Method for producing a flat steel product with an amorphous, partially amorphous or fine-crystalline microstructure and flat steel product with such characteristics

Patent metadata

Field	Value
Publication number	US-10730105-B2
Application number	US-201414763249-A
Country	US
Kind code	B2
Filing date	Jan 24, 2014
Priority date	Jan 25, 2013
Publication date	Aug 4, 2020
Grant date	Aug 4, 2020

Abstract

A method is provided for producing a 0.8-4.5 mm thick steel strip with an amorphous, partially amorphous or fine-crystalline microstructure with grain sizes in the range of 10-10000 nm and also a flat steel product made therefrom. A molten steel is cast into a cast strip in a casting device and cooled down at an accelerated rate. Along with Fe and impurities that are unavoidable for production-related reasons, the molten material contains at least two elements belonging to the group “Si, B, C and P”. In this case, the following applies for the contents of these elements (in % by weight) Si: 1.2-7.0%, B: 0.4-4.0%, C: 0.5-4.0%, P: 1.5-8.0%. With a corresponding composition and a microstructure with corresponding characteristics, a flat steel product according to the invention has a HV0.5 hardness of 760-900.

First claim

The invention claimed is:

1. A method for producing a flat steel product with an amorphous, a partially amorphous, or a fine-crystalline microstructure, the fine-crystalline microstructure having grain sizes in the range of 10-10000 nm, comprising:
casting molten steel into a cast strip in a casting device comprising two rolls rotating counter to one another wherein a molten pool of metal feeds a gap between the two rolls;
cooling said molten steel at an accelerated rate in a casting region defined by the gap between the two rolls to form a cast strip;
further cooling the cast strip leaving the casting region using an additional cooling device, wherein the molten steel is cooled down at a cooling rate of at least 200 K/s to a temperature below the glass transition temperature T G ; and
hot-rolling the cast strip at an initial hot-rolling temperature lying in the range between the glass transition temperature T G and the crystallization temperature T x to form a flat steel product,
wherein the thickness of the cast strip is 0.8-4.5 mm and the molten steel comprises, along with iron and unavoidable impurities, 1.2-7.0% Si and at least one element selected from the group consisting of B, C and P, wherein (in % by weight):
B: 0.4-4.0%,
C: 0.5-4.0%, and/or
P: 1.5-8.0%
and also optionally one or more elements selected from the group consisting of Cu, Cr, Al, N, Nb, Mn, Ti and V, wherein (in % by weight):
Cu: up to 5.0%,
Cr: up to 10.0%,
Al: up to 10.0%,
N: up to 0.5%,
Nb: up to 2.0%,
Mn: up to 3.0%,
Ti: up to 2.0%, and/or
V: up to 2.0%.

2. The method as claimed in claim 1 , wherein the molten steel is cooled at a cooling rate of up to 1100 K/s.

3. The method as claimed in claim 1 , wherein the casting region of the casting device is formed on at least one longitudinal side by a wall that moves in a casting direction and is cooled during the casting operation, and wherein the molten steel is cooled by contact with the moving and cooled wall at a cooling rate of at least 200 K/s.

4. The method as claimed in claim 3 , wherein, after leaving the casting region, the cast strip continues to be cooled at a cooling rate of at least 200 K/s by the additional cooling device.

5. The method as claimed in claim 3 , wherein the cast strip leaving the casting region is cooled continuously until its temperature is below the glass transition temperature T G of the respective steel.

6. The method as claimed in claim 3 , further comprising hot-rolling the cast strip at an initial hot-rolling temperature of 500-1000° C. to form a hot strip.

7. The method as claimed in claim 3 , further comprising annealing the cast strip leaving the casting device and having an amorphous or partially amorphous microstructure at an annealing temperature T anneal corresponding at least to the crystallization temperature T x of the respective steel.

8. The method as claimed in claim 7 , wherein the annealing temperature T anneal lies in the range of 500-1000° C.

9. The method as claimed in claim 1 , wherein the molten steel contains at least one element selected from the group consisting of Cu, Cr, Al, N, Nb, Mn, Ti and V.

10. The method as claimed in claim 1 , wherein, for at least one of the elements selected from the group consisting of B, C, and P, at least one of the following respectively applies (in % by weight):
B: 0.4-3.0%,
C: 0.5-3.0%
and/or
P: 2.0-6.0%.

11. The method as claimed in claim 1 , wherein the molten steel comprises (in % by weight) at least one element selected from the group consisting of Cu, Cr, Al and N, wherein (in % by weight):
Cu: 0.1-5.0%,
Cr: 0.5-10.0%,
Al: 1.0-10.0%, and/or
N: 0.005-0.5%.

12. The method as claimed in claim 1 , wherein a strip speed at which the cast strip leaves the gap is 0.3-1.7 m/s.

13. The method as claimed in claim 1 , wherein the Si is 2.0-6.0%.

14. A flat steel product made according to the method of claim 1 with a thickness of 0.8-4.5 mm, comprising a steel that comprises, along with iron and unavoidable impurities, 1.2-7.0% Si and at least one element selected from the group consisting of B, C and P, wherein (in % by weight):
B: 0.4-4.0%,
C: 0.5-4.0%, and
P: 1.5-8.0%,
and optionally one or more elements selected from the group consisting of Cu, Cr, Al, N, Nb, Mn, Ti and V, wherein (in % by weight):
Cu: up to 5.0%,
Cr: up to 10.0%,
Al: up to 10.0%,
N: up to 0.5%,
Nb: up to 2.0%,
Mn: up to 3.0%,
Ti: up to 2.0%, and/or
V: up to 2.0%,
and having an amorphous, partially amorphous or fine-crystalline microstructure with grain sizes that lie in the range of 10-10000 nm, wherein the HV0.5 hardness of the flat steel product is 760-900.

Assignees

• Thyssenkrupp Steel Europe Ag

Inventors

• Dorner Dorothée
• Höckling Christian
• Hofmann Harald
• Schirmer Matthias
• Daamen Markus

Classifications

• C22C1/11

  Making amorphous alloys · CPC title

• B22D11/0611 Primary

  formed by a single casting wheel, e.g. for casting amorphous metal strips or wires · CPC title

• B22D11/0622

  formed by two casting wheels · CPC title

• C22C33/003

  making amorphous alloys · CPC title

• C21D1/18

  Hardening (C21D1/02 takes precedence); Quenching with or without subsequent tempering (quenching devices C21D1/62) · CPC title