Gas atmosphere control in laser printing using metallic powders

Patent metadata

Field	Value
Publication number	US-10730142-B2
Application number	US-201514822225-A
Country	US
Kind code	B2
Filing date	Aug 10, 2015
Priority date	Aug 12, 2014
Publication date	Aug 4, 2020
Grant date	Aug 4, 2020

Abstract

Methods and systems for controlling gas atmospheres in three-dimensional laser printing and weld overlay consolidation operations using metallic powders are provided. In one or more embodiments, such systems and methods comprise a printing chamber or laser weld overlay system, a gas supply system, a feed powder system, and one or more sensors employed to control the printing or welding operation. The methods and systems of the invention employ one or more inert gases having a purity greater than or equal to 99.995%

First claim

The invention claimed is:

1. A method for controlling gas atmospheres in three-dimensional laser printing using metallic powders, comprising the steps of:
a. providing a 3D printer comprising a printing chamber, a gas supply system, and a feed powder system;
b. providing an inert gas having a purity greater than or equal to 99.995% from the gas supply system to the printing chamber;
c. providing one or more feed powders from the feed powder system to the printing chamber;
d. providing one or more gas sensors located in one or more of the printing chamber, gas supply system, or feed powder systems; and
e. printing an article,

wherein at least one of the one or more gas sensors is a gas composition sensor, and wherein one or more outputs from the at least one gas composition sensor effects an increase or decrease of an overall flowrate of the inert gas in order to maintain an atmosperic contaimant level inside the printing chamber below a desired value.

2. The method of claim 1 , wherein the one or more outputs from the one or more gas sensors is selected from the oxygen concentration inside the printing chamber, the oxygen concentration inside the feed powder system, or both.

3. The method of claim 2 , wherein an initially high oxygen concentration results in the one or more gas sensors modulating the gas supply system to increase the overall flowrate of the inert gas until a desired oxygen level is reached.

4. The method of claim 1 , further comprising providing an in-line gas purifier within the gas supply system or between the gas supply system and the printing chamber.

5. The method of claim 1 , wherein the inert gas purity is greater than or equal to 99.998%.

6. The method of claim 5 , wherein the inert gas purity is greater than or equal to 99.999%.

7. The method of claim 1 , wherein one or more of the gas sensors is a zirconia gas sensor having a millivolt reading more negative than −185 mV at a zirconia cell operation temperature of 600° C.

8. The method of claim 1 , wherein the one or more feed powders are selected from alloy steels; superalloys; titanium, aluminum, nickel, copper, precious metals, cobalt, zirconium, niobium, molybdenum, tungsten, tantalum, hafnium, magnesium, and boron alloys; powder compositions resulting in composite parts containing metals, carbides, nitrides, aluminides, silicides, or borides; and combinations thereof.

9. The method of claim 1 , where in the inert gas is selected from argon, helium and krypton, or combinations thereof.

10. The method of claim 1 , wherein the printing chamber comprises a powder bed, and further comprising the step of pre-heating the powder bed to a temperature greater than about 400° C. prior to the printing step.

11. The method of claim 1 , wherein at least one of the one or more gas sensors is connected to electromechanical gas flow controls inside the gas supply system.

Assignees

• Air Prod & Chem

Inventors

• Zurecki Zbigniew
• Ghosh Ranajit

Classifications

• B22F10/322

  of the gas flow, e.g. rate or direction · CPC title

• B22F12/90

  Means for process control, e.g. cameras or sensors · CPC title

• B22F12/70

  Gas flow means · CPC title

• B22F12/52

  Hoppers · CPC title

• B22F10/64

  by thermal means (control of energy beam parameters for post heating B22F10/364) · CPC title