Selective catalytic reduction process and method of regenerating deactivated SCR catalyst of a parallel flue gas treating system

Patent metadata

Field	Value
Publication number	US-10722844-B2
Application number	US-201916543035-A
Country	US
Kind code	B2
Filing date	Aug 16, 2019
Priority date	Aug 22, 2018
Publication date	Jul 28, 2020
Grant date	Jul 28, 2020

Abstract

Presented is a process for the regeneration of a deactivated nitrogen oxide decomposition catalyst of a selective catalytic reduction system that is a component of a flue gas treating system that is one of parallel flue gas treating systems. The selective catalytic reduction system is isolated to provide a closed system in which a regeneration gas is circulated to regenerate the deactivated nitrogen oxide decomposition catalyst. Denitrified flue gas from a parallel flue gas treating system is introduced and used within the closed system as regeneration gas.

First claim

That which is claimed is:

1. A process for selective catalytic reduction of nitrogen oxides contained in a gas stream and regeneration of a deactivated SCR catalyst, wherein said process comprises:
providing a first processed flue gas stream, containing nitrogen oxides and sulfur compounds, and a second processed flue gas stream, containing nitrogen oxides and sulfur compounds;
passing said first processed flue gas stream to a first SCR system having an upstream inlet and a downstream outlet that includes a first SCR catalyst and contacting said first processed flue gas stream with said first SCR catalyst in the presence of ammonia for a time sufficient to provide a deactivated first SCR catalyst deactivated by sulfur compounds and yielding from said first SCR system a first denitrified flue gas stream for discharge into a stack;
passing said second processed flue gas stream to a second SCR system that includes a second SCR catalyst and yielding from said second SCR system a second denitrified flue gas stream for discharge;
discontinuing said step of passing said first processed flue gas stream to said first SCR system by isolating said first SCR system to provide a closed system;
introducing at an introduction rate a portion of said second denitrified flue gas stream into said closed system as a regeneration gas used to regenerate said first SCR catalyst and to yield a regeneration effluent gas containing SOx and ammonia; and circulating at a circulation rate all or part of said regeneration effluent gas from said downstream outlet to said upstream inlet; and
removing at a removal rate a portion of said regeneration effluent gas from said closed system and introducing said portion of said regeneration effluent gas into a parallel flue gas treating system that includes a second acid gas removal unit, a second particulate removal unit and said second SCR system, wherein said parallel flue gas treating system provides for removing at least a portion of the SOx and ammonia contained in said regeneration effluent gas of said first SCR system.

2. The process as recited in claim 1 , further comprising:
burning a combustible material within a first furnace component of a flue gas treating system and yielding therefrom a first flue gas stream, comprising nitrogen oxides, acid gas components, and particulates;
treating said first flue gas stream by a first acid gas removal unit to remove a portion of the acid gas components from said first flue gas stream and to yield a first desulfurized flue gas stream; and
removing particulates from said first flue gas stream or said first desulfurized flue gas stream by a first particulate removal unit to yield said first processed flue gas stream.

3. The process as recited in claim 2 , further comprising:
removing a portion of said nitrogen oxides in said first flue gas stream by introducing either ammonia or urea or both into said first furnace to induce selective non-catalytic reduction of said nitrogen oxides.

4. The process as recited in claim 3 , further comprising:
introducing heat energy into said regeneration effluent gas of said closed system to thereby control a regeneration temperature of said regeneration gas.

5. The process as recited in claim 4 , further comprising:
measuring said system pressure and comparing said system pressure against a desired system pressure to provide a differential system pressure; and
adjusting said portion of said second denitrified flue gas stream that is introduced into said closed system in response to said differential system pressure to maintain said system pressure at said desired system pressure.

6. The process as recited in claim 5 , further comprising:
measuring said removal rate of said portion of said regeneration effluent gas to provide a measured removal rate and comparing said measured removal rate against a desired removal rate to provide a differential removal rate; and
adjusting said removal rate in response to said differential removal rate to maintain said removal rate at said desired removal rate.

7. The process as recited in claim 6 , further comprising:
measuring said circulation rate of said regeneration gas to provide a measured circulation rate and comparing said measured circulation rate against a desired circulation rate to provide a differential circulation rate; and
adjusting said circulation rate in response to said differential circulation rate to maintain said circulation at said desired circulation rate.

8. The process as recited in claim 1 , further comprising:
burning a first combustible material within a first furnace component with a downstream flue gas treating system and yielding therefrom a first flue gas stream, comprising nitrogen oxides, acid gas components, and particulates;
removing particulates from said first flue gas stream by a first particulate removal unit to provide a first cleaned gas stream; and
treating said cleaned flue gas stream by an acid gas removal unit to remove acid gas components from said first cleaned flue gas stream and to yield a first desulfurized flue gas stream as said first processed flue gas stream to said first SCR system.

9. The process as recited in claim 8 , further comprising:
removing a portion of said nitrogen oxides in said first flue gas stream by introducing either ammonia or urea or both into said first furnace to induce selective non-catalytic reduction of said nitrogen oxides.

10. The process as recited in claim 9 , further comprising:
introducing heat energy into said regeneration gas of said closed system to thereby control a regeneration temperature of said regeneration gas.

11. The process as recited in claim 10 , further comprising:
measuring said system pressure and comparing said system pressure against a desired system pressure to provide a differential system pressure; and
adjusting said portion of said second denitrified flue gas stream that is introduced into said closed system in response to said differential system pressure to maintain said system pressure at said desired system pressure.

12. The process as recited in claim 11 , further comprising:
measuring said removal rate of said portion of said regeneration effluent gas to provide a measured removal rate and comparing said measured removal rate against a desired removal rate to provide a differential removal rate; and
adjusting said removal rate in response to said differential removal rate to maintain said removal rate at said desired removal rate.

13. The process as recited in claim 12 , further comprising:
measuring said circulation rate of said regeneration gas to provide a measured circulation rate and comparing said measured circulation rate against a desired circulation rate to provide a differential circulation rate; and
adjusting said circulation rate in response to said differential circulation rate to maintain said circulation at said desired circulation rate.

14. The process as recited in claim 1 , further comprising:
passing said first processed flue gas stream around said closed system as a by-pass stream and passing said by-pass stream to said stack.

15. The process as recited in claim 4 , further comprising:
measuring said introduction rate of said portion of said second processed flue gas to provide a measured introduction rate and comparing said measured introduction rate against a desired introduction rate to provide a differential introduction rate; and
adjusting said introduction rate of said portion of said second processed flue gas stream in response to said differential introduction rate to maintain said introduction rate at sa

Assignees

• Shell Oil Co

Inventors

• Seng Guido

Classifications

• F23J15/02

  of purifiers, e.g. for removing noxious material (traps for solid residues F23J3/04) · CPC title

• F23J11/12

  Smoke conduit systems for factories or large buildings · CPC title

• B01D2258/0283

  Flue gases · CPC title

• B01D2257/404

  Nitrogen oxides other than dinitrogen oxide · CPC title

• B01D53/96

  Regeneration, reactivation or recycling of reactants · CPC title