Capsule design for the capture of reagents

Patent metadata

Field	Value
Publication number	US-10723932-B2
Application number	US-201916690990-A
Country	US
Kind code	B2
Filing date	Nov 21, 2019
Priority date	Jan 2, 2018
Publication date	Jul 28, 2020
Grant date	Jul 28, 2020

Abstract

A method of using a gas control additive to provide gas migration control in a wellbore includes the steps of mixing the gas control additive with a cement to form a cement slurry, where the gas control additive includes a semi-permeable membrane and a scrubbing agent, such that the semi-permeable membrane forms a shell around a core such that the scrubbing agent is in the core, introducing the cement slurry to the wellbore, and reacting the scrubbing agent with an antagonistic gas to produce a helper byproduct, where the antagonistic gas migrates from a hydrocarbon-bearing formation into the wellbore and permeates through the semi-permeable membrane to the core of the gas control additive.

First claim

What is claimed is:

1. A method of using a gas control additive to provide gas migration control in a wellbore, the method comprising the steps of:
mixing the gas control additive with a cement to form a cement slurry, where the gas control additive is formed by the steps of:
mixing a first solvent, a first monomer, and a surfactant to produce a continuous phase;
mixing a second solvent, a second monomer, and a scrubbing agent to produce a dispersed phase;
mixing the continuous phase and the dispersed phase to form a mixture having an emulsion such that the dispersed phase is dispersed as droplets in the continuous phase, where an interface defines the droplets of the dispersed phase dispersed in the continuous phase;
forming a polymer on the interface of the droplets, such that the polymer forms a semi-permeable membrane around a core, where the core contains the dispersed phase, such that the semi-permeable membrane around the core forms the gas control additive; and
settling the gas control additive from the mixture; and
separating the gas control additive from the mixture using a separation method;

introducing the cement slurry into the wellbore; and
reacting the scrubbing agent with an antagonistic gas to produce a helper byproduct, where the antagonistic gas migrates from a hydrocarbon-bearing formation into the wellbore and permeates through the semi-permeable membrane to the core of the gas control additive,
where the scrubbing agent is selected from the group consisting of: iron (III) oxide, calcium hydroxide, and combinations of the same.

2. A method of using a gas control additive to provide gas migration control in a wellbore, the method comprising the steps of:
mixing the gas control additive with a cement to form a cement slurry, where the gas control additive is formed by the steps of:
mixing a first solvent, a first monomer, and a surfactant to produce a continuous phase;
mixing a second solvent, a second monomer, and a scrubbing agent to produce a dispersed phase;
mixing the continuous phase and the dispersed phase to form a mixture having an emulsion such that the dispersed phase is dispersed as droplets in the continuous phase, where an interface defines the droplets of the dispersed phase dispersed in the continuous phase;
forming a polymer on the interface of the droplets, such that the polymer forms a semi-permeable membrane around a core, where the core contains the dispersed phase, such that the semi-permeable membrane around the core forms the gas control additive; and
settling the gas control additive from the mixture; and
separating the gas control additive from the mixture using a separation method;

introducing the cement slurry into the wellbore; and
reacting the scrubbing agent with an antagonistic gas to produce a helper byproduct, where the antagonistic gas migrates from a hydrocarbon-bearing formation into the wellbore and permeates through the semi-permeable membrane to the core of the gas control additive,
where the helper byproduct is selected from the group consisting of: water, calcium carbonate, calcium bicarbonate, and combinations of the same.

3. A method of using a gas control additive to provide gas migration control in a wellbore, the method comprising the steps of:
mixing the gas control additive with a cement to form a cement slurry, where the gas control additive is formed by the steps of:
mixing a first solvent, a first monomer, and a surfactant to produce a continuous phase;
mixing a second solvent, a second monomer, and a scrubbing agent to produce a dispersed phase;
mixing the continuous phase and the dispersed phase to form a mixture having an emulsion such that the dispersed phase is dispersed as droplets in the continuous phase, where an interface defines the droplets of the dispersed phase dispersed in the continuous phase;
forming a polymer on the interface of the droplets, such that the polymer forms a semi-permeable membrane around a core, where the core contains the dispersed phase, such that the semi-permeable membrane around the core forms the gas control additive; and
settling the gas control additive from the mixture; and
separating the gas control additive from the mixture using a separation method;

introducing the cement slurry into the wellbore; and
reacting the scrubbing agent with an antagonistic gas to produce a helper byproduct, where the antagonistic gas migrates from a hydrocarbon-bearing formation into the wellbore and permeates through the semi-permeable membrane to the core of the gas control additive,
where the scrubbing agent is tethered in the core via site-isolation using a chelating agent selected from the group consisting of: polyethylene glycols, polystyrenes, polyethylene imine, polyvinyl alcohols, ethylenediaminetetraacetic acid, hydroxyethylethylenediaminetriacetic acid, nitrilotriacetic acid, diethylenetriaminepentaacetic acid, and combinations of the same.

Assignees

• Saudi Arabian Oil Co

Inventors

• Contreras Elizabeth Q

Classifications

• C04B20/0232

  with carbon dioxide · CPC title

• C04B28/02 Primary

  containing hydraulic cements other than calcium sulfates · CPC title

• C04B2103/0006

  Alkali metal or inorganic ammonium compounds · CPC title

• C04B14/308

  Iron oxide · CPC title

• C09K8/493

  Additives for reducing or preventing gas migration · CPC title