Anode slurry for lithium ion battery

Patent metadata

Field	Value
Publication number	US-10727489-B2
Application number	US-201716313944-A
Country	US
Kind code	B2
Filing date	Sep 29, 2017
Priority date	Oct 11, 2016
Publication date	Jul 28, 2020
Grant date	Jul 28, 2020

Abstract

Provided herein is a lithium-ion battery anode slurry, comprising: an anode active material, a conductive agent, a binder material, and a solvent, wherein the anode active material has a particle size D50 in the range from about 10 μm to about 40 μm, and wherein the slurry coated onto a current collector having a wet film thickness of about 100 μm has a drying time of about 5 minutes or less under an environment having a temperature of about 60° C. to about 90° C. and a relative humidity of about 25% to about 40%. The anode slurry disclosed herein has homogeneous ingredient dispersion and quick drying capability for making a lithium-ion battery with high quality and consistent performance. In addition, these properties of the anode slurry increase productivity and reduce the cost of manufacturing lithium-ion batteries.

First claim

What is claimed is:

1. A lithium-ion battery anode slurry, comprising: an anode active material, a conductive agent, a binder material, and a solvent,
wherein the anode active material has a particle size D50 in the range from about 10 μm to about 40 μm, and wherein the slurry coated onto a current collector having a wet film thickness of about 100 μm has a drying time of about 5 minutes or less under an environment having a temperature of about 60° C. to about 90° C. and a relative humidity of about 25% to about 40%;
wherein the solvent is present in an amount from about 40% to about 60% by weight, based on the total weight of the slurry; and
wherein the viscosity of the slurry is in the range from about 500 mPa·s to about 1,700 mPa·s.

2. The slurry of claim 1 , wherein the anode active material has a D10 value of at least 3 μm.

3. The slurry of claim 1 , wherein the anode active material has a D90 value of less than or equal to 70 μm.

4. The slurry of claim 1 , wherein the anode active material is present in an amount from 35% to 70% by weight; wherein the conductive agent is present in an amount from 0.8% to 5% by weight; wherein the binder material is present in an amount from 0.5% to 6% by weight, and wherein all weight % values are based on the total weight of the slurry.

5. The slurry of claim 1 , wherein the anode active material is selected from the group consisting of natural graphite particulate, synthetic graphite particulate, hard carbon, soft carbon, mesocarbon microbeads (MCMB), Sn particulate, SnO 2 , SnO, Li 4 Ti 5 Oi 2 particulate, Si particulate, Si—C composite particulate, and combinations thereof.

6. The slurry of claim 1 , wherein the conductive agent is selected from the group consisting of carbon, carbon black, graphite, expanded graphite, graphene, graphene nanoplatelets, carbon fibres, carbon nano-fibers, graphitized carbon flake, carbon tubes, carbon nanotubes, activated carbon, mesoporous carbon, and combinations thereof.

7. The slurry of claim 1 , wherein the binder material is selected from the group consisting of styrene-butadiene rubber, acrylated styrene-butadiene rubber, acrylonitrile copolymer, acrylonitrile-butadiene rubber, nitrile butadiene rubber, acrylonitrile-styrene-butadiene copolymer, acryl rubber, butyl rubber, fluorine rubber, polytetrafluoroethylene, polyethylene, polypropylene, ethylene/propylene copolymers, polybutadiene, polyethylene oxide, chlorosulfonated polyethylene, polyvinylpyrrolidone, polyvinylpyridine, polyvinyl alcohol, polyvinyl acetate, polyepichlorohydrin, polyphosphazene, polyacrylonitrile, polystyrene, latex, acrylic resins, phenolic resins, epoxy resins, carboxymethyl cellulose, hydroxypropyl cellulose, cellulose acetate, cellulose acetate butyrate, cellulose acetate propionate, cyanoethylcellulose, cyanoethylsucrose, polyester, polyamide, polyether, polyimide, polycarboxylate, polycarboxylic acid, polyacrylic acid, polyacrylate, polymethacrylic acid, polymethacrylate, polyacrylamide, polyurethane, fluorinated polymer, chlorinated polymer, a salt of alginic acid, polyvinylidene fluoride, poly(vinylidene fluoride)-hexafluoropropene, and combinations thereof.

8. The slurry of claim 7 , wherein the salt of alginic acid comprises a cation selected from Na, Li, K, Ca, NH 4 , Mg, Al, or a combination thereof.

9. The slurry of claim 1 , wherein the solvent is selected from the group consisting of N-methyl-2-pyrrolidone, dimethylformamide, dimethyl sulfoxide, acetonitrile, butylene carbonate, propylene carbonate, ethyl bromide, tetrahydrofuran, dimethyl carbonate, diethyl carbonate, ethyl methyl, carbonate methyl propyl carbonate, ethylene carbonate, water, pure water, de-ionized water, distilled water, ethanol, isopropanol, methanol, acetone, n-propanol, t-butanol, and combinations thereof.

10. The slurry of claim 1 , wherein the vapor pressure of the solvent is at least 15 kPa.

11. The slurry of claim 1 , wherein the pH of the slurry is from about 7 to about 9.

12. The slurry of claim 1 , wherein the coated slurry film is dried by a box oven, a conveyor oven, or a hot plate.

13. The slurry of claim 1 , wherein the solvent has a boiling point of less than 140° C., less than 120° C., or less than 100° C.

14. The slurry of claim 1 , wherein the ratio D90/D10 of the anode active material is from about 3 to about 10, or from about 5 to about 8.

15. The slurry of claim 1 , wherein the slurry coated onto the current collector in the form of a film has a drying time of about 2.5 minutes or less.

16. The slurry of claim 1 , wherein the particle size distribution of the anode active material is bimodal with a first peak at about 10 μm and a second peak at about 25 μm.

17. A negative electrode for a lithium-ion battery, the negative electrode comprising: an anode current collector; and an anode electrode layer dispersed on the anode current collector, wherein the anode electrode layer is formed using the anode slurry of claim 1 .

18. A lithium-ion battery comprising: a cathode; an anode; and a separator interposed between the cathode and the anode, wherein at least one of the anode is the negative electrode of claim 17 .

Assignees

• Grst Int Ltd

Inventors

• Ho Kam Piu
• Wang Ranshi
• Shen Peihua

Classifications

• H01M2004/027

  Negative electrodes · CPC title

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M4/621

  Binders · CPC title

• H01M4/587

  for inserting or intercalating light metals · CPC title