Porous shaped carbon products

Patent metadata

Field	Value
Publication number	US-10722867-B2
Application number	US-201615131829-A
Country	US
Kind code	B2
Filing date	Apr 18, 2016
Priority date	Oct 28, 2015
Publication date	Jul 28, 2020
Grant date	Jul 28, 2020

Abstract

Shaped porous carbon products and processes for preparing these products are provided. The shaped porous carbon products can be used, for example, as catalyst supports and adsorbents. Catalyst compositions including these shaped porous carbon products, processes of preparing the catalyst compositions, and various processes of using the shaped porous carbon products and catalyst compositions are also provided.

First claim

What is claimed is:

1. A process for preparing a shaped porous carbon product, the process comprising:
mixing a carbonaceous material comprising activated carbon and/or carbon black and an organic binder to form a carbon-binder mixture, wherein the binder comprises: (i) a saccharide selected from the group consisting of a monosaccharide, a disaccharide, an oligosaccharide, a derivative thereof, and any combination thereof and/or (ii) cellulosic compound;
forming the carbon-binder mixture to produce a shaped carbon composite; and
heating the shaped carbon composite in a heating zone to carbonize the binder thereby producing the shaped porous carbon product,
wherein the content of the saccharide and/or cellulosic compound binder(s) in the carbon-binder mixture is from about 20 wt. % to about 65 wt. %.

2. The process of claim 1 wherein the heating zone comprises at least two heating stages that are each maintained at an approximately constant temperature and the temperature of each stage differs by at least about 50° C., with the temperature increasing from one stage to the next.

3. The process of claim 2 wherein the temperature of each stage differs by from about 50° C. to about 500° C.

4. The process of claim 2 wherein the heating zone comprises a multi-stage continuous rotary kiln.

5. The process of claim 1 wherein the heating zone comprises at least three heating stages that are each maintained at an approximately constant temperature and the temperature of each stage independently differs by at least about 50° C. from the preceding stage.

6. The process of claim 1 wherein the carbon-binder mixture further comprises a solvent.

7. The process of claim 6 wherein the process further comprises drying the shaped carbon composite to remove at least a portion of the solvent contained therein.

8. The process of claim 7 wherein the water content of the shaped carbon composite after drying is in the range of from about 2 wt. % to about 15 wt. %.

9. The process of claim 7 wherein the heating zone further comprises one or more stages for drying the shaped carbon composite.

10. The process of claim 7 wherein the heating zone comprises a belt conveyor furnace.

11. The process of claim 1 wherein the binder comprises: (i) the saccharide selected from the group consisting of a monosaccharide, a disaccharide, an oligosaccharide, a derivative thereof, and any combination thereof and (ii) the cellulosic compound, wherein a 2 wt. % aqueous solution of the cellulosic compound has a viscosity of no greater than about 500 mPa·s at 25° C. and/or the cellulosic compound has a number average molecular weight (M n ) that is no greater than about 50,000 g/mol.

12. The process of claim 1 wherein the shaped carbon composite is heated to a final temperature in the range of from about 400° C. to about 1,000° C. in the heating zone.

13. The process of claim 1 wherein the shaped carbon composite is formed by extruding the carbon-binder mixture.

14. The process of claim 1 wherein the weight ratio of binder to carbonaceous material in the carbon-binder mixture is from about 1:4 to about 3:1.

15. The process of claim 1 wherein the shaped porous carbon product has a radial piece crush strength greater than about 4.4 N/mm (1 lb/mm).

16. The process of claim 1 wherein the shaped porous carbon product has a mechanical piece crush strength greater than about 22 N (5 lbs).

17. The process of claim 1 wherein the binder does not comprise a non-carbohydrate synthetic polymer.

18. The process of claim 1 wherein the carbonaceous material comprises carbon black.

19. The process of claim 18 wherein the carbon black has a BET specific surface area from about 5 m 2 /g to about 500 m 2 /g.

20. The process of claim 1 wherein the cellulosic compound is selected from the group consisting of methylcellulose, ethylcellulose, ethylmethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, methylhydroxyethylcellulose, ethylhydroxyethylcellulose, hydroxypropylmethylcellulose, carboxymethylcellulose, and mixtures thereof.

21. The process of claim 1 wherein the cellulosic compound comprises a starch.

22. The process of claim 1 wherein the binder comprises the saccharide and the cellulosic compound, wherein the saccharide is selected from the group consisting of glucose, fructose or hydrate thereof and the cellulosic compound is selected from the group consisting of hydroxyethylcellulose, methylcellulose, and starch.

23. The process of claim 22 wherein the content of the saccharide and cellulosic compound binder in the carbon-binder mixture is from about 35 wt. % to about 65 wt. %.

Assignees

• Archer Daniels Midland Co

Inventors

• Diamond Gary M
• Zhu Guang
• Murphy Vincent J
• Dias Eric

Classifications

• Y02E60/10

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• C04B2111/0081

  as catalysts or catalyst carriers · CPC title

• C04B2111/00793

  as filters or diaphragms · CPC title

• C04B2235/96

  Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance · CPC title

• C04B2235/606

  Drying · CPC title