Tack-free polyurethane flexible foam

Patent metadata

Field	Value
Publication number	US-10723828-B2
Application number	US-201716300670-A
Country	US
Kind code	B2
Filing date	May 2, 2017
Priority date	May 12, 2016
Publication date	Jul 28, 2020
Grant date	Jul 28, 2020

Abstract

Described herein is a process for producing flexible polyurethane foams, in which (a) polyisocyanate prepolymer, is mixed with (b) polymeric compounds having groups reactive toward isocyanates, (c) optionally chain extenders and/or crosslinkers, (d) catalyst, (e) blowing agent comprising water and (f) optionally additives to give a reaction mixture and reacted to give a flexible polyurethane foam.

First claim

The invention claimed is:

1. A process for producing flexible polyurethane foams, in which
a) polyisocyanate prepolymer, is mixed with
b) polymeric compounds having groups reactive toward isocyanates,
c) optionally chain extenders and/or crosslinkers,
d) catalyst,
e) blowing agent comprising water and
f) optionally additives

to give a reaction mixture and reacted to give the flexible polyurethane foam,
wherein the polyisocyanate prepolymer (a) has an NCO content of from 16 to 30% by weight, based on a total weight of the polyisocyanate prepolymer a), and is obtainable by reacting
a1) diphenylmethane diisocyanate comprising:
a1a) diphenylmethane 2,4′-diisocyanate,
a1b) diphenylmethane 4,4′-diisocyanate and
a1c) higher homologues of diphenylmethane diisocyanate having more than two rings with

a2) polyols comprising:
a2a) ethylene-oxide-rich polyalkylene oxide having a hydroxyl number of from 20 to 60 mg KOH/g derived from one or more bifunctional to tetrafunctional starter molecules and a proportion of ethylene oxide units, based on a total weight of alkylene oxide units, of at least 55% by weight and
a2b) low-ethylene oxide polyalkylene oxide having a hydroxyl number of from 20 to 60 mg KOH/g derived from one or more bifunctional to tetrafunctional starter molecules and a proportion of ethylene oxide units, based on the total weight of alkylene oxide units, of not more than 20% by weight

and
where a proportion of a1a) diphenylmethane 2,4′-diisocyanate is from 5 to 15% by weight and that of a1b) diphenylmethane 4,4′-diisocyanate is from 40 to 80% by weight, based on a total weight of the diphenylmethane diisocyanate a1),
and the polymeric compounds (b) having groups which are reactive toward isocyanates comprise
b1) from 60 to 80% by weight of at least one polyalkylene oxide having a hydroxyl number of from 20 to 60 mg KOH/g derived from one or more bifunctional to tetrafunctional starter molecules and a proportion of ethylene oxide units, based on a total weight of alkylene oxide units, of from 55 to 95% by weight,
b2) from 20 to 30% by weight of at least one polyalkylene oxide having a hydroxyl number of from 20 to 80 mg KOH/g derived from one or more bifunctional to tetrafunctional starter molecules and a proportion of ethylene oxide units, based on a total weight of alkylene oxide units, of from 0 to 40% by weight

and
where a proportion of the compounds b1) and b2), based on a total weight of the polymeric compounds b) having groups which are reactive toward isocyanates, is at least 80% by weight.

2. The process according to claim 1 , wherein the a1) diphenylmethane diisocyanate comprises
from 5 to 15% by weight of a1a) diphenylmethane 2,4-diisocyanate,
from 40 to 70% by weight of diphenylmethane 4,4′-diisocyanate and
from 10 to 30% by weight of a1c) higher homologues of diphenylmethane diisocyanate having more than two rings, in each case based on the total weight of the diphenylmethane diisocyanate a1).

3. The process according to claim 1 , wherein a proportion of a2a) ethylene oxide-rich polyalkylene oxide is from 4 to 8% by weight and a proportion of (a2b) low-ethylene oxide polyalkylene oxide is from 10 to 16% by weight, in each case based on the total weight of the polyisocyanate prepolymer a).

4. The process according to claim 1 , wherein the polyalkylene oxide (a2a) has a proportion of primary OH groups of from 70 to 100%, based on a total number of OH groups of the polyalkylene oxide (a2b), and the polyalkylene oxide (a2) has a proportion of primary OH groups of from 30 to 0%, based on a total number of OH groups of the polyalkylene oxide a2).

5. The process according to claim 1 , wherein the polyalkylene oxide b1) has a proportion of primary OH groups of from 70 to 100%, based on a total number of OH groups of the polyalkylene oxide b1), and the polyalkylene oxide b2) has a proportion of primary OH groups of from 30 to 0%, based on a total number of OH groups of the polyalkylene oxide b2).

6. The process according to claim 1 , wherein the reaction of the reaction mixture to give the flexible polyurethane foam is carried out at an isocyanate index of from 55 to 105.

7. The process according to claim 1 , wherein the flexible polyurethane foam is produced in a closed mold.

8. The process according to claim 1 , wherein the flexible polyurethane foam has a density of from 20 to 70 g/l.

9. The process according to claim 1 , wherein the flexible polyurethane foam has an indentation hardness at 40%.

10. A flexible polyurethane foam obtainable by a process according to claim 1 .

11. The flexible polyurethane foam according to claim 10 , wherein an extractable content of aromatic amines in a test specimen from a surface having dimensions of 3 cm×3 cm and a thickness of 0.5 cm in 50 ml of acetic acid is less than 1 ppm.

Assignees

• Basf Se

Inventors

• Lutter Heinz-Dieter
• Faehmel Manuela
• Simon Kirsten
• Petrini Claudio

Classifications

• C08G2110/0083

  prepared using water as the sole blowing agent · CPC title

• C08G2110/0008

  flexible · CPC title

• C08G2110/005

  < 50kg/m3 · CPC title

• C08G18/485

  containing mixed oxyethylene-oxypropylene or oxyethylene-higher oxyalkylene end groups · CPC title

• C08J2205/06

  Flexible foams · CPC title