrate consisting of the successive steps:
a) applying a weft or a non-woven reinforcing strip onto the substrate
b) applying a peelable adhesive composition layer on a surface of the substrate,
c) observing a gumming time ranging from 10 to 30 minutes,
d) displaying the flexible surface coating on the substrate by contacting the flexible surface coating with the adhesive layer on the surface of the substrate,

wherein said adhesive composition comprises:
i) from 10% to 40% by weight of at least one natural latex,
ii) from 10% to 40% by weight of dry material based on the total weight of the adhesive composition, of at least one polymeric composition having a glass transition temperature ranging from −50° C. to 0° C., said polymeric composition comprising:
(1) a terpolymer of vinyl acetate, of ethylene and of acrylate and a mixture of polyester and polyurethane, and/or
(2) a terpolymer of vinyl acetate, of ethylene and of acrylate,

iii) from 10% to 40% by weight based on the total weight of the adhesive composition, of at least one filler having an apparent density ranging from 1.30 to 1.70, wherein the amount of applied adhesive composition is greater than or equal to 200 g/m 2 , and wherein
said substrate and said flexible surface coating, after pulling off, are both capable of being recovered without any adhesive residues after removal of the peelable film or membrane obtained after drying of the peelable adhesive composition.

15. The method of claim 14 , wherein the weft is a grid, a woven or non-woven material.

16. A method for applying a flexible surface coating on a substrate consisting of the successive steps:
a) applying a peelable adhesive composition layer on a surface of the substrate,
b) observing a gumming time ranging from 10 to 30 minutes,
c) displaying the flexible surface coating on the substrate by contacting the flexible surface coating with the adhesive layer on the surface of the substrate, and
d) smoothing the adhesive composition under the flexible surface coating,

wherein said adhesive composition comprises:
i) from 10% to 40% by weight of at least one natural latex,
ii) from 10% to 40% by weight of dry material based on the total weight of the adhesive composition, of at least one polymeric composition having a glass transition temperature ranging from −50° C. to 0° C., said polymeric composition comprising:
(1) a terpolymer of vinyl acetate, of ethylene and of acrylate and a mixture of polyester and polyurethane, and/or
(2) a terpolymer of vinyl acetate, of ethylene and of acrylate,

iii) from 10% to 40% by weight based on the total weight of the adhesive composition, of at least one filler having an apparent density ranging from 1.30 to 1.70, wherein the amount of applied adhesive composition is greater than or equal to 200 g/m 2 , and wherein

said substrate and said flexible surface coating, after pulling off, are both capable of being recovered without any adhesive residues after removal of the peelable film or membrane obtained after drying of the peelable adhesive composition.

Assignees

• Bostik Sa

Inventors

• Casimiro Jessie
• Verscheure Eric

Classifications

• B32B43/006

  Delaminating · CPC title

• B32B2305/20

  in the form of a non-woven mat · CPC title

• B05D1/40

  Distributing applied liquids or other fluent materials by members moving relatively to surface · CPC title

• C09J107/02 Primary

  Latex · CPC title

• C08L23/0853

  Ethylene vinyl acetate copolymers · CPC title