Gas-phase process for the polymerization of propylene

Patent metadata

Field	Value
Publication number	US-10730974-B2
Application number	US-201615750469-A
Country	US
Kind code	B2
Filing date	Aug 3, 2016
Priority date	Aug 4, 2015
Publication date	Aug 4, 2020
Grant date	Aug 4, 2020

Abstract

A gas-phase process for the homopolymerization or copolymerization of propylene with other olefins, including carrying out the polymerization in the presence of a catalyst system made from or containing: (a) a solid catalyst component made from or containing Mg, Ti, halogen, an electron donor selected from 1.3-diethers and an olefin polymer in a specific amount; (b) an aluminum alkyl compound and (c) an external electron donor (ED) compound, wherein components (b) and (c) being employed in amounts such that the Al/(ED) molar ratio ranges from about 2 to about 200.

First claim

What is claimed is:

1. A gas-phase process for the homopolymerization of propylene or copolymerization of propylene with other olefins comprising:
(i) carrying out the polymerization in the presence of a catalyst system comprising:
(a) a solid catalyst component comprising
(A) Mg,
(B) Ti,
(C) halogen,
(D) an electron donor, wherein the electron donor consists of 1,3-diethers and
(E) an olefin polymer in an amount ranging from about 10 to about 85 weight % of the total weight of the solid catalyst component,
wherein the 1,3-diether/Mg molar ratio ranges from about 0.030 to about 0.150;

(b) an aluminum alkyl compound; and
(c) an external electron donor (ED) compound selected from silicon compounds, ethers, esters, amines, heterocyclic compounds, ketones,

wherein components (b) and (c) being employed in amounts such that the Al/(ED) molar ratio ranges from about 2 to about 200.

2. The gas phase process according to claim 1 , wherein the solid catalyst component has an average particle size ranging from about 10 to about 100 μm.

3. The gas phase process according to claim 1 , wherein the 1,3-diethers are compounds of formula (I)

where R I and R II are the same or different and are hydrogen or linear or branched C 1 -C 18 hydrocarbon groups which can also form one or more cyclic structures; R III groups, equal or different from each other, are hydrogen or C 1 -C 18 hydrocarbon groups; R IV groups equal or different from each other, have the same meaning of R III providing that R IV groups are not hydrogen; each of R I to R IV groups can contain heteroatoms selected from halogens, N, O, S and Si.

4. The gas phase process according to claim 3 , wherein the 1,3 diethers are compounds of formula (III):

where the R VI radicals equal or different are hydrogen; halogens; C 1 -C 20 alkyl radicals, linear or branched; C 3 -C 20 cycloalkyl, C 6 -C 20 aryl, C 7 -C 20 alkylaryl and C 7 -C 20 aralkyl radicals, optionally containing one or more heteroatoms selected from the group consisting of N, O, S, P, Si and halogens as substitutes for carbon or hydrogen atoms, or both.

5. The gas phase process according to claim 1 , wherein the 1,3-diether/Mg molar ratio ranges from 0.035 to 0.1.

6. The gas phase process according to claim 1 , wherein the Mg/Ti molar ratio ranges from about 4 to about 10.

7. The gas phase process according to claim 1 , wherein the olefin polymer is selected from the group consisting of homopolymers and copolymers of olefins of formula CH 2 ═CHR, wherein R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms.

8. The gas phase process according to claim 7 , wherein the olefins are selected from the group consisting of ethylene, propylene or mixtures thereof.

9. The gas phase process according to claim 7 , wherein the weight of olefin polymer ranges from about 15 to about 75% of the total weight of the solid catalyst component (a).

10. The gas phase process according to claim 1 , wherein the alkyl-Al compound (b) is selected from the group consisting of trialkyl aluminum compounds.

11. The gas phase process according to claim 1 , wherein the aluminum alkyl compound is present in amount such that the Al/Ti molar ratio ranges from about 10 to about 400.

12. The gas phase process according to claim 1 , wherein the external donor compounds are silicon compounds having at least a Si—O—C bond.

13. The gas phase process according to claim 12 , wherein the silicon compounds are of formula R a 5 R b 6 Si(OR 7 ) c , where a and b are integer from 0 to 2, c is an integer from 1 to 3 and the sum (a+b+c) is 4; R 5 , R 6 , and R 7 , are alkyl, cycloalkyl or aryl radicals with 1-18 carbon atoms optionally containing heteroatoms selected from N, O, halogen and P.

14. The gas phase process of claim 1 , wherein the polymerization is carried out in a gas-phase fluidized bed reactor.

15. The gas phase process of claim 1 , wherein the polymerization is carried out in a gas-phase mechanically agitated bed reactor.

Assignees

• Basell Poliolefine Italia Srl

Inventors

• Morini Giampiero
• Covezzi Massimo
• DALL'OCCO Tiziano
• Liguori Dario
• Piemontesi Fabrizio
• Vitale Gianni

Classifications

• C08F2410/06

  Catalyst characterized by its size · CPC title

• C08F110/06 Primary

  Propene · CPC title

• C08F2/34

  Polymerisation in gaseous state · CPC title

• C08F4/6492

  containing aliphatic unsaturation · CPC title

• C08F110/02

  Ethene · CPC title