Manufacturing core-shell catalyst and apparatus for scale-up manufacturing the same

Patent metadata

Field	Value
Publication number	US-10722859-B2
Application number	US-201715646997-A
Country	US
Kind code	B2
Filing date	Jul 11, 2017
Priority date	Dec 7, 2016
Publication date	Jul 28, 2020
Grant date	Jul 28, 2020

Abstract

To provide a reactor to improve evenness in the thickness of shell metals coated on the surface of core particles by increasing area sizes in the reactor chamber to control electric potentials, the present invention is configured to comprise a top surface able to move up and down while serving as a working electrode, a wall serving as a working electrode, a bottom surface, a standard electrode, a power supplying part and a solution injecting part, wherein the top surface can move up and down automatically by an electric motor or manually. Also, the top surface is configured to be suitable for the interior diameter of the reactor chamber, for solutions inside the reactor chamber not to leak from the top surface or from the crevice between the top surface and the wall of the reactor chamber. The bottom surface of the reactor chamber may comprise an impeller or an ultrasonic wave diffuser to bring about even diffusion in the reactor chamber.

First claim

The invention claimed is:

1. An underpotential deposition (UPD) reactor comprising:
a top surface configured as an electric conductor to serve as a working electrode and further configured to be able to move up and down using an electric motor;
a wall configured to have an interior which is the same shape as an exterior of the top surface and configured to have an interior diameter which is the same as the diameter of the exterior of the top surface to allow the top surface to move up and down within the interior of the wall, and configured as an electric conductor to serve as the working electrode together with the top surface;
a bottom surface configured to face the top surface and to be connected to the wall; and
a power supplying part to input voltages into a reference electrode and a counter electrode and a solution injecting part,
wherein the UPD reactor comprises one or more of titanium, niobium or graphite.

2. The UPD reactor of claim 1 , further comprising a sensor to measure temperatures, pressures, voltages and concentration of products.

3. The UPD reactor of claim 2 , wherein the sensor to measure concentration of products is configured to comprise infrared light sources and a detector to detect the infrared light sources.

4. The UPD reactor of claim 1 , wherein the top surface can move up and down by the electric motor and a driving shaft connected to the electric motor.

5. The UPD reactor of claim 1 , wherein the top surface configured to be able to move up and down by a driving shaft that is manually controllable.

6. The UPD reactor of claim 1 , wherein the top surface comprises a plurality of channels to allow solutions under the top surface to go up through the top surface, and wherein the channels comprise filters.

7. The UPD reactor of claim 1 , wherein the top surface comprises a plurality of channels to allow solutions over the top surface to come down through the top surface.

8. The UPD reactor of claim 1 , wherein the wall comprises two or more of the reference and counter electrodes installed through the wall, wherein the reference and counter electrodes do not protrude from the interior surface of the wall and wherein filters are placed at the end of the reference and counter electrodes contacting solutions inside the wall.

9. The UPD reactor of claim 1 , wherein the bottom surface is configured to comprise an impeller to mix solutions inside the reactor chamber and a motor to drive the impeller.

10. The UPD reactor of claim 1 , wherein the bottom surface is configured to comprise a flat or convex-type ultrasonic generator to mix solutions inside the reactor chamber.

11. The UPD reactor of claim 9 , wherein the impeller is configured to be enclosed in the bottom surface not to protrude outwardly.

12. The UPD reactor of claim 10 , wherein the ultrasonic generator is configured to be enclosed in the bottom surface not to protrude outwardly.

Assignees

• Korea Inst Energy Res

Inventors

• Park Gu-Gon
• Hwang Sun-Mi
• Yim Sung-Dae
• Kim Chang-Soo
• Lee Won-Yong
• Yang Tae-Hyun
• Park Seok-Hee
• Kim Minjin
• Sohn Young-Jun
• Bae Byungchan
• Kim Seung-Gon
• Shin Dongwon

Classifications

• B01J19/087 Primary

  employing electric or magnetic energy · CPC title

• B01F31/83

  comprising a supplementary stirring element · CPC title

• B01F31/86

  with vibration of the receptacle or part of it · CPC title

• Y02E60/50

  Fuel cells · CPC title

• H01M4/9041

  Metals or alloys (H01M4/92 takes precedence) · CPC title